16.1 Flashcards

1
Q

An acid is a substance that, when…

A

dissolved in water, increases the concentration of H+ ions.

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2
Q

A base is a substance that, when…

A

dissolved in water, increases the concentration of OH- ions.

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3
Q

An acid is a…

A

proton donor

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4
Q

A base is a…

A

proton acceptor

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5
Q

Water is amphiprotic. What does this mean

A

It can act as a base and an acid depending on the equation

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6
Q

In an equation, Acid turns into …
Base to…

A

Acid to … conjugate base (conjugate base loses an H compared to acid)
Base to…conjugate acid (conjugate acid gains an H compared to base)

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7
Q

Stronger​ acid + Stronger base =

A

Weaker base + weaker acid

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8
Q

Weaker​ acid + Weaker​ base =

A

stronger​ acid + stronger abse

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9
Q

Water is amphoteric.​
In pure water, a few molecules act as bases and a few act as acids.​
This is referred to as…

A

autoionization

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10
Q
  1. If a solution is neutral…
  2. If a solution is acidic…
  3. If a solution is basic…
A
  1. [H+] = [OH-]
  2. [H+] > [OH-]
  3. [H+] < [OH-]
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11
Q

Two ways to measure pH is with a…

A

pH meter
pH meters are used for accurate measurement of pH; electrodes indicate small changes in voltage to detect pH.​

Another method is with indicators.​
They give less accurate, but quick measurements.​
An indicator is a compound that has one color in its acid form and another color in its basic form.​

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12
Q

The larger the value of Ka…

A

The stronger the acid

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13
Q

Polyprotic acids have more than…

A

one acidic proton.​
It is always easier to remove the first proton than any successive proton.​

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14
Q

Salts are…

A

by-products of neutralization reactions.
They can be made by many other reactions. ​
The main product of the neutralization reaction is water.​

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15
Q

Salts are

A

ionic compounds and many ions are acidic or basic!​

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16
Q

The cation can be…

A

acidic or neutral.

17
Q

The anion can be…

A

acidic, basic, or neutral.​

18
Q

Anions of strong acids (conjugate bases of strong acids) are…

A

neutral

19
Q

Anions of weak acids (conjugate bases of weak acids) are…

A

basic

20
Q

Transition and post-transition metal cations are…

A

acidic

21
Q

Polyatomic cations are typically…

A

the conjugate acids of a weak base, so they are acidic (ex. NH4+)

22
Q

In the period, polarity is more important, as the electronegativity of A increases…

A

Acid strength increases

23
Q

Two contributions to H-A strength

A

H—A bond polarity: H-A bond must be polarized with δ+ on the H atom and δ– on the A atom. ​

Bond strength: weaker H-A bonds can be broken more easily, making the acid stronger.​

24
Q

In the group, bond strength is more important, going down in the group…

A

acid strength increases (longer bonds are weaker).

25
Q
  1. Oxyacids consist of…
  2. Generally, as the electronegativity of the nonmetal (X) increases
A
  1. H, O, and one other element, which typically is a nonmetal.​
  2. the acidity increases for acids with the same structure.​
26
Q

Oxyacids:
If the oxidation number increases…

A

the acidity increases

27
Q

Carboxylic acids are…

A

organic acids containing the —COOH group​

28
Q

A Brønsted–Lowry (B-L) acid must have

A

at least one removable (acidic) proton (H+) to donate.​

29
Q

A Brønsted–Lowry (B-L) base

A

must have at least one nonbonding pair of electrons to accept a proton (H+).​