Week 2 Flashcards

1
Q

what the rate of separation governed by

A

mass transfer

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2
Q

what the extent of separation process is limited by

A

thermodynamic equilibrium

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3
Q

At equilibrium there is ____ net transfer

A

no

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3
Q

Dalton’s law

A

sum of partial pressures equals total pressure

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3
Q

Raoult’s law

A

Vapour pressure of J = mol fraction of A * vapour pressure of pure A

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4
Q

Henry’s law

A

When the liquid composition is very small. Vapour pressure of J = mol fraction of A * Henry’s constant for A

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5
Q

The result of material balance equations between streams entering & leaving a separation unit

A

Operating line

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6
Q

Material balance when stream reach equilibrium. Determines the degree of separation

A

Equilibrium line

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7
Q

Is a separation stage in which equilibrium has been allowed to be achieved

A

Ideal stage

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8
Q

mixture of two or more components in fluidic states whose proportions cannot be altered or changed by simple distillation

A

azeotrope

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9
Q

A method used to find the vapour-liquid equilibrium ratios for different substances at different conditions of pressure and temperature

A

DePriester Charts

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10
Q

Ratio of partial pressure to the mole fraction in the liquid

A

volatility

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11
Q

ratio of the individual volatilities

A

relative volatility

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12
Q

indicates that both the vapour and the liquid phases have the exact same composition, at which point no further enrichment can occur in azeotropes

A

pinch point

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13
Q

Antoine equation

A

p* = A - (B/T+C)

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14
Q

Relative volatility of A

Ratio of the partial pressure to the mole fraction in the liquid

A

Pa/Xa
partial pressure of A/ mole fraction of A

15
Q

Relative volatility of A

Relative volatility of component A to component B

A

Pa * Xb/ Xa *Pb

16
Q

Rapid transfer means the system is ____ from equilibrium

A

far

17
Q

________ transfer means the system is far from equilibrium

A

Rapid

18
Q

Mol fraction A (Xa) Dalton and Raoult’s law

A

P-PA / PA - P*B

19
Q

Henry’s law is used when liquid composition is very ____.

A

small

20
Q

K-value equations

A

yA = Kxa