Week 4 Flashcards
fats
- needed for health
- provides mouth feel
- fat is made of C, H, and O like carbs and proteins
lipids
a family of organic compounds that are not soluble in water
what do lipids include
- triglycerides (fats and oils)
- phospholipids (lecithin)
- sterols (cholesterol)
triglycerides
make up ~95% of all lipids in foods and the human body
triglycerides (fats)
lipids that are solid at room temp
triglycerides (oils)
lipids that are liquid at room temp
functions of fat
- bodys chief storage form of excess food energy - survival during feast-or-famine
- provides much of the energy needed for the bodys work
- fat on healthy-weight person is more than enough for entire marathon
- energy when a person becomes ill and stops eating
fat cells (adipose cells)
specialized for fat storage
- they expand and multiply (we store more)
adipose (fat) tissue
is an metabolically active tissue
- secretes hormones and produces enzymes that influence food intake and affect the body’s use of nutrients
why can more fat be stored than glycogen?
fats pack tightly together without water allowing far more fat to be stored compared to glycogen
- far more efficient storage form
other functions of fat
- shock absorber
- thermoregulation
- cell membrane
- aids in absorption of some phytochemicals
shock absorber
pads of fat surround vital internal organs
thermoregulation
fat pads under the skin insulate the body from temperature extremes
cell membranes
lipids are a component of cell membrane
needed nutrients
fat-soluble vitamins (A, D, E, and K) are found mainly in foods that contain fat
essential fatty acids
serve as raw materials for other compounds (eicosanoids)
fats and pleasure
- people naturally like high-fat foods
- fats carry many compounds that give foods pleasant aromas and flavours
- fat makes meat and baked goods tender
value of fats
the energy density of fats makes foods rich in fat valuable in some situations
- a hunter or hiker = long distances or very cold weather
- potentially unneeded calories if sedentary
satiety
feeling of fullness or satisfaction that people experience AFTER meals
satiation
feeling of fullness WHILE eating
fat and satiety
fat contributes to satiety
- fat in foods triggers a series of physiological events that slow the emptying of stomach and promote satiety
- fat in the SI signals release of CCK
3 classes of lipids
- triglycerides
- phospholipids
- sterol
triglyceride
3 fatty acids + glycerol
fatty acids
organic acids composed of carbon chains of various lengths
- each has an acid end and hydrogens attached to all the carbon atoms of the chain
- differ on the basis of length and degree of saturation (even with the same triglyceride)
glycerol
serves as the backbone for triglycerides
0 double bonds
saturated fat
1 double bond
monounsaturated fat
more than 1 double bond
polyunsaturated bond
does where the double bond occurs matter?
YES
1. 1st carbon bond on third carbon = omega-3
2. 1st carbon bond on sixth carbon = omega-6
what does the degree of saturation affect?
melting temperature
1. more UNSATURATED the fatty acids = the more LIQUID the fat is at room temperature (ex. sunflower oil)
2. the more SATURATED the fatty acids = the FIRMER the fat is at room temperature (ex. lard)
chain length - long fatty acids
most common in the diet
- 12-24 carbons
- found in meat, seafood, vegetable oils
chain length - medium + short fatty acids
medium: 6-10 carbons
short: less than 6 carbons
- found in mainly dairy products and coconut oil
what does decreased carbon chain length mean?
reduced firmness
example of chain length and firmness
saturated plant oils such as cocoa butter and palm oil are softer than animal fats due to their shorter chain length
health recommendations and fats
- limit saturated fats and limiting/avoiding trans fats
- using monounsaturated fats or polyunsaturated fats and instead
***the harder the fat= the poorer the choice (lard=bad)
vegetable oils and fish oils
- most are rich in polyunsaturated fatty acids (safflower, sunflower , corn oil)
- some vegetable oils are rich in monounsaturated fatty acids (olive oil)
what fats are the most saturated
animal and tropical fats
1. fatty meats: over 1/3 of fat in most meats is saturated
2. whole-milk products: over 1/2 fat in whole milk and other high-fat dairy products, is saturated
3. coconut and palm oils: mostly used in commercially prepared foods
why should you switch monounsaturated or polyunsaturated fats instead of saturated and trans fats?
reduce CVD
olive oil
- rich in monounsaturated fatty acids
- offers a degree of protection against heart disease when used in place of other fats (mediterranean regions)
dark-coloured olive oils
deliver more phytochemicals - less processed
what does “light” on olive oil mean?
means color, not nutritional value
canola oil
- rich in both monounsaturated and polyunsaturated fatty acids
- lowest in saturated fat
hydrogenation
a chemical process by which hydrogens are added to monounsaturated or polyunsaturated fatty acids to reduce the number of double bonds, making the fats more saturated (solid) and more resistant to oxidation
disadvantage and advantage of hydrogenation
disadvantage: bad for us
advantage: good for food industry = makes them creamy and last longer
how are trans-fatty acids formed?
