Water Flashcards

1
Q

How does rain form?

A
  • Cools to saturation point
  • Adiabatic decompression – no temp change, no energy change, was below saturation point, forced upwards and decompresses, but there is no energy change so it rains
  • Meeting of two air masses – warm moist air forced to move over cold air and decompresses
  • Contact with cold object – warm sea to cool land
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2
Q

Orographic and Conventional Rain?

A
  • Orographic – Moist air rising over mountains – more rain when down wind – creates a rainshadow effect on the leeward side of mountain ranges, e.g. East vs. Western UK.
  • Convectional rain – Short duration high intensity rainfall – UK only during summer - warmth of the ground causes moist air to rise, the air cools and condenses as rain, leads to short duration, intense rain typical of continental interior (not especially in the UK)
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3
Q

Rain typical of UK?

A

• Frontal or cyclonic rain - Typical of UK - Rotating weather systems contain warm and cold air – anticlockwise rotating systems in the Northern Hemisphere contain warm and cold air bodies
o Warm front where warm air rises over cold - Long duration, low intensity rain – followed by high intensity, short duration rain - In UK a day of rain is followed by day of showers.
• Most rain on Western side of UK – First contact of North Atlantic – Where highest points are – higher topography
• North York Mores is exception – they jut out – cycling systems more likely to hit them – similarly in North Norfolk – wetter than they should be – These parts of East Coast more likely to have snow due to the systems come from the North Sea and bring colder air from continental Europe

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4
Q

Types of rain measurement?

A

• Point measurement - storage raingauges - typically daily or monthly recording - recording raingauges - measures intensity by registering change of water level or tipping bucket.
o About 400 rain gages in the UK
o Tipping bucket – two buckets on see-saw mechanism – creates voltage which produces intensity readings
= how many point measurements are needed?
- UK density is 1 per 60 km2
• Spatial measurement - weather radar or satellite - difficult to calibrate radar signal against real rainfall parameters.
o Difficult to calibrate weather radar – no intensity

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5
Q

Use of areal rainfall?

A

o Arithmetic mean – mean of data
o Theissen Polygon – area-weighted rainfall??
o Isohyetal method – a line joining two points of the same rainfall – contouring method
o Preferred method – Hypsometric/multiquadratic methods – Area-weighting and adjusting for topography (altitude) in 2 or 3D

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6
Q

Interception and types?

A

rainfall falling on vegetation rather than on land surface

- interception loss – the amount of rain never reaching the ground
- throughfall – the amount of rain that gets through to the surface
- throughfall is generally less than gross rainfall
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7
Q

What is evaporation?

A

The loss of water from the Earth surface as water vapour, this definition includes water loss through transpiration of plants (evaporation and evapotranspiration are synonymous)

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8
Q

What controls evaporation?

A
  • temperature – temperature of the air and the surface
  • saturation deficit – how much water vapour is in the air
  • solar radiation
  • wind speed
  • nature of the evaporating surface – (rougher surface = more evaportation)
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9
Q

Potential vs actual evapotranspiration?

A
  • meteorological factors give rise to a potential evaporation but this rate will only occur if there no supply limitation
  • actual evaporation ≤ potential evaporation
  • the difference between actual and potential evaporation is controlled by soil moisture.
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10
Q

• Why do negative values of actual evaporation occur?

A

o Groundwater storage is supplying the river flow
• Rainfall from winter, released from storage in summer
• Comparison between total potential evaporation and annual actual evaportation works best on a yearly basis where changes in storage are minimised

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11
Q

What is runoff?

A

the gravitational movement of water in surface channels of whatever size

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12
Q

Hyrdrograph explained

A
  • the Hydrograph –
    o when it rains the rivers go up
    o sometimes referred to as the storm hydrograph
  • the hydrograph is sourced from a range of places
    o direct precipitation – precipitation directly enters the stream
    o quick flow – the rapid response to rainfall– new water
  • slow flow – the flow in the river between storm events, often referred to as base flow – water does not stop flowing during dry periods – old water
  • the quick flow component divides between old and new water
    o old water – water in the catchment/soil/ground prior to the event that is pushed out by the rain
    o new water – water coming in with the storm
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13
Q

Horton theory?

