14.2 Functional Group Chemistry Flashcards
1
Q
What type of carbon bonds do compounds in the alkane group have?
A
only single carbon bonds
2
Q
What is the alkane group?
A
A homologous series of hydrocarbon compounds with only single carbon bonds, there are no C=C bonds present
3
Q
What is the general formula of alkanes?
A
CnH2n+2
4
Q
What type of hydrocarbons are alkanes?
A
Alkanes are classified as saturated hydrocarbons
5
Q
What does it mean if an alkane is saturated?
A
all the carbon bonds in alkanes are single bonds
6
Q
What colour are alkanes?
A
They are colourless compounds
7
Q
What changes across the alkane group?
A
have a gradual change in their physical properties as the number of carbon atoms in the chain increases
8
Q
Are alkanes reactive?
A
Alkanes are generally unreactive compounds
9
Q
What reactions can alkanes undergo? (3)
A
- they undergo combustion reactions
- can be cracked into smaller molecules
- react with halogens in the presence of light
10
Q
What fossil fuel is an alkane?
A
Methane is an alkane and is the major component of natural gas
11
Q
What are the first 3 alkanes?
A
methane
ethane
propane
12
Q
What is a substitution reaction?
A
In a substitution reaction, one atom is swapped with another atom
13
Q
With what group do alkanes react with in a substitution reaction?
A
Alkanes undergo a substitution reaction with halogens
14
Q
What condition must be present for a substitution reaction between halogens and alkanes to occur?
A
the presence of ultraviolet radiation
15
Q
Word equation for methane and bromine
A
Methane + Bromine → Bromomethane + Hydrogen Bromide
16
Q
Chemical Equation for methane and bromine
A
CH4 + Br2 → CH3Br + HBr
17
Q
What is the alkene group?
A
A homologous series of hydrocarbon compounds with carbon-carbon double bonds (C = C)
18
Q
What is the general formula for the alkene group?
A
CnH2n
19
Q
What chemical characteristic do ALL alkenes have?
A
All alkenes contain a double carbon bond, which is shown as two lines between two of the carbon atoms
20
Q
What is the double carbon bond present in alkenes known as?
A
This is the alkene functional group and is what allows alkenes to react in ways that alkanes cannot
21
Q
What type of hydrocarbons are alkenes?
A
Compounds that have a C=C double bond are also called unsaturated compounds
22
Q
Why is catalytic cracking used?
A
Although there is use for each fraction obtained from the fractional distillation of crude oil, the amount of longer chain hydrocarbons produced is far greater than needed
23
Q
What is converted into what during catalytic cracking?
A
A process called catalytic cracking is used to convert longer-chain molecules into short-chain and more useful hydrocarbons
24
Q
What is a product of cracking alkenes?
A
Alkenes and hydrogen are produced from the cracking of alkanes
25
What 2 alkenes are most commonly used in cracking and what do they produce?
Kerosene and diesel oil are often cracked to produce petrol, other alkenes and hydrogen
26
1. What is the first step for catalytic cracking?
catalytic cracking
Fractions containing large hydrocarbon molecules are heated at 600 – 700°C to vaporise them
27
2. What happens to the hydrocarbon vapours?
catalytic cracking
Vapours will then pass over a hot catalyst of silica or alumina
28
3. Why are the vapours passed over a hot catalyst? What reaction occurs?
catalytic cracking
This process breaks covalent bonds in the molecules, causing thermal decomposition reactions
29
4. What happens as a result of these reactions?
catalytic cracking
As a result, cracking produces smaller alkanes and alkenes.
The molecules are broken up in a random way which produce a mixture of alkanes and alkenes
30
5. What are the optimum conditions for catalytic cracking?
catalytic cracking
Hydrogen and a higher proportion of alkenes are formed at temperatures of above 700ºC and higher pressure
31
Do alkanes and alkenes have the same molecular structures?
NO
| they have different ones
32
What is the difference between alkanes and alkenes referring to their carbon bonds?
All alkanes are saturated and alkenes are unsaturated
33
What chemical property allows us to differentiate between alkanes and alkenes?
