VESPR theory Flashcards

1
Q

what is an electron domain geometry

A

the type of shape that is formed just by how many electron domains there are (based on just the number )

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2
Q

What is molecular geometry

A

the shape of a molecule based on the influences of different bonds and lone electron pairs around the central atom

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3
Q

what determines a linear VESPR shape

A

if there are 2 bonding electrons domains on the centeral atom

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4
Q

what determines a trigonal planar shape

A

when there are three bonding electron domains around the central atom

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5
Q

What determines the tetrahedral VESPR shape

A

When there is four bonding electron domains

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6
Q

What determines a trigonal bipyramidal VESPR shape

A

when there are 5 bonding electron domains

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7
Q

What determines a octrahedral VESPR shape

A

When there are 6 bonding electron domains

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8
Q

What is the general formula for the molecular shape? and what is the meaning of each letter

A

A X(n) E(n)
- a = central atom
- x= the valence elements (aka the number of bonds to the central atom
- n = number of occurance
- e = the number SINGLE electrons around the central atom (if there is no electrons around the central atom then just elimante the e and just keep formula to AX(n))

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9
Q

what determines if the MG will be different from the EDG

A

if there is an E in the general formula then the answer will vary

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10
Q

What are all the possiblities for a central molecule with 2 electron domains

A

it can only be linear

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11
Q

What are the possibilities for a central atom that has three electron domains

A
  • 3 bonds and no non bonding electrons = trigonal planar
  • 2 bonds and 1 non bonding electron pair = bent
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12
Q

What are the possibilities for a for a central molecule that has 4 electron domains

A
  • 4 bonds and no non bonding electrons = tetahedral
  • 3 bonds and 1 non bonding electron pair = trigonal pyramidal
  • 2 bonds and 2 non bonding electron pair = bent
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13
Q

What are the possibilities for a central atom with 5 electron domains

A
  • 5 bonds and no non bonding pairs = trigonal bipyramidal
  • 4 bonds and one non bonding pair = see saw
  • 3 bonds and two non bonding pairs = T-shape
  • 2 bonds and three non bonding pairs = linear
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14
Q

What are the possiblities of a central molecule that has 6 electron bonding domains

A
  • 6 bonds and no non bonding pair = octrahedral
  • 5 bonds and 1 non bonding pair = square pyramidal
  • 4 bonds and 2 non bonding pairs = square planar
  • 3 bonds and 3 non bonding pairs = T - shaped
  • 2 bonds and 4 non bonding pairs = linear
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15
Q

What is the bond angle in a linear shape

A

180 degree

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16
Q

What is the bond angle in a bent shape

A

119.3 degree

17
Q

What is the bond angle in a trigonal pyramidal shape

A

106.7

18
Q

what is the bond angle in a trigonal planar shape

A

120

19
Q

What is the bond angle of a t shaped

A

86.2

20
Q

What is the bond angle of a tetrahederal shape

A

109.5

21
Q

What is the bond angle of a trigonal bipyramidal

A

90 degree between the top or bottom atoms
120 degree between one in the same plane

22
Q

What is the bond angle of a octahederal shape

A

90 degree between any domain

23
Q
A