Whitening Flashcards
History of Tooth Whitening
- 1980s: innovation
- 1990s: emerging
- 2000s: commodity (look younger, improve self-confidence, smile more)
Stains/Discolorations
- important to identify causes of stain prior to initiating tx
- certain stain types are more response to “bleaching”
- two categories: extrinsic and intrinsic
Extrinsic stain
- occur after tooth eruption
- caused by tobacco, food, drink, metals, alloys
- caused by chromogens accumulating on external surface of tooth (incorporated into dental pellicle)
- most can be removed via routine prophylaxis
- darken over time, become more difficult to remove when left unaddressed
- HIGHLY RESPONSIVE to whitening
Intrinsic Stains
- can occur during development/throughout life
- “internal” stains
- CAN’T be removed via prophy
- can be reduced
* *YELLOW stain: high typical responses
* *BLUE-GRAY stain: slow and low typical responses
* *BROWN stain: moderate typical responses
What causes intrinsic stains?
- age: enamel thinning, dentinal thickening, secondary dentin formation
- genetics/systemic conditions/developmental disorders: amelogenesis imperfecta, dentinogenesis imperfecta
- antibiotics: tetracycline
- fluoride: >1-2 ppm
- trauma
Inactive Ingredients of Whitening
- thickening agents
- carrier
- surfactant/detergent
- preservatives
- flavoring
Thickening agents
- increase viscosity
- increases oxygen-releasing time=increased activity (4X)
- polyacrylic acid polymer (carboxypolymethylene=Carbopol)
Carrier
- maintains moisture
2. glycerine and/or propylene glycol
Surfactant/detergent
- increases effectiveness by acting as surface-wetting agent
- prevent reattachment of chromogens
Preservatives
- prevent bacterial growth
2. sodium benzoate or propylparaben
Flavoring
- increase patient acceptance
2. flavors/sweeteners
Active ingredients of whitening
- carbadmide peroxide
OR
- hydrogen peroxide
Carbamide Peroxide
hydrogen peroxide and urea
Hydrogen Peroxide
absorbed into enamel and dentin
Comparing hydrogen peroxide to carbamide peroxide
10% carbamide=3% hydrogen peroxide
35% carbamide=12% hydrogen peroxide
How is carbamide peroxide different from hydrogen peroxide?
- hydrogen peroxide=very unstable
2. hydrogen peroxide penetrates the tooth more quickly than carbamide peroxide
How does whitening work?
- basic mechanism is same for both active ingredients
- tooth is semi-permeable membrane
- peroxide penetrates to the pulp in 5 to 15 minutes
* *bleach passes from incisal edge to apex of tooth - color change is same at pulp as at dentin-enamel junction
How does whitening work?
Ex: hydrogen peroxide
- H2O2 is unstable and reactive
- H2O2 breaks down in water
- oxygen free radicals look for something to attach to
- most easily attacked are double carbon bonds that are the source of most stains
How it works: oxidation-reduction reaction
- O2 molecules enters the enamel and dentinal tubules
- attracted to double bonds of stain molecules
- double bonds are broken down into single bonds (alters internal colors)
- changes molecules to become translucent
The organic colors are mostly __
- aldehydes
2. esters