The presence of the C=C double bond allows alkenes to react in ways that alkanes cannot
34
1. What substance can be used to differentiate between alkanes and alkenes?
differentiating between alkenes and alkanes
bromine water
35
2. What is bromine water?
differentiating between alkenes and alkanes
Bromine water is an orange coloured solution of bromine
36
3. What will happen when bromine water is shaken with an alkane? Why?
differentiating between alkenes and alkanes
When bromine water is shaken with an Alkane, it will remain as an orange solution as alkanes do not have double carbon bonds (C=C) so the bromine remains in solution
37
4. What will happen when bromine water is shaken with an alkene? Why?
differentiating between alkenes and alkanes
when bromine water is shaken with an alkene, the alkene will decolourise the bromine water and turn colourless as alkenes do have double carbon bonds (C=C)
38
5. Why do the double carbon bonds decolourise the bromine water?
differentiating between alkenes and alkanes
The bromine atoms add across the C=C double bond hence the solution no longer contains the orange coloured bromine
39
6. What is this decolorisation reaction called?
differentiating between alkenes and alkanes
This reaction between alkenes and bromine is called an addition reaction
40
7. What is an addition reaction?
differentiating between alkenes and alkanes
A reaction in which a simple molecule adds across the carbon-carbon double bond of an alkene
41
1. How are addition polymers formed? What makes them up?
addition polymerisation
Addition polymers are formed by the joining up of many small molecules called monomers
42
2. In what monomers does addition polymerisation take place?
addition polymerisation
Addition polymerisation only occurs in monomers that contain C=C bonds
43
3. What happens to the double carbon bonds during addition polymerisation? What new bonds are formed?
addition polymerisation
One of the bonds in each double bond breaks and forms a bond with the adjacent monomer
44
4. What is an example of a polymer synthesised from alkene monomers? What is it made of?
addition polymerisation
A common example is poly-ethene (polythene) which is the addition of many ethene monomers
45
What is an example of an addition reaction?
ethene + bromine
46
What is formed between the addition reaction of ethene and bromine?
ethene + bromine --> 1,2-dibromoethane
47
1. With what element do alkenes react to form alkanes?
hydrogenation reactions
Alkenes also undergo addition reactions with hydrogen in which an alkane is formed
48
2. What is the reaction between alkenes and
hydrogen called?
h r
These are hydrogenation reactions
49
3. What conditions are needed for hydrogenation reactions to occur?
hydrogenation reactions
occur at 150ºC using a nickel catalyst
50
4. What practical use do hydrogenation reactions have?
hydrogenation reactions
Hydrogenation reactions are used to change vegetable oils into margarine to be sold in supermarkets
51
1. What do alkenes react with to form alcohol?
hydration reactions
Alkenes also undergo addition reactions with steam in which an alcohol is formed
52
2. What is the reaction called that turns alkenes into alcohol?
hr
Since water is being added to the molecule it is also called a hydration reaction
53
3. What conditions are needed for hydration reactions to occur?
hydration reactions
Temperature of around 330ºC
Pressure of 60 – 70 atm
Concentrated phosphoric acid catalyst
54
4. Where are hydration reactions important?
hydration reactions
The reaction is very important industrially for the production of alcohols
55
What are the alcohols?
Family of organic compounds that all contain the -OH functional group
56
What is the functional group?
This is the group of atoms responsible for their chemical properties and reactions
57
Which alcohol is considered the most important?
Ethanol (C2H5OH) is one of the most important alcohols
58
Where is ethanol found?
It is the type of alcohol found in alcoholic drinks such as wine and beer
It is also used as fuel for cars and as a solvent
59
What does alcohol produce when it burns?
Alcohols burn in excess oxygen and produce CO2 and H2O
60
Chemical equation for combustion of ethanol
C2H5OH(l) + 3 O2(g) ==> 2 CO2(g) + 3 H2O(g)
61
What two methods can be used to create ethanol?
