Y2 Thermodynamics (P) Flashcards
Enthalpy change
Enthalpy of formation
Enthalpy of combustion
Enthalpy of formation equation
Enthalpy of combustion equation
First and second ionisation Enthalpy
First and second electron affinity
Hess’s Law
Sublimation
State change from solid to gas
Constructing born Haber cycles
Short born haber cycles
Lattice Enthalpy comparisons
Lattice dissociation Enthalpy
Lattice formation Enthalpy
Atomisation Enthalpy
Electron affinity general
Born haber cycle example and order
Enthalpy of solution
Enthalpy of hydration
Short born haber cycles formula
LE (lattice Enthalpy of)
Assumptions of the perfect ionic model
Why Perfect ionic model most often does not hold true
PIM cations are
Polarising ( smaller means greater charge density)
PIM anions are
Polarisable ( larger the size means the electron cloud is distorted more easily )
When does PIM not hold true?
What do things tend to in chemistry
Entropy (disorder)
The more disordered a substance
The greater the entropy value
Entropy change as temp increases
Increases as particles gain more energy and move further apart (less ordered)
Entropy
With entropy questions always remember to
Divide by 1000 as units are J/K/mol but need Kj/K/mol
All spontaneous reactions have
Positive entropy value, disorder increases
Spontaneity
When is delta G feasible?
When it is less than zero
To find temp reaction becomes feasible
Set delta G to zero
Gibbs free energy equation
Graphing Gibbs free energy equation
On the graph when is it feasible (possibilities)
Enthalpy of fusion
Enthalpy of Vapourisation
Enthalpy of hydrogenation