week 1 Flashcards

1
Q

what is a system in thermodynamic

A

system is a universe defined by a boundary

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2
Q

what is a boundary in thermodynamic

A

this can be an actual or imaginary limitation of an area

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3
Q

what is a control volume in thermodynamic

A

if a boundary is fixed, then it is controlled via ‘control volume’

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4
Q

what is a surrounding in thermodynamic

A

what is outside the actual system

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5
Q

what are the types of systems called (2)

A

open and closed systems

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6
Q

what is an open system?

A

one where mass many enter or leave the system (in this case at the same rate, not gathering more mass)

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7
Q

what is the difference between gas constant and universal gas constant

A

gas constant is depending on the substance

the universal gas constant depends on nature

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8
Q

what is the difference between gas constant and universal gas constant

A

gas constant is depending on the substance

the universal gas constant depends on nature (always constant)

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9
Q

what is molar mass

A

this is mass of a given chemical element or compound divided by the amount of substance

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10
Q

what is the equation for 1st law of thermodynamics (energy transfer into our out of system )

A

Q - W = (Change in) U

heat transfer - work done = change in internal energy

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11
Q

how many independent parameters of state does air have

A

2 independent parameters
pressure and volume or pressure and temperature
temperature and volume and so on…..
different combinations but only 2 can be used to describe the air

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12
Q

the equation to find the perfect gas

A

the equation of state:

pressure = desnity X gas constant X ABS temperature

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13
Q

what is the value and units of universal gas constant

A

8.3J /mol K

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14
Q

what is the gas constant of air

A

287 J/kg·K

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15
Q

what does the air contain?

A

21% oxygen and 79% nitrogen

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16
Q

what is the molar mass of air

A

28.97 g/mol

17
Q

what is entropy

A

measurement of disorder

measure of randomness or irreversibility of the system

18
Q

what does the first law show us

A

it shows us the energy balance equation:

Q - W = change in internal energy

19
Q

what does the second law show us (2)

A

entropy always increases or remains constant

thermal efficacy of any heat engine is always BELOW 100% (engine always produces heat)

20
Q

what does the second law show us (2)

A

entropy always increases or remains constant

thermal efficacy of any heat engine is always BELOW 100% (engine always produces heat)

21
Q

what does the third law show us

A

entropy is zero at zero temperature

22
Q

what does irreversibility mean, from the point of view of the behaviour of the system

A

entropy increases in irreversible processes

23
Q

how many processes does a cycle have

A

each cycle has 2 process as a minimum, mostly 4 but at least 2

24
Q

what thermodynamics processes are there (4)

A

adiabatic - no heat exchange
isobaric - pressure
isochoric - volume
isothermal - temperature

25
Q

isothermal

A

where the system’s temperature is constant

26
Q

isochoric

A

where the system’s volume is constant

27
Q

isobaric

A

where the system’s pressure is constant

28
Q

adiabatic

A

where no heat is exchanged by the system