Y2 Thermodynamics (P) Flashcards

1
Q

Enthalpy change

A
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2
Q

Enthalpy of formation

A
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3
Q

Enthalpy of combustion

A
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4
Q

Enthalpy of formation equation

A
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5
Q

Enthalpy of combustion equation

A
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6
Q

First and second ionisation Enthalpy

A
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7
Q

First and second electron affinity

A
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8
Q

Hess’s Law

A
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9
Q

Sublimation

A

State change from solid to gas

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10
Q

Constructing born Haber cycles

A
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11
Q

Short born haber cycles

A
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12
Q

Lattice Enthalpy comparisons

A
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13
Q

Lattice dissociation Enthalpy

A
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14
Q

Lattice formation Enthalpy

A
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15
Q

Atomisation Enthalpy

A
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16
Q

Electron affinity general

A
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17
Q

Born haber cycle example and order

18
Q

Enthalpy of solution

19
Q

Enthalpy of hydration

20
Q

Short born haber cycles formula

A

LE (lattice Enthalpy of)

21
Q

Assumptions of the perfect ionic model

22
Q

Why Perfect ionic model most often does not hold true

23
Q

PIM cations are

A

Polarising ( smaller means greater charge density)

24
Q

PIM anions are

A

Polarisable ( larger the size means the electron cloud is distorted more easily )

25
When does PIM not hold true?
26
What do things tend to in chemistry
Entropy (disorder)
27
The more disordered a substance
The greater the entropy value
28
Entropy change as temp increases
Increases as particles gain more energy and move further apart (less ordered)
29
Entropy
30
With entropy questions always remember to
Divide by 1000 as units are J/K/mol but need Kj/K/mol
31
All spontaneous reactions have
Positive entropy value, disorder increases
32
Spontaneity
33
When is delta G feasible?
When it is less than zero
34
To find temp reaction becomes feasible
Set delta G to zero
35
Gibbs free energy equation
36
Graphing Gibbs free energy equation
37
On the graph when is it feasible (possibilities)
38
Enthalpy of fusion
39
Enthalpy of Vapourisation
40
Enthalpy of hydrogenation