The hydration of ethene with steam
| The fermentation of glucose
62
1. What is passed over what to create gaseous ethanol in the hydration of ethene?
hydration of ethene
A mixture of ethene and steam is passed over a hot catalyst of phosphoric acid
63
2. What is the temperature and pressure?
hydration of ethene
temperature of 330°C
The pressure is used 60-70 atmosphere
64
3 What happens to the gaseous ethanol?
hydration of ethene
The gaseous ethanol is then condensed into a liquid for use
65
1. What is dissolved and what must be added to begin the process?
Fermentation of glucose
Sugar or starch is dissolved in water and yeast is added
66
2. In what conditions is this mixture fermented?
Fermentation of glucose
The mixture is then fermented between 15 and 35°C with the absence of oxygen for a few days
67
3. What does yeast contain which is useful for this reaction?
Fermentation of glucose
Yeast contains enzymes that break down starch or sugar to glucose
68
4. What will happen if the temperature becomes too low?
Fermentation of glucose
If the temperature is too low the reaction rate will be too slow
69
5. What will happen if the temperature is too high?
Fermentation of glucose
if it is too high the enzymes will become denatured
70
6. What do the yeast do to form ethanol? What other product is formed?
Fermentation of glucose
the yeast respire anaerobically using the glucose to form ethanol and carbon dioxide
71
7. What is the chemical reaction for the fermentation of glucose?
Fermentation of glucose
C6H12O6 + Enzymes → 2CO2 + 2C2H5OH
72
8. Why is ethanol production by fermentation a batch process?
Fermentation of glucose
The yeast are killed off once the concentration of alcohol reaches around 15%, hence the reaction vessel is emptied and the process is started again
73
What is the difference between the hydration of ethene and fermentation in terms of equipment?
H - complex set-up required
F - simple equipment needed
74
What is the difference between the hydration of ethene and fermentation in terms of the raw materials?
H - uses non-renewable resources (crude oil)
F - uses renewable resources (Sugar cane)
75
What is the difference between the hydration of ethene and fermentation in terms of the type of process?
H - continuous process
F - Batch Process - everything is
76
What is the difference between the hydration of ethene and fermentation in terms of the rate of reaction?
H - fast
F - slow
77
What is the difference between the hydration of ethene and fermentation in terms of the quality of product?
H - produces pure ethanol
F - produces a dilute solution requiring further processing
78
What is the difference between the hydration of ethene and fermentation in terms of the atmospheric effects?
H - no greenhouse gas is produced but pollutants are formed from the burning of fossil fuels to maintain a high temperature
F - CO2 produced which is a greenhouse gas
79
What is the difference between the hydration of ethene and fermentation in terms of the reaction conditions?
H - high temperatures and pressures required, increasing the energy input and cost
F- Low temperatures required
80
What does it mean when the hydration of ethene is referred to as a continuous process? Is this good or bad?
a stream of reactant is constantly passed over the catalyst. This is more EFFICIENT than a batch process
81
What does it mean when fermentation is referred to as a batch process? Is this good or bad?
everything is mixed together in a reaction vessel and then left for several days. That batch is then removed and a new reaction is set up - this is inefficient
82
What are carboxylic acids?
These are a homologous series of organic compounds that all contain the same functional group: –COOH
83
What colour are carboxylic acids?
They are colourless liquids
84
How strong are carboxylic acids?
are weakly acidic
85
What chemical properties do carboxylic acids have?
have typical acidic properties
86
What solutions do carboxylic acids react with?
They react with alkaline solutions
87
What colour do carboxylic acids turn blue litmus paper?
turn blue litmus red
88
What salts do carboxylic acids form?
form salts called ethanoates
89
What are the first 3 carboxylic acids?
methanoic acid
ethanoic acid
propanoic acid
90
What can ethanoic acid do in water?
Ethanoic acid is a typically weak acid and dissociates slightly in water
91
What is produced when ethanoic acid dissociates in water?
a mildly acidic solution
92
What is the ionic equation for the dissociation of ethanoic acid?
