1- Chapter 14 - Temperature Flashcards
Average Molecular kinetic energy?
kT
Photon Energy=
hf
What range of energyies do reactions happen and why
- 15-30kT = energy needed
- as kT was average energy and very few molecules need the erergy for a resonable rate.
(E/kT is between 15 and 30)
n/n0=
(n is number with energy more, n0 is total)
(number of particles in states different by energy E)
e-E/kT
Pressure difference in a fluid =
hρg
Whats the origin of the boltzman factor?
the progressivly smaller probability of repeativly gaining extra energy from other particles.
What is activation energy?
The energy needed by to break bonds in a substance before a reaction can take place.
What is the boltzman factor?
e-E/kT
Proportional to rate of reaction
WHat happens when E>>kT
Temperature is low, but a change in temperature will gratly increase the boltzman factor.