1.3 Flashcards
Orbital boxes
1s, 2s, 2p, 3s, 3p, 4s, 3d. 4s comes before 3d if it is an ion or transition metal
Dative covalent bond
When one atom provides both of the electrons that form the covalent bond
Resonance structure
More stable than normal structure. A double and single bond will flip around e.g. ozone
VSEPR
Valence Shell Electron Pair Repulsion Theory. Outer electrons repel each other
Strength of electron repulsions
(Decreasing in strength): non-bonding/non-bonding; non-bonding/bonding; bonding/bonding. This can cause distortions in the shapes of molecules
Number of electron pairs, formula
Number of outer electrons on central atom + number of bonded atoms — charge. DIVIDE ALL THIS BY 2
Linear
2 electron pairs. 180
Trigonal planar
3 pairs. 120
Tetrahedral
4 pairs. 109.5
Trigonal bipyramidal
5 pairs. Down 90, across 120
Octahedral
6 pairs. 90
Bonding pairs
Shape is dependent on number of bonded electrons, so answer to formula may not always be right
Minimising electron repulsion
Lone pairs of electrons are always positioned equatorially to minimise repulsion. The shape of the molecule is also supposed to minimise this
Ionic bonds
Will form when atoms can rearrange their electrons to produce an arrangement of lower energy. Ionic lattices are more stable