A

• Slow flow: Base flow Horton:
o Soil surface partitions rainfall into a surface flow and groundwater flow
o Partitioning is controlled by infiltration capacity of soil surface
o Infiltration capacity declines during a rainstorm generating more infiltration-excess runoff
o Therefore, hydrograph dominated by “new” water from overland flow
• Surface runoff (overland flow) – hydrograph dominated by “new water” – infiltration capacity exceeded due to crusting over of surfaces and water flows to rivers – infiltration excess
• Experimented in Northern Texas – large rainstorms in bare soils– observed overland flow – not relatable

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14
Q

Hewlett theory?

A

o Overland flow is very rare, most rainfall infiltrates the soil
o Soils saturate leaving infiltration capacity is zero, i.e. saturation excess runoff
o Runoff generated only in saturated areas of catchment but that these are variable and would be expected to increase during a storm.
o Often referred to as a variable-source model
• Soil saturates but not to the surface – rainfall builds up in the soil – water that reaches river will be “old water”
• Still thought that most water was “new” – wrong

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15
Q

What runoff theory actually occurs?

A
  • Hewlett
  • Very rare overland flow
  • Most water is “old” – oxygen isotopes
  • Horton - Works best for bare soils in arid regions, even here source areas are variable, i.e. Hewlett is a better model
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16
Q

Unit hydrograph?

A
  • Time based relationship – gives a unit
  • Need to be adjusted for location
  • How much runoff does a unit of rain produced?
  • Unit hydrographs can be seasonally adjusted but requires a lot of information and difficult to calculate
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17
Q

Stage relationship?

A
  • During flood prediction depth is more important than volume
  • Stage = river height
  • Relationship between river height and flow at a given location
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18
Q

Frequency analysis?

A

• Flow duration curve: no use for predicting floods or droughts – used to predict dilution – cumulative frequency plot
• Annual maximum series – good for flood prediction – highest flow period
• Annual minimum series – good for drought prediction – lowest flow period
• Peaks over threshold (Partial duration series) – an improvement on the annual maximum series as it allows for more than one flood per year and other flood data is not thrown out – can find river thresholds
o Calculation of return period
• The return period is the probability of an event expressed in terms of years
• This is the Gringorten formula

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19
Q

How do we measure flow?

A
  • gauging stations – a structure with a fixed cross-section in which stage and/or velocity can be measured.
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20
Q

Groundwater profile?

A
  • Unsaturated zone – rocks, little water in pores
  • Capillary zone/fringe – pores full of water
  • Water table at bottom of the capillary fringe
  • Saturated zone – pore zone full of water

Water is more attracted to surfaces than to itself – will spread across a surface = wetting

Capillary fringe – water attracted upwards by empty pore spaces

Water table = point where water pressure = atmospheric pressure – When water stops being held in place by capillary forces
Water table – the point to which a bore hole will fill to

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21
Q

Capillary forces?

A

• Force due to surface tension and wetting effect
• Water surface acts an elastic membrane because of attraction between water and molecules
• Wetting:
o Ideal situation is a monolayer
o On a dirty surface there is an angle of contact
o Angle of contact greater than 90 degees the liquid is non-wetting
o Water is attracted to surface (it is wetting) this causes capillary rise
o For water in a glass:
• H=15/r
• H= height of capillary fringe
• R = radius of glass tube
• Pores in soil act as capillaries
• Water in a capillary is below atmospheric pressure, the water table is defined as the point where the water table is at atmospheric pressure

22
Q

Interaction between water table and capillary fringe

A
  • Size of capillary fringe is dependent on porosity
  • Fringe moves up and down with water table but some water is retained
  • Specific yield is the amount of water returned for per drop in water table
  • Specific retention is amount retained
23
Q

Porosity?

