WM Flashcards
General formula of alcohols
ROH
General formula of aldehydes
RCHO
General formula of ketones
RCOR
General formula of carboxylic acids
RCOOH
General formula of acid anhydrides
(RCO)2O
General formula of esters
RCOOR
General formula of ethers
ROR
Structural formula of aldehydes
O // R--C \ H
Structural formula of ketones
R \ C == O / R
Structural formula of carboxylic acids
O // R -- C \ OH
Structural formula of acid anhydrides
R – C – O – C – R
|| ||
O O
Structural formula of esters
O
||
R – C – O – R
Structural formula of ethers
R – O – R
Suffix for alcohols
-ol
Suffix for aldehydes
-al
Suffix for ketones
-one
Suffix for carboxylic acids
-oic acid
Suffix for acid anhydrides
-oic anhydride
Suffix for esters
-oate
Suffix for ethers
-oxy-
What can primary alcohols be oxidised in to?
Aldehydes and then carboxylic acids
What can secondary alcohols be oxidised to?
Ketones
What can tertiary alcohols be oxidised to?
Nothing. They can’t be oxidised
How do you oxidise primary alcohols?
1) Gently heat ethanol with potassium(VI) diachromate solution and sulfuric acid in a flask to produce ethanal.
2) As theres lots of oxidising agent you need to remove aldehyde as soon as its formed by using a distillation apparatus.
3) To produce a carboxylic acid the alcohol has to vigorously oxidised by heating under reflux.
What forms when you dehydrate an alcohol?
An alkene.
What catalyst is used to oxidise ethanol?
Potassium(VI) diachromate solution
What catalyst is used to dehydrate ethanol?
Pumice stone or aluminium oxide (Al2O3)
How to dehydrate ethanol?
- Ethanol vapour passed over hot catalyst (pumice stone or aluminium oxide).
OR - Reflux ethanol with excess concentrated sulfuric acid at 170. Ethene produced is collected over water.
What forms when alcohols react with carboxylic acids?
Esters
What forms when alcohols react with acid anhydrides?
Esters
How to test for phenols?
Use iron(II) chloride solution. Turn purple
What forms when acid anhydrides react with phenols?
Esters
Are phenols a strong or weak acid?
Weak
Do phenols and carbonate solutions react? Why?
No as sodium carbonate isn’t a strong enough base to remove hydrogen ion.