Water-Napper Flashcards
General Statements on Water
- most abundant molecule in living systems, approx 70% mass of cell
- factor in structure of biomolecules
- water is participant in many biomchemical reactions
Rule of Hydrogen Bonding
Anything that can form a hydrogen bond, MUST for a hydrogen bond.
Hydrogen Bonds
- bonds are 1/25 the strength of covalent bonds
- linear hydrogen bonds are stronger than hydrogen bonds as part of an angle
- double the length of covalent bonds
Water and Hydrogen Bonding
- Water can accept and donate two hydrogen bonds (because it is a dipole with oxygen being more electronegative)
- water hydrogen bonds with itself which leads to its high heat of vaporization(the amount of energy needed to vaporize a liquid) and high specific heat capacity (the amount of energy required to raise the temp one degree)
Ice
Water as a solid(ice) is an arrangement where each water molecule forms exactly 4 bonds and therefore gives it a lower density than liquid water, making it float
Water as a Solvent
water can and will dissolve polar compounds and compounds that can ionize. Water manipulates its charges to insulate what it is breaking down CL- attracts the hydrogen sides of water which facilitates its dissolving
Hydrophilic
- Water loving molecules
- generally polar
Hydrophobic
- water fearing
- generally nonpolar
Solubility of Water
- more nonpolar groups, less soluble something is
- more polar groups means more soluble
- hydrogen bonding increases solubility
pH Scale
- body pH is about 7.4
- a difference of one pH is a ten fold difference (ex 7 to 4 is 101010 or 1000 fold difference)
Henderson-Hasselbach Equation
pH=pKa+log[A-]/[HA]
-in the equation the weak acid goes on the bottom, conjugate base on the top
Buffers
- Solution that can resist changes in pH with the addition of acid or base
- Buffers are 1pH unit above, and below pKa values