VIIA n VIIB Flashcards
Who suggested the word halogen
BERZELIUS
Halogen came from the greek words _____ and _______ which means “producer of sea salt”
SEA SALT AND TO PRODUCE
The oxidation property of halogens _____ with increasing atomic number
DECREASES
Is the first element in the halogen group in the PT. Its atomic number is 9 and its atomic wt. is 19
FLUORINE
Physical state of fluorine
PALE YELLOW GAS
Natural sources of fluorine
- FLUOROSPAR
- FLUORAPATITE
- CRYOLITE
Fluorine poisoning (mottled enamel and abnormal bone growth)
FLUOROSIS
Use of NaF
2% IN 4 APPLICATION
Use of SnF2
8% freshly preparation
Uses of dichlorofluoromethane
- FREON
- REFRIGERANT
- PROPELLANT
The second lightest of the halogens
CHLORINE
- AKA dephlogisticated muriatic acid
- found in large quantities as sodium chloride in seawater and in-land deposits
- used as H2O disinfectant
CHLORINE
Physical state of chlorine
GREENISH YELLOW GAS
- Most predominant ANION
- does not readily react to carbon
CHLORINE
Use of NaOCl
DAKIN’S SOLUTION
Use of labarraques solution aka diluted dakins solution (2.5%)
CHLORINATED SODA LIME SOLUTION
Use of Ca(OCl)2
MURIATE OF LIME
Use of diluted HCL 10%
TREATMENT TO ACHLORHYDRIA (LACKING OF HYDROCHLORIDE)
Is sedative and antidepressant
BROMINE
Toxicity of bromine
BROMINISM (SKIN ERUPTION, PSYCHOSIS, WEAKNESS, H/A)
Treatment to brominism
NaCl or NH4Cl
Physical state of bromine
REDDISH BROWN FUMING LIQUID WITH SUFFOCATING ODOR
- 0.1N bromine solution
- sedative and used in iodometry
KOPPESCHAAR’S SOLUTION
- AKA Eka-iodine
- least electronegative element
- only synthetic halogen
- only radioactive halogen
- only metallic halogen
ASTATINE
Synthesis of thyroid hormones
IODINE
CCl4 or CHCl color
VIOLET
Physical state of iodine
GRAYISH BLACK SOLID, VIOLET COLORED VAPOR
Increase solubility of I2
POTASSIUM IODIDE
Lugol’s solution -> contains triiodide (I3)
STRONG IODINE SOLUTION
2% iodine in 50% alcohol with NaI
IODINE TINCTURE
- Carbolised iodine solution
- antiseptic
MANDEL’S SOLUTION
- Polyvinylpyrolidone (PVP)
- Iodophores - liberates free iodine
POVIDONE-IODINE (BETADINE®)
- Phenolated iodine solution
- disinfectant
BOULTON’S SOLUTION
Iodine preparations
- STRONG IODINE SOLUTION / LUGOL’S SOLUTION
- SATURATED SOLUTION OF POTASSIUM IODIDE (KISS)
- AKA Eka-manganese
- 1st element produced artificially
- used in preparation of radiopharmaceuticals
- diagnostic agent
TECHNETIUM
Physical state of manganese
SILVERY-GRAY METAL
Salt forms of manganese
- HAUSMANNITE
- BRAUNITE
Is a silicate mineral containing both di- and tri- valent manganese
BRAUNITE
Is a complex oxide of manganese containing both di- and tri- valent manganese
HAUSMANITE
- Mineral chameleon
- oxidizing agents, volumetric solution in permanganometry
KMnO4
Mn+2 =
Mn+3 =
Mn+4 =
Mn+6 =
Mn+7 =
n+2 = MANGANOUS
Mn+3 = MANGANIC
Mn+4 = MANGANITE
Mn+6 = MANGANATE
Mn+7 = PERMANGANATE