1.7 Flashcards
kinetics
shows how a chemical process occurs
the rate law
aA+bB–> cC+dD. shows the relationship between the reaction rate and the concentrations of reactants
k
rate constant. unique for each reaction
orders of reaction
with respect to A and B have to be found experimentally
increasing the concentration
increases the reaction rate. order of the reaction depends on this
overall rate of a reaction
the sum of the powers of each individual reactant’s concentrations. so overall rate would be x + y
zero order
no impact
first order
doubles rate. ls -1
second order
quadruples rate 2 mol-1 ls-1
units for k
depend on the overall rate of reaction 3 mol-2 l2s-1
determining step
the slow step of a reaction. the integers in the rate equation refer to the actual number of particles involved in the smaller step of the reaction