week 2) Macromolecules Flashcards
Carbon
Framework of biological molecules consists primarly of carbon bonded to
- C
- O, N, S, P or H
- can form up to 4 covalent bonds
- hydrocarbons: molecule consisting only of carbon and hydrogen
- nonpolar
- functional groups add chemical properties
functional groups
confer specific chemical properties to biomolecules
Isomers
molecules with the same molecular or empirical formula
Strcutural isomers
groups attached to different carbons
Stereoisomers
differ in how groups attached to a given carbon
Enantiomer
type of stereoisomer
- chiral mirror image molecules that can’t be superimposed
- D sugar and Lamino acids are biological relevant molecules that each have a corresponding enantiomer
Polymer macromolecules
Carbohydrates, nucleid acids, and proetin are polymer macromolecules
Lipids
macromolecules but not polymers
- no subunits (nucleotides, amino acids, sugar) to form a chain
- some lipids. just have hydrocabon chains
Assembly and disassembly of polymers
Dehadration synthesis
- formation of large molecules by the removal of water
- monomemrs are joined to form polymers
Hydrolysis
- breakdown of large molecules by the addition of water
- polymers broken down to monomers
Carbohydrates
- Molecules with 1:2:1 ratio of carbon, hydrogen, oxygen
- Empirical formula (CH2O)n
- C-H covalent bonds hold much energy
- carbohydrates are good energy storage molecules
- ex: starch, glucose
Monosaccharides
simplest carbohydrate
- 6 carbon sugars play important roles in biology
- not only foud in carbohydrates, but also nucleic acids
- glucose C6 H12 O6
- Enzymes that act on different sugars can distinguish structural stereoisomers of this basic 6 carbon skeleton
Disaccharides
- 2 monosaccharides linked together by dehydration synthesis
- used for sugar transport or energy storgar
- ex:
- sucrose(glucose+fructose)
- ## lactose(glucose+galactose)
Polysaccharides
long chains of monosaccharides
- linked through dehydration synthesis
Energy storage
- plants use starch
- Animals use glycogen
Strcutural support
- plants use cellulose
- arthropods and fungi use chitin
Starch and glycogen
starch(glucose polymer) is the primary energy storage polysaccharide in plants
- to produce ATP plants relelase gluco
cellulose
- important polysaccharide
- ## linear chain of several hundreds or thousands of glucose monomers (unbranched)