A

• Proportion that is void space, fraction of rock volume
o Expressed as a percentage or fraction of the rock volume
o Porosity varies from about zero up to 60%
• Effective porosity
o Interconnected porosity
• Permeability
o How easily a fluid can move through a rock
o A rock/sediment with sufficient permeability to supply water in useful quantities is called an aquifer
• Clay – high porosity but low permeability + very large capillary fringes = no getting it out
• Sandstone – high porosity and high effective porosity
• Chalk has a lot of porosity in its matrix + low specific yields – all the transport in the fractures

24
Q

Aquifer and 2 mains types

A

a rock/sediment with sufficient permeability to supply water in useful quantities
• Useful = relative to place

Coal measures = good aquifer but not used in Durham as there are good surface water sources

What might be an aquifer in one area may not be in another

Aquitard/Aquiclude:

  • A rock/sediment with insufficient permeability to supply useful water
  • Aquitard – very slow movement
  • Aquiclude - Excludes water
25
Q

Elastic storage?

A
  • Water under pressure is compressed and can push grains apart to give additional storage space if water is removed the additional weight of the confining bed
  • If water is removed the additional weight of the confining bed compresses the grains and more water is squeezed out
26
Q

Storage coefficient:

A
  • Volume of water released per unit of rainfall

* Useful for both confined and unconfined aquifers

27
Q

Types of aquifer?

A

• Igenous rocks
– Little initial porosity or permeability
– Fringes of igneous units may weather to give some aquifers
• Metamorphic rocks
– Not considered to be potential aquifers
• Sedimentary rocks
– All major aquifers
– Clastic sedimentary tend to have intergranular porosity
– Porosity/permeability varies with grain size and grain size distribution
– Clays and shales have high porosities but low permeabilities
– Limestones tend not to have useful intergranular porosity
– Chemical sediments, esp evaporties can be particulary impermeable
– In general porosities decrease with depth
• Confined
– An aquifer bounded by aquitards or aquicludes
– Water comes under pressure
– Artesian Basin
• Unconfined
– Unbound or outcrops to surface
• Perched
– An aquifer bounded beneath by an aquitard and situated above regional water table

28
Q

Artesian basins

A

• Water and the aquifer is slightly compressible so puncturing the aquifer, pressurises the water and releases more water than it should – decompresses the stone

29
Q

Bypass flow?

A

water bypasses the soil and flows rapidly into the water table

30
Q

Macropore?

A
  • Pores that can drain under gravity
  • Suitably connected to allow drainage
  • Can be thought as the soil or unsaturated equivalent of fractures
  • Literature says pores greater than between 30 mm and 2 mm
  • Pores that allow drainage as saturation is approached
  • Macropores are the pores that become active at suctions lower than the field capacity
31
Q

Types of macropore?

A
•	Faunal
o	Burrows of everything from rabbit to nematodes
o	Wormhole – most important
•	Come from the surface to depth and remain open when soil is wet unlike most cracking
•	Root holes
o	Tabular macropores from living or dead roots
•	Cracks
o	Desiccation cracks
o	Cracks from mechanical cultivation
o	Planar features
•	Natural soil pipes
o	Result from natural soil processes
•	Cutans
32
Q

Measuring macroporosity

A
  • Thin sections are no good
  • Suction plate
  • Assumes that macropores operate at a suction but they don’t
  • Plate allows set matric potential to drain a soil core
  • Tracers
  • Measures the pores doing transporting
  • Stop when dye appears in bottom – this has moved down by gravity – find macropores, which travel from surface to depth
  • No real field methods
33
Q

Nature of macropore flow

A

• It is a balance between input rate infiltration capacity and saturation
• It starts raining
• Precip. Rate < infiltration capacity
• All water is absorbed
• Precip. Rate > infiltration capacity
• Either rate is too fast or infiltration capacity has decreased
• Water ponds on soil surface
• Water flows down any slope
➢ Unsaturated overland flow
• Water will enter and flow down available macropores
➢ Unsaturated macropore flow
• Water is unlikely to flow very far
• Infiltration capacity is exceeded because soil is saturated
• Water ponds on soil surface
• Matrix of soil is full
• Water flows down any slope
➢ saturated overland flow
• Water will enter and flow down available macropores
➢ saturated macropore flow
• Water could flow across surface considerable distance

34
Q

Modelling macropore flow:

A

• Two domains – slow flowing water matrix – fast flowing macropore network
o Matrix vs. macropores
o Matrix flow is Darcian
o Macropore flow is non-Darcian more like a pipe
• Macropore network
• Number, size and connectivity of macropores
• Interactions
• How does flow in matrix interact with flow in macropores?
• Initiation
• When does what type of flow start?

