10.2 Flashcards
1
Q
what does catenation mean?
A
the ability to form bonds between atoms of the same element
2
Q
What can heterolytic fission produce?
A
ions
3
Q
what do the half arrows represent?
A
single electrons
4
Q
Why are alkanes unreactive?
A
- the carbon-hydrogen bonds are considered to be non-polar (or weakly polar) bonds bc of the small difference in electronegativity
- the c-c & c-h bonds are relatively strong covalent bonds -> this means that the alkanes are kinetically stable unless applied w enough energy to overcome the activation energy for the reaction
5
Q
what determines the type of combustion?
A
- the amount of oxygen present
- alkanes undergo complete combustion in the presence of excess oxygen
6
Q
what is homolytic fission?
A
when 2 electrons of a covalent bond are evenly split between 2 atoms resulting in 2 free radicals that have a single reaction
7
Q
what are the 3 steps of free-radical substitution?
A
- initiation
- propagation
- termination