Y2 Thermodynamics (P) Flashcards

1
Q

Enthalpy change

A
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2
Q

Enthalpy of formation

A
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3
Q

Enthalpy of combustion

A
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4
Q

Enthalpy of formation equation

A
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5
Q

Enthalpy of combustion equation

A
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6
Q

First and second ionisation Enthalpy

A
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7
Q

First and second electron affinity

A
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8
Q

Hess’s Law

A
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9
Q

Sublimation

A

State change from solid to gas

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10
Q

Constructing born Haber cycles

A
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11
Q

Short born haber cycles

A
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12
Q

Lattice Enthalpy comparisons

A
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13
Q

Lattice dissociation Enthalpy

A
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14
Q

Lattice formation Enthalpy

A
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15
Q

Atomisation Enthalpy

A
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16
Q

Electron affinity general

A
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17
Q

Born haber cycle example and order

A
18
Q

Enthalpy of solution

A
19
Q

Enthalpy of hydration

A
20
Q

Short born haber cycles formula

A

LE (lattice Enthalpy of)

21
Q

Assumptions of the perfect ionic model

A
22
Q

Why Perfect ionic model most often does not hold true

A
23
Q

PIM cations are

A

Polarising ( smaller means greater charge density)

24
Q

PIM anions are

A

Polarisable ( larger the size means the electron cloud is distorted more easily )

25
Q

When does PIM not hold true?

A
26
Q

What do things tend to in chemistry

A

Entropy (disorder)

27
Q

The more disordered a substance

A

The greater the entropy value

28
Q

Entropy change as temp increases

A

Increases as particles gain more energy and move further apart (less ordered)

29
Q

Entropy

A
30
Q

With entropy questions always remember to

A

Divide by 1000 as units are J/K/mol but need Kj/K/mol

31
Q

All spontaneous reactions have

A

Positive entropy value, disorder increases

32
Q

Spontaneity

A
33
Q

When is delta G feasible?

A

When it is less than zero

34
Q

To find temp reaction becomes feasible

A

Set delta G to zero

35
Q

Gibbs free energy equation

A
36
Q

Graphing Gibbs free energy equation

A
37
Q

On the graph when is it feasible (possibilities)

A
38
Q

Enthalpy of fusion

A
39
Q

Enthalpy of Vapourisation

A
40
Q

Enthalpy of hydrogenation

A