35
Q

Lateral flow?

A
  • Layers within a soil can have an infiltration capacity
  • Layers can act like the soil surface
  • The equivalent of overland flow can occur along a layer
  • This is lateral interflow
  • A subsurface, horizontal macropore flow
36
Q

Significance of bypass flow:

A
  • Occurs above field capacity i.e water does not drain from the soil by anything other than bypass flow
  • Matrix flow is too slow
  • These types of flow bypass the matrix
  • Overland flow
  • Macropore flow
  • Lateral interflow
  • Bypass flow allows rapid water and pollutant off soils
  • Bypass flow carries the majority of flow and contaminant in most soils
  • Bypass flow allows rapid movement of pollutants off fields and through soil
  • By definition bypass flow bypasses the soil matrix and so limits the opportunity for degradation and adsorption to retard or diminish pollution
  • Movement of pollutants in bypass flow means that pollution is event bases
  • Pesticides, phosphates and soil erosion show event-based hydrology, nitrates and chlorides do not
  • If we can predict times of bypass flow we can protect water intakes
37
Q

Water profile and water table?

A

Water profile
• Water table divides the saturated from the unsaturated zones
• Yet above the water the capillary fringe is saturated
Water table
• The point at which the water pressure is at atmospheric pressure
• The definition of head implies negative pressures above the water table

38
Q

Suction?

A

• Negative pressure above the water table prevents unsaturated flow into wells – negative pressure = suction
• Comes from adsorption – capillary action and osmosis
• Capillary forces –
o Grain size dependent – the smaller the grain size the smaller the pores the greater the capillary action
• Adsorption – surface charge and surface charge dependent
o Therefore grain size dependent and better with clay than quartz
• Osmosis
o Differences due to ionic concentrations
o Requires a membrane
o Least important of the three mechanisms of suction
o Requires a membrane, e.g. roots
• Suction is referred to as matric suction or matric potential
• Total head(f) = elevation head(ye) + suction head(ye) + osmotic head (yo)

39
Q

Moisture characteristic?

A

• Suction increases as moisture content decreases – less force from gravity acting against suction
• Air entry value – No water will drain until a certain suction is reached
• Wilt point – suction at which roots cannot extract all the water we need
• Permanent wilt point – point at which suction can no longer function – plant will die
o The suction at which the plant can no longer function
• Field capacity – suction at which pores cease to drain under gravity

Large pore spaces – hard to keep water in
Small pore spaces – hard to get air in to create suction

40
Q

Hysteresis?

A

o The moisture characteristic, showing the main wetting and drying boundary curves
o Moisture characteristic is dependent on whether you are wetting or drying the soil
o Pores empty at larger suction than they fill
o Path dependent

Ink bottle effect = pores are not capillary tubes – are like old ink bottles
• Suction is controlled by the pore necks
• Contact angle effect – advancing wetting front has a larger contact angle
• Pore body – wider radius
• Pore neck – smaller radius

41
Q

Drying and wetting?

A

Drying – holds onto more water because of forces in pore body
Wetting – holds onto less water than expected

42
Q

Contact angle effect?

A

Because of clays smaller pore sizes – they are better at holding onto water and less effected by drawing water out – although they have tortuosity problems they have higher hydraulic conductivity at higher metric flow

43
Q

Zero flux plane?

A
  • In a soil at equilibrium elevation head means that flow is downward
  • Evaporation at the soil surface causes suctions to increase at the surface
  • As suction increases flow can reverse and water moves upwards
  • The plane that divides water moving up and water moving down is the zero flux plane
  • No water movement
  • Forces forcing water up and down are equal – divergent flux plane – will lower during summer as top layer becomes increasingly dry - a drying front – water can’t cross the plane
44
Q

Flow and hydraulic conductivity?

A

• Flow can be from areas of low suction to areas of high suction
• K(unsaturated) < K(saturated)
o Decrease in effective cross-section and increase in tortuosity
• K(unsat) for a clay > K(unsat) for a sand
o Sand is a good barrier to unsaturated flow

45
Q

Moisture content measurement?

