Week 1 Flashcards
Hydrogen bond
A bond made between a hydrogen molecule (acceptor) and a molecule with high electronegativity like oxygen, fluorine, or nitrogen (donor).
Acceptor
A hydrogen molecule bonded to a highly electronegative molecule which will give the hydrogen a partial positive charge.
Donor
A highly electronegative molecule that has a partial to full negative charge
Lone electron pairs
Lone electron pairs occur when a bond is not formed with another atom. These electrons reside in the valence shell
Dipole (moment)
A dipole moment occurs when a molecule or atom has an area of higher electronegativity as compared to an other area. This uneven sharing of electrons causes a dipole or a direction of stronger electron presence to occur. This makes one end more positive and one end more negative
Dielectric constant (permittivity)
This concept applies to how well a molecule can align itself charge wise if an electric field is added. The ions align themselves in the same direction. Something with high permittivity is better able to align itself in one direct and can conduct currents better
Triple point
This is the point where all three states of matter exist in the same point in time
Equilibrium content
Describes a hygroscopic material or a material that is holding on to moisture where it is also surrounded by air. It is neither gaining nor losing moisture. This depends on the relative humidity and temperature and the material
Tetrahedral
The is a four directional shape of the molecular electron. It is the bonding pattern of water molecules, this allows for equal numbers or donors and acceptors
Hexagonal ice structure
This is the structure that ice creates when it freezes. The tetrahedral lattice structure extends and rotates to for layers of hexagons
Mixture model
This is the model that describes water molecules in that there are bulky clusters of water molecules that have hydrogen bonds similar to that of conventional water or ice and in addition to this, there are more dense species in between the bulky cluster. This theory gives liquid water more density because there are more molecules but the same 85% of hydrogen bonds retained from the frozen state
Interstitial model
The interstitial model is a mixture of the continuum model and the mixture model. This theory describes water as having the same bonds as with ice, with little distortion, but with free un-bonded water molecules filling in the interstitial space
Pressure shift freezing
If you bring food to a specific pressure, (where the pressure is high and the freezing point is depressed fairly significantly), and then you suddenly release that pressure, the freezing point will increase suddenly and the food will be frozen super quickly. This is what happens with freeze drying?
Reverse thawing
With increased pressure, the freezing temperature is decreased. This means if something is held at the same temperature that it was frozen in, but much higher pressure is added, the freezing temperature will go down and the food will actually thaw at the same temperature.
Continuum model
This model describes liquid water density by saying that the bonds that were formed with solid ice are still there, they are just compressed in some areas. The bonds are distorted rather than broken. The corset model