Water-Napper Flashcards

1
Q

General Statements on Water

A
  • most abundant molecule in living systems, approx 70% mass of cell
  • factor in structure of biomolecules
  • water is participant in many biomchemical reactions
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2
Q

Rule of Hydrogen Bonding

A

Anything that can form a hydrogen bond, MUST for a hydrogen bond.

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3
Q

Hydrogen Bonds

A
  • bonds are 1/25 the strength of covalent bonds
  • linear hydrogen bonds are stronger than hydrogen bonds as part of an angle
  • double the length of covalent bonds
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4
Q

Water and Hydrogen Bonding

A
  • Water can accept and donate two hydrogen bonds (because it is a dipole with oxygen being more electronegative)
  • water hydrogen bonds with itself which leads to its high heat of vaporization(the amount of energy needed to vaporize a liquid) and high specific heat capacity (the amount of energy required to raise the temp one degree)
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5
Q

Ice

A

Water as a solid(ice) is an arrangement where each water molecule forms exactly 4 bonds and therefore gives it a lower density than liquid water, making it float

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6
Q

Water as a Solvent

A

water can and will dissolve polar compounds and compounds that can ionize. Water manipulates its charges to insulate what it is breaking down CL- attracts the hydrogen sides of water which facilitates its dissolving

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7
Q

Hydrophilic

A
  • Water loving molecules

- generally polar

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8
Q

Hydrophobic

A
  • water fearing

- generally nonpolar

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9
Q

Solubility of Water

A
  • more nonpolar groups, less soluble something is
  • more polar groups means more soluble
  • hydrogen bonding increases solubility
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10
Q

pH Scale

A
  • body pH is about 7.4

- a difference of one pH is a ten fold difference (ex 7 to 4 is 101010 or 1000 fold difference)

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11
Q

Henderson-Hasselbach Equation

A

pH=pKa+log[A-]/[HA]

-in the equation the weak acid goes on the bottom, conjugate base on the top

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12
Q

Buffers

A
  • Solution that can resist changes in pH with the addition of acid or base
  • Buffers are 1pH unit above, and below pKa values
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