- fat is generally partially hydrogenated but some double bonds remain
- double bonds change from cis to the trans formation
***polyunsaturated fat is rarely hydrogenated completely
health claim- disease reduction in fat
a healthy diet low in saturated and trans fats may reduce risk of heart disease
advantages of hydrogenation?
- protects against oxidation by making polyunsaturated fats more saturated (commercial benefit=increased shelf life)
- alters texture of food making liquid vegetable oils more solid (CB= improves food texture)
- hydrogenated oils has a higher smoke point = more stable in high cooking temps
what does less double bonds mean?
food lasts longer
alternatives to hydrogenation
- add BHA and BHT to react with O2 before it can do damage
- keep refrigerated (help last longer)
partially hydrogenated oils (PHOs)
banned sept 17, 2018
phospholipids
2 fatty acids + glycerol + a phosphorus-containing molecule
- fatty acid is soluble in fat and phosphorus is soluble in water
***phospholipids are emulsifiers
emulsifier
a substance that mixes both fat and water and disperses the fat in the water, forming an emulsion
ex. oil and vinegar dressing vs mayonnaise (has lecithin)
lecithin and other phospholipids
play key roles in structure of cell membranes
lecithin supplements
have no special ability to promote health
- body can make all that it needs
- are a fat so provide kcal: digested (lecithinase)
- lecithin is found in eggs and peanuts
sterols
large molecules consisting of interconnected rings of carbon atoms with side chains of carbon, hydrogen and oxygen
- present in foods derived from both plants and animals
cholesterol
only food derived from animals contain significant amounts of cholesterol
VEGAN = NO CHOLESTEROL
phytosterols (plant sterols)
plant-derived compounds that have structural similarities to cholesterol
- they lower blood cholesterol by competing with cholesterol for absorption
ex. seeds and nuts
what serves as the precursor for making bile?
cholesterol (a sterol)
bile
- bile is an emulsifier made by liver and store in gallbladder
- does not digest fats, only emulsifying
- emulsifies fats allowing contact with enzymes in watery fluids to split the fatty acids from glycerol backbone for absorption
other sterols
vitamin D and sex hormones (estrogen and progesterone)
sterol (cholesterol)
- component of cell membrane
- can be made by the body - not an essential nutrient
- forms a major part of the plaques that narrow arteries in atherosclerosis
(plaques cause heart attacks and strokes)
where is cholesterol manufactured?
the liver
- makes 800-1500mg/day (endogenous production)
- the body makes more cholesterol (endogenous) than what is eaten (exogenous)
digestion of fats in the mouth
lingual lipase produced by tongue acts on triglycerides with short and medium chain fatty acids
lingual lipase
- plays a major role in infants (breaks down breast milk)
- little important to digestion in adults
digestion of fat in the stomach
- strong and muscular - mix fat with stomach contents
- churning grinds the solid pieces into finer particles and disperses the fat into small droplets
- gastric lipase breaks doen triglycerides
gastric lipase
begins the break down triglycerides
- works best in the acidic environments of the stomach
digestion of fats in the SI
- when fat enters SI, bile is secreted
- bile emulsifies fat particles, mixing them with watery fluid for contact with fat-digesting enzymes secreted by pancreas for digestion
- triglycerides are split into monoglycerides, free fatty acids and glycerol
- these cling together in spheres surrounded by bile
- bile shuttles lipids across mucus layer to absorptive cells of intestinal villi
- these cells extract the lipids
- bile may be absorbed and reused to exit with the feces
what if someones gallbladder has been removed?
- liver still produces bile (small continuous amount in SI)
- they can no longer store bile and release it at mealtime
diet recommendation for those without a gallbladder
lesser fat because they are not able to cope with as much fat at once
percentage of triglycerides absorbed after a meal
up to 98% of triglycerides are absorbed from a meal
smaller products of lipid digestion
glycerol, short and medium chain fatty acids pass directly through the cells of intestinal lining into bloodstream and into liver
larger products of lipid digestion
inside intestinal cells, monoglycerides and long-chain fatty acids are reformed into triglycerides and clustered together with proteins and phospholipids (don’t go directly to bloodstream)
what do larger products of lipid digestion form before going into bloodstream?
they form chylomicrons
chylomicrons
the largest and least dense type of lipoprotein
- acts as a transport vehicle
- travel in the lymph to the bloodstream
- body tissues take triglycerides from chylomicrons in the bloodstream
(ex. muscles, breasts, etc.)