CH3COOH ⇌ H+ + CH3COO-
93
Where does the equilibrium lie during the ionisation of ethanoic acid?
far to the left
94
With what 3 compounds does ethanoic acid react with?
Ethanoic acid reacts with the more reactive metals, hydroxides and carbonates
95
What is produced when ethanoic acid reacts with metals?
In the reaction with metals a metal salt and hydrogen gas are produced
96
Give the chemical equation for the reaction between magnesium and ethanoic acid?
What is the salt formed in this reaction called?
2CH3COOH + Mg → (CH3COO)2Mg + H2
magnesum ethanoate
97
What is formed when ethanoic acid reacts with hydroxides? What type of reaction is this?
In the reaction with hydroxides a salt and water are formed in a neutralisation reaction
98
Give the equation for the reaction between potassium hydroxide and ethanoic acid
What is the name of the salt formed?
CH3COOH + KOH → CH3COOK + H2O
potassium ethanoate
99
What is formed when ethanoic acid reacts with carbonates?
In the reaction with carbonates a metal salt, water and carbon dioxide gas are produced
100
Give the equation for the reaction between potassium carbonate and ethanoic acid
What is the name of the salt formed?
2CH3COOH + K2CO3 → 2CH3COOK + H2O + CO2
potassium ethanoate
101
In what two ways can carboxylic acids be made?
Oxidation by fermentation
Oxidation with potassium manganate (VII)
102
1. What is oxidised?
Oxidation by fermentation
The microbial oxidation of ethanol
103
2. What will the microbial oxidation fo alcohol produce?
Oxidation by fermentation
a weak solution of vinegar (ethanoic acid).
104
3. What happens when you leave a bottle of wine opened?
Oxidation by fermentation
bacteria in the air (acetobacter) will use atmospheric oxygen from air to oxidise the ethanol in the wine
The acidic, vinegary taste of wine which has been left open for several days is due to the presence of ethanoic acid
105
4. What is the chemical equation for oxidation by fermentation to produce ethanoic acid?
Oxidation by fermentation
C2H5OH + O2 → CH3COOH + H2O
106
1. What needs to be added to alcohols to create carboxylic acids?
o pm
Alcohols can also be oxidised to carboxylic acids by heating with acidified potassium manganate (VII)
107
2. How I the heating of the solution performed?
Oxidation with potassium manganate (VII)
The heating is performed under reflux which involves heating the reaction mixture in a vessel with a condenser attached to the top
108
3. Why is a condenser used?
Oxidation with potassium manganate (VII)
The condenser prevents the volatile alcohol from escaping the reaction vessel as alcohols have low boiling points
109
1. What two compounds are used to make esters?
Making esters
Alcohols and carboxylic acids react to make esters
110
2. What are the reactions that create esters called?
Making esters
esterification reactions
111
3. What functional group do esters have?
Making esters
Esters are compounds with the functional group R-COO-R
112
4. What do esters look like and where are they used?
Making esters
Esters are sweet-smelling oily liquids used in food flavourings and perfumes
113
5. What is the catalyst used to create esters?
Making esters
concentrated sulfuric acid
114
6. What will be formed when ethanoic acid reacts with ethanol?
Making esters
Ethanoic acid will react with ethanol in the presence of concentrated sulfuric acid (catalyst) to form ETHYL ETHANOATE
115
7. Chemical equation for reaction between ethanoic acid and ethanol?
Making esters
CH3COOH + C2H5OH → CH3COOC2H5 + H2O
116
8. Draw the compounds which are present in the reaction between ethanoic acid and ethanol and the products
Making esters
on website
117
1. What does the first part of the name indicate?
Naming esters
The first part of the name indicates the length of the carbon chain in the alcohol,
118
2. What does the first part of the name end in?
Naming esters
ends with the letters ‘- yl’
119
3. What does the second part of the name indicate?
Naming esters
The second part of the name indicates the length of the carbon chain in the carboxylic acid
120
4. What does the second part of the name end in?
Naming esters
ends with the letters ‘- oate’
121
5. What is the name of the ester formed from pentanol and butanoic acid?
Naming esters
pentyl butanoate
