WEEK8 Flashcards
What is one way to determine if a reaction is going from order to disorder?(1)
By the number of moles. If there are more moles of the product than the reactants
What is one way to determine if a reaction is going from order to disorder?(2)
Increasing your temperature. Higher the temperature the more energy the molecules have because of this this they jump around more
What is one way to determine if a reaction is going from order to disorder?(3)
Change of states. Solid to Liquid to Gas
What is one way to determine if a reaction is going from order to disorder?(4)
If solid dissolves in a liquid. Breaks into cations and anions
What is one way to determine if a reaction is going from order to disorder?(5)
Gas dissolved in liquid to gas dissolved in atmosphere
What is the direction of a spontaneous process?
Spontaneous processes tend to proceed from states of low probability to higher probability
What quantity does thermodynamics define?
Entropy(S)=kInW
W=# of ways of dispersing a fixed amount of energy
K=1.380.65 x 10^-23JK^-1
What is the most practical way to determine (S)?
Change in (S)J mol^-1 K^-1=S()final-(S)initial
what does the change in S tell us?
That any event accompanied by an increase in entropy of an isolated system has a tendency to occur spontaneously
What factors affect entropy?
- Volume
- Temperature
- Physical state
- Number of particles
What is the equation for the relationship between the entropy of the surroundings enthalpy of the system?
Change in Ssytem+change in -Hof system/T
When is a reaction exothermic?
when heat is transferred from the system to its surroundings (delta H is negative)