A
  • Gravimetric method – dig up, weigh, dry, weigh – destructive
  • Capacitance probe
  • Gypsum – measures electrical conductivity – two electrodes in gypsum block – standardise – bury block – disruptive
  • Neutron probe – source of neutrons – bounce off water molecules – return to reader and shows abundance of water molecules

Suction: - tensiometer

46
Q

Infiltration capacity?

A
  • The capacity for the soil surface to take in water
  • Has the same units as hydraulic conductivity (m/s)
  • Infiltration capacity decreases over a rainstorm
  • Large at beginning of rainstorm
  • Soil surface sucks in water
  • Soil wets up suction declines and so does the infiltration capacity - less force pulling water in
  • At saturation infilitration approximated to the saturated hydraulic conductivity but is generally slightly lower
  • Lower because of soil crusting– storm causes particles to fill in pores
47
Q

What is regulated and who regulates it?

A

What is regulated – the water quality that reaches the property (not tap water)

Who regulates?
• Drinking Water Inspectorate
– Controls what enters a property from water companies
• Environment Agencies (SEPA)
– Control river, lakes, groundwater, estuaries and bathing waters
– Ocean quality is governed by international treaty
• Water quality defined by EU law and statutory water quality standards
• All legislation is moving to European Water Framework Directive

48
Q

Physical characteristics of water quality?

A
  • PH – physical not chemical because it is measured physically (electrode)
  • Temperature – Hot water is a pollutant – e,g outflows of hot water from power stations – kill marine life
  • Transparency – plant life in river needs sunlight – needs transparency
  • Colour – Has to be removed before water can be supplied – water cant be treated until the colour has been removed (colour is dissolved substances and reacts with the treatment chemicals – chlorine reacts to form chloroform) – cant be treated when colour load too high
  • Turbidity – particulate material – high turbidity lowers light penetration – less photosynthesis – measured by light penetration
  • Suspended solids – e.g. poo levels – measured by filiation
  • Total dissolved solids (TDS) – measured by evaporation after dryness – what gets through the filter from suspended solids test – hard for fresh waters – easy for brackish or saline waters (sea water)
  • Conductivity – Easy to measure on fresh waters – harder on sea water due to high figures
49
Q

Chemical water quality

A

• Dissolved inorganic substances
o Major cations (Na, K, - indicates sea water influence
o Ca, Mg – indicates terrestrial influence
o Major anions (HCO3-, Cl-, SO42- (indicates reduction)
o Minor ions
o Typically major nutrients (nitrate, phosphate)
• Organic substances
o Particulate Organic Carbon (POC) – major influencer of suspended solids
o Dissolved organic carbon (DOC) – major influencer of water colour
o Individual pollutant compounds
• Dissolved oxygen – we want high levels
– Saturation is temperature dependent – as water heats – less oxygen
• 14.63 ppm at 0oC, 9 ppm at 20oC
– Vital to life in the water
– Seawater holds less oxygen – 75% of fresh water
– Much water quality control is about diss. Oxygen
• Presence of reducing species, e.g. Ammonia
• Carbon dioxide
– Water hardness – how much larva would be produced if soap was added – measure of calcium and magnesium in water
– Alkalinity – normally how much co2 dissolved in it – want a positive alkalinity – some buffering capacity if there is an incident in transit – NOT HOW ALAKALINE WATER IS - how much acid you can put in before it changes

50
Q

Biological water quality

A
•	Advantages
o	Time integration – not a spot measurement
o	Condition integration
o	“Good ecological status”
•	Indicator species
o	Presence/absence –benthickmacroinvertibrates 
o	Bioaccumulators
•	Community measures – locally specific
o	Kick samples 
o	Fish counts

Biological water quality
• Aquatic flora
• Aquatic fauna
• Diseases – E.coli

51
Q

What is BOD and COD?

A

COD or Chemical Oxygen Demand is the total measurement of all chemicals in the water that can be oxidized
BOD- Biochemical Oxygen Demand is supposed to measure the amount of food (or organic carbons) that bacteria can oxidize