1.4 Bonding Flashcards

1
Q

what is ionic bonding

A

an electrostatic attraction between oppositley charged ions

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2
Q

what is an ionic crystal

A

-lattice of ions
-held together by electrostatic attraction of oppositely charged ions

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3
Q

Why do ionic compounds have high melting points

A
  • strong electrostatic attraction between oppositely charged ions require lots of energy to break
  • therefore they have high melting points
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4
Q

What is a covalent bond

A
  • involves the sharing of electron pairs between atoms
  • forms due to electrostatic attraction between the positive nuclei of the bonded atoms and the negative electrons which are between the two nuclei
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5
Q
A
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6
Q

What is ionic bonding found between

A

non-metal + metal

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7
Q

What is ionic bonding found between

A

non-metal + metal

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8
Q

What is covalent bonding found between

A

non metal + non-metal

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9
Q

What is metallic bonding found between

A

metal + metal

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10
Q

why are metals conductive?

A

due to the sea of delocalised electrons

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11
Q

what is the point of chemical bonding

A

chemical bonding occurs for atoms to get a stable electron configuration

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12
Q

define a chemical bond

A

a chemical bond is an electrostatic force of attraction between elements with a positive and negative charge

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13
Q

giant covalent

A

high melting point

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14
Q

simple covalent

A

low melting point (small molecules)

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15
Q

how to drawn ionic bonding

A

dot and cross diagram

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16
Q

how to draw covalent bonding

A

dot and cross diagram but with overlapping orbital

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17
Q

Why is a covalent bond formed

A

By sharing a pair of electrons (each electron donates an electron each to the shared pair)

18
Q

What is bond polarity

A

separation of electric charge along a bond.
polar bonds occur when electrons in the bond are not shared equally

19
Q
A
20
Q

Electronegativity

A

The ability of an atom to attract the shared pair of electrons (electron density) in a covalent bond towards itself

21
Q

Factors that affect Electronegativity

A
  • nuclear charge
  • atomic radius
  • shielding
22
Q

Electronegativity trend across a group:

A
  • increases across a group
23
Q

Electronegativity down a period

A
  • Decreases down a period
24
Q

What properties cause a dipole bond to form

A

The electronegativities of the elements are different

25
Q

What bond occurs when there is no dipole?

A

pure covalent

26
Q

what bond occurs when there is a dipole?

A

polar covalent

27
Q

where will delta- go?

A

The more electronegative

28
Q

where will delta+ go?

A

The least electronegative

29
Q

What is a temporary dipole

A

an uneven distribution of electrons, making one half of the molecule more negatively charged than the other

30
Q

What is a permanent dipole

A
  • when 2 covalently bonded atoms have different electronegativities, forming a polar bond. This causes a delta- and delta+ region
31
Q

What is an induced dipole

A

created when electron distribution around a molecule is influenced by a charged particle

32
Q

Compare the bond character in a covalent bond and ionic bond

A

covalent bond - electrons equally shared between atoms, no overall charge

ionic bond - complete transfer of electrons between atoms to produce ions will full charges

33
Q

what type of intermolecular forces are there

A
  • Temporary dipole
  • Permanent dipole
  • Hydrogen bonding
34
Q
A
35
Q

what is a dipole

A

A molecule with 2 different charges

36
Q

hydrogen bonding

A

permanent dipole-dipole but occurs when a H is bonded to:
- fluorine
- oxygen
- nitrogen

37
Q

Strength of intermolecular forces:

A

h-bonding > permanent dipole-dipole > van der Waals’

this means that H-bonding has a higher boiling point.

38
Q

what is a lone pair of electrons

A

a pair of electrons in a valence shell that are no involved in bonding

39
Q

What happens to boiling points across a group

A

they increase

40
Q

why do boiling point increase across a group

A
  • number of electron increase
  • strength of intermolecular forces increase (more electrons = greater strength)
41
Q

why are boiling points of Group 4 hydrides lower than hydrides of Groups 5, 6 and 7

A

5, 6 and 7 are more likely to have dipole-dipole