1.2 Amount Of Substance Part 1 Flashcards
Define relative atomic mass (Ar)
The weighted average of all the isotopes relative to 1/12th the mass of carbon-12
How do you calculate the Ar? (Relative atomic mass)
(Mass x abundance of each isotope) / total abundance
Define the relative molecular mass
The mass of a molecule of the compound relative to 1/12th of the mass of an atom of carbon 12
Define relative formula mass
The mass of one formula unit of an ionic compound relative to 1/12th of the mass of an atom of carbon-12
Define a mole
The amount of substance that contains as many particles as there are in exactly 12g of carbon-12
The mass of one mole of a substance is equal to what?
Its Mr in grams
What is molar mass measured in?
gmol-1
How many mole equations are there?
4
What is the first mole equation
Mol = mass (g) / Mr
What is the second mole equation?
Mol = concentration (moldm-3) x volume (dm3)
What is the 3rd mole calculation?
Mol = number of particles / Avogadro’s constant
What is the fourth mole equation?
Mol = P(Pa)xV(m3) / R(8.314)xT(K)
P= pressure V= volume T= temp
Calculate the number of moles in 36g of water
2.0 (mass/mr)
Calculate the mass of 5 moles of methane
80g (MrxMol)
Calculate the number of moles in 50 mg of iodine
2.0 x10(-4) (mass/mr)
Calculate the number of moles of ammonia in 34kg
2000mol (mass/Mr)
Calculate the number of moles of calcium carbonate in 2 tonnes
20000mol (mass/Mr)
Calculate the number of carbon atoms in 100mg of diamond
5.02 x10(2)
How many grams of magnesium contains 1.204 x10(24) atoms?
48.6g
How do you convert cm3 to dm3?
x10(-3)
How do you convert from dm3 to cm3?
x10(3)
Calculate the number of moles hydrochloric acid in 25.0 cm3 of a 0.200 moldm(-3) solution
5.00 x10(-3)
Calculate the volume of 0.050 moldm(-3) NaOH which contains 0.020 moles
0.40 dm3
When doing mole calculation what MUST mass be in?
grams
When doing mole calculations what MUST volume be in?
dm3
Calculate the mass of sodium chloride required to make 50cm3 of a 0.25 moldm(-3) solution
0.73g
8.00g of NaOH is dissolved in 250cm(3) of solution. Calculate its concentration in moldm(-3)
0.800 moldm(-3)
What are the assumptions made for the ideal gas equation?
- There are no intermolecular forces between the molecules
* The volume occupied by the molecules themselves is entirely negligible relative to the volume of the container
Convert 25 degrees to kelvin
298K
Convert -40 degrees to Kelvin
233K
How do you change degrees to kelvin?
Add on 273
What volume, in cm3, is occupied by 0.25mol of a gas at a pressure of 150 kPa and a temperature of 20 degrees Celsius?
4.1 x103 (ideal gas equation)
At 450K an 800mg sample of helium occupies a glass bulb of volume in 10.0dm3. Calculate the pressure, in kPa, exerted by the helium under these conditions
74.8 kPa (ideal gas equation)
0.7100g of a gas when contained in a vessel of volume 8.200 x 102 cm3 exerted a pressure of 50.65 kPa at a temperature of 227.0degrees Celsius. Calculate the moles and then the Mr of the gas. Suggest it’s identity.
Mr - 71.06
Cl2
What is the unit for density (chemistry)
gcm(-3)
50 cm3 of ethanol has a mass of 38g. Calculate its density.
0.76 gcm(-3)
There are 550mol of pure platinum in a bar measuring 10cm by 10cm by 50cm. What is the density of platinum in kgdm(-3)
21kgdm(-3)
A sample of sodium chloride, density 2.16 gcm(-3), has a volume of 5 x 10(-2) cm3. Calculate the number of ions in the sample.
3.69 x(-3)
Define empirical formula
The simplest whole number ratio of atoms of each element present in a molecule
Define molecular formula
The actual number of atoms of each element present in a molecule
Find the empirical formula of an oxide of sulfur formed when 3.2g sulfur combines with 3.2g of oxygen
SO2
How do you calculate empirical formula?
- Work out the number of moles
* Divide by the smallest number
Find the empirical formula of phosphorus formed when 1.24g phosphorus combines with 0.96 of oxygen.
P2O3
Find the empirical formula of an oxide of lead formed when 6.2g lead burns in oxygen to give 6.84g of the oxide
Pb3O4
Find the empirical formula of s compound containing the following percentages mass:
Na- 32.4%
S- 22.5%
O- 45.1%
Na2SO4
What do you need to calculate the molecular formula?
- the empirical formula
* the Mr
A compound of Mr 188 has the following percentage composition by mass:
C 12.78%, H 2.13%, Br 85.2%
Calculate the molecular formula
Empirical - CH2Br
Molecular - C2H4Br2