Week 2 Flashcards
what the rate of separation governed by
mass transfer
what the extent of separation process is limited by
thermodynamic equilibrium
At equilibrium there is ____ net transfer
no
Dalton’s law
sum of partial pressures equals total pressure
Raoult’s law
Vapour pressure of J = mol fraction of A * vapour pressure of pure A
Henry’s law
When the liquid composition is very small. Vapour pressure of J = mol fraction of A * Henry’s constant for A
The result of material balance equations between streams entering & leaving a separation unit
Operating line
Material balance when stream reach equilibrium. Determines the degree of separation
Equilibrium line
Is a separation stage in which equilibrium has been allowed to be achieved
Ideal stage
mixture of two or more components in fluidic states whose proportions cannot be altered or changed by simple distillation
azeotrope
A method used to find the vapour-liquid equilibrium ratios for different substances at different conditions of pressure and temperature
DePriester Charts
Ratio of partial pressure to the mole fraction in the liquid
volatility
ratio of the individual volatilities
relative volatility
indicates that both the vapour and the liquid phases have the exact same composition, at which point no further enrichment can occur in azeotropes
pinch point
Antoine equation
p* = A - (B/T+C)