13. Carbonates Flashcards

1
Q

What does limestone mainly consist of?

A

Limestone consists mainly of calcium carbonate, CaCO3

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2
Q

What is lime?

A

calcium oxide

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3
Q

How is lime made?

A

manufactured from calcium carbonate by thermal decomposition:

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4
Q

What is the chemical equation for the thermal decomposition of limestone?

A

CaCO3 → CaO + CO2

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5
Q

What is slaked lime?

A

calcium hydroxide

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6
Q

How is calcium hydroxide made?

A

made by adding a small amount of water slowly to calcium oxide

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7
Q

What is the chemical equation for the manufacture of slaked lime?

A

CaO + H2O → Ca(OH)2

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8
Q

What is limewater?

A

Limewater is a solution of calcium hydroxide in water

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9
Q

is limewater acidic or alkaline?

A

alkaline

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10
Q

What is formed when carbon dioxide is added to limewater?

A

The addition of carbon dioxide to calcium hydroxide produces the initial starting material, calcium carbonate

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11
Q

What is the chemical equation for the reaction between carbon dioxide and limewater?

A

CO2 + Ca(OH)2 → CaCO3 + H2O

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12
Q

Why does limewater turn cloudy upon contact with carbon dioxide?

A

turns cloudy due to calcium carbonate forming, which is an insoluble precipitate and the solution turns milky? cloudy

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13
Q

What do these 3 reactions constitute?

A

The limestone cycle

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14
Q

What does limestone help the manufacture of? 2

A

Limestone (calcium carbonate) is used in the manufacture of iron and cement

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15
Q

How does limestone help in the production of iron?

A

In the production of iron, limestone is added to the blast furnace where it decomposes to form lime (CaO) and carbon dioxide

The lime reacts with silica impurities to form calcium silicate, which floats to the top of the molten iron and is removed:

CaO + SiO2 → CaSiO3

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16
Q
  1. How is cement manufactured?

manufacture of cement

A

Cement is manufactured by heating a mixture of powdered limestone and clay in a rotary kiln

17
Q
  1. What is added to the rotary kiln?

manufacture of cement

A

Once heated, calcium sulfate and water are added which produce cement

18
Q
  1. What is cement? What is it made of?

manufacture of cement

A

Cement is a hardened, interlocked structure of calcium aluminate (Ca(AlO2)2 and calcium silicate (CaSiO3)

19
Q

How can calcium carbonate be used?

A

CaCO3 is also used in treating excess acidity in soils and lakes where it is often preferred to lime because it does not make the water in the soil alkaline

20
Q

how can lime be used?

A

Lime (calcium oxide) is used in lime mortar and in flue-gas desulfurisation

21
Q

What does flue gas desulfurisation involve?

A

Flue-gas desulfurization involves spraying acidic sulfur dioxide emissions with jets of slaked lime to reduce pollution by neutralising these gases before they leave the factory chimneys

22
Q

What may happen if too much lime is added when treating acidic soils?

A

It is also used in treating excess acidity in soils and lakes. If excess lime is used, however, the water in the soil may become too alkaline

23
Q

How can slaked lime be used? 2

A

Slaked lime (calcium hydroxide) is used in treating acidic soils and neutralising acidic industrial wasted products