1st SEMESTER - 2 Flashcards

1
Q

VSEPR Theory

A

Valence Shell Electron Pair Repulsion Theory.

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2
Q

Linus Pauling

A

He showed mathematically how an s orbital and p orbitals can combine to form four equivalent atomic orbitals.

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3
Q

Dispersion Forces

A

Weakest interaction between non polar covalent molecules produced through “temporary dipoles”.

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4
Q

Resonance property

A

Migration of electrons and shows stability of a molecule.

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5
Q

How does sp hybrid orbitals form?

A

sp hybridized orbitals form when one s orbital and one p orbital overlaps forming a sigma overlap.

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6
Q

What is the product of hybridization?

A

Hybrid Orbitals

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7
Q

Define melting point.

A

Temperature at which particles of solid is changed to liquid through application of heat.

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8
Q

Sigma overlap between one s orbital and three p orbitals.

A

sp3 hybrid orbitals

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9
Q

Hybridization between alkyne molecules.

A

sp hybridization

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10
Q

Bond angle and shape of sp3 hybridization

A

105-110 degrees, tetrahedral

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11
Q

Intramolecular Forces

A

Chemical bonds present between atoms.

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12
Q

sp2 hybridization

A

Happens when one s orbital overlap with two p orbitals.

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13
Q

_________________ is inversely proportional to bond length.

A

Bong strength

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14
Q

He introduced the concept of electronegativity.

A

Linus Pauling

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15
Q

Hybridization of alkenes.

A

sp2 hybridization

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16
Q

sp3 hybridization

A

Overlap between s atomic orbital and three p orbitals.

17
Q

How many pi bonds and sigma bonds present in an sp hybridization of carbon? How about sp3? How about sp2?

A

sp - 2 pi bonds, 2 sigma bonds
sp3 - no pi bond, 4 sigma bonds
sp2 - 1 pi bond, 3 sigma bonds

18
Q

H - Bond

A

When hydrogen act as a bridge between two most electronegative atoms.

19
Q

Define surface tension and its relationship with intermolecular forces.

A

The liquids ability to resist spreading out. The higher the intermolecular force between atoms, the higher the surface tension.

20
Q

Force between polar molecules. Usually in liquids.

A

Dipole-Dipole

21
Q

Sublimation

A

Ability of solid to change to gas without undergoing the liquid phase.

22
Q

Volatility

A

Describes how readily a substance vaporizes that vary by the number of hydrogen bonds present between molecules.

23
Q

The more _________ the molecule is, the lower the dispersion forces.

A

Sperical

24
Q

Bond angle of sp hybridized atoms.

A

180 degrees; linear

25
Q

Hybridization of N₂ molecule

A

sp hybridization

26
Q

Characteristics of hybridized orbitals.

A

Directional and has bigger lobes.

27
Q

Hybridization of CO₂

A

sp hybridized

28
Q

Distortion of electron cloud caused by another molecule.

A

Polarization

29
Q

Hybridization of H₂O

A

sp3 hybridized

30
Q

The magnitude of Va Der Waals IMF strength is dependent on the ____ and _____ of the molecule.

A

size, shape

31
Q

IMF present between water molecules.

A

Hydrogen Bonds

32
Q

Hybrid orbitals that forms a trigonal shape.

A

sp² hyrid orbitals

33
Q

Dipole-Dipole

A

Attractions between oppositely charged regions of a polar molecule.

34
Q

Strongest type of IMF

A

Hydrogen Bonds