1. Stoichiometric Relationships Flashcards

1
Q

What is a mole?

A

A unit that measures the amount of substance.

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2
Q

How many elementary entities are in one mole?

A

6.02 x 10^23

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3
Q

What is an elementary entity?

A

Any particle. Eg: an atom, molecule or ion.

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4
Q

N= ?

A

n x NA

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5
Q

What is the molar mass?

A

The mass of one mole of an element/ compound.

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6
Q

n= ?

A

m/ M

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7
Q

N/ NA = ?

A

m/ M

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8
Q

Define ‘molecular formula’.

A

The actual number of atoms in a compound.

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9
Q

Define ‘empirical formula’.

A

The simplest whole number ratio of atoms in a compound.

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10
Q

What are the units for molar mass?

A

gmol-1

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11
Q

How do you find the limiting reactant?

A

Divide the given moles by the stochiometric coefficient.

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12
Q

Define ‘theoretical yield’.

A

The mass of product formed if reactants react completely, according to molar ratios.

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13
Q

Define ‘actual yield’.

A

The mass of product obtained in a reaction.

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14
Q

Define ‘percentage yield.’

A

A measure of the reaction efficiency.

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15
Q

What is the formula for percentage yield?

A

(Actual yield/ theoretical yield) x100

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16
Q

Give 5 reasons why a reaction may not be 100% efficient.

A
  • Transfer losses (left in glassware)
  • Side reactions.
  • Reaction reaches equilibrium.
  • Reactants may be impure.
  • Reaction is slow.
17
Q

Define ‘atom economy’.

A

A measure of efficiency that assesses how many reactant atoms are transformed to the desired products.

18
Q

What is the formula for atom economy?

A

Atom economy= (Mr of desired product/ sum of Mr of all products) x100

19
Q

Give 2 ways that atom economy can be improved.

A
  • Undesired products can be recycled within a chemical plant.
  • Undesired products can be bought by another company for another process.
20
Q

For gases, moles= ?

A

volume / molar volume

21
Q

State Avogadro’s Law.

A

The volume of gas is directionally proportional to the number of moles.

22
Q

At stp, how much volume does one mole of gas occupy?

A

22.7 dm-3

23
Q

What are the values of standard temperature and pressure?

A

273K and 100KPa

24
Q

What is a homogeneous reaction?

A

A reaction where all of the species are in the same phase.

25
Q

What is a heterogeneous reaction?

A

A reaction where the species are in different phases.

26
Q

Density= ?

A

Mass/ volume

27
Q

State the 5 assumptions of an ideal gas.

A
  • Gas molecules are in a constant, random motion.
  • Molecular collisions are perfectly elastic.
  • The volume occupied by gas molecules is negligible.
  • There are no intermolecular forces.
  • Kinetic energy is directionally proportional to temperature in Kelvin.
28
Q

At which temperatures do real gases act least like ideal gases?

A

At low temperatures, kinetic energy falls. Upon collision, attractive forces form and collisions are not elastic.

29
Q

At which pressures do real gases act least like ideal gases?

A

At high pressures, there are more molecules in the space so the volume of particles becomes more significant.

30
Q

In which conditions does a gas behave like an ideal gas?

A

High temperatures and low pressures.

31
Q

(P1V1) / T1= ?

A

(P2V2) / T2

32
Q

PV= ?

A

nRT

33
Q

What is the formula for percentage uncertainty?

A

(Total uncertainty/ measured uncertainty) x100

34
Q

What are the units for Avogadro’s constant?

A

mol-1

35
Q

concentration= ?

A

moles x volume

36
Q

How many dm3 is 1cm3

A

0.001

37
Q

What is the formula for ppm?

A

Ppm= (mass/ total mass of solution) x 1,000,000

38
Q

C1V1= ?

A

C2V2