Week 9 Flashcards
What is an ion
If protons don’t equal the amount of electrons then the atom is charged
Isotopes
If the number of neutrons vary then it’s an isotope
Periodic table
Elements are arranged in their increasing atomic number (z) / proton number
How to get atomic weight
Times the protons by the elements abundance in the atmosphere E.G
12 x 0.989 = 11.868
13 x 0.011 = 0.143
11.868 + 0.143 = 12.011 = carbons atomic weight
Ions
If electrons are gained or lost atoms become charged
+ve = cations
-ve = anions
Ionic Compounds
When a non-metal reacts with a metal electron transfer occurs. Electrostatic attraction between +ve and -ve happens E.g. Na+ and Cl- = NaCl
Charges balance to produce a neutral compound E.g Ca2+ and 2Cl- = CaCl2
They tend to have high melting points and conduct electricity when a liquid
Molecular compounds
Covalent compounds - atoms share electrons
Interactions within a molecule are strong but interactions between molecules are weak and they have low melting and boiling points
Empirical formula
Gives elements the smallest possible ratio, usually used for ionic compounds
To obtain this divide the molecular formula by its lowest denominator
E.g. C2H6 ethane = CH3
Divided by 2
Single and double bonds
If 2 electrons are shared between a pair of atoms it’s a single bond
If 4 electrons are shared it’s a double bond
Double bonds are stronger and short than single bonds
Single bonds can rotate whereas double bonds and even triple bonds can’t
Isomers
Different molecules that have the same formula but different connectivity
Gives them different reactivity and properties
Structural isomers
Cis/trans isomers
Molecular shape
Molecules have a 3D shape
Tetrahedral methane:
Carbon at the centre of tetrahedron
Hydrogen at vertices
Different from square planar:
Nickel at centre of square
CO at vertices of square
Planar
Octahedral:
SF6
S in the centre of the octahedron
F at the vertices
Planar:
Flat
All the atoms are in the same space
E.g. Benzene
Sterics and electronics
Molecular shape is a product of steric and electronic effects
Sterics:
Atoms occupy space
Atoms bonded to the same central atom will want to be as far away as possible
Electronics:
Electrons interact with each other - like charges repel
Lots of electrons can interact in lots of different ways - each will have a different energy