VESPR theory Flashcards
what is an electron domain geometry
the type of shape that is formed just by how many electron domains there are (based on just the number )
What is molecular geometry
the shape of a molecule based on the influences of different bonds and lone electron pairs around the central atom
what determines a linear VESPR shape
if there are 2 bonding electrons domains on the centeral atom
what determines a trigonal planar shape
when there are three bonding electron domains around the central atom
What determines the tetrahedral VESPR shape
When there is four bonding electron domains
What determines a trigonal bipyramidal VESPR shape
when there are 5 bonding electron domains
What determines a octrahedral VESPR shape
When there are 6 bonding electron domains
What is the general formula for the molecular shape? and what is the meaning of each letter
A X(n) E(n)
- a = central atom
- x= the valence elements (aka the number of bonds to the central atom
- n = number of occurance
- e = the number SINGLE electrons around the central atom (if there is no electrons around the central atom then just elimante the e and just keep formula to AX(n))
what determines if the MG will be different from the EDG
if there is an E in the general formula then the answer will vary
What are all the possiblities for a central molecule with 2 electron domains
it can only be linear
What are the possibilities for a central atom that has three electron domains
- 3 bonds and no non bonding electrons = trigonal planar
- 2 bonds and 1 non bonding electron pair = bent
What are the possibilities for a for a central molecule that has 4 electron domains
- 4 bonds and no non bonding electrons = tetahedral
- 3 bonds and 1 non bonding electron pair = trigonal pyramidal
- 2 bonds and 2 non bonding electron pair = bent
What are the possibilities for a central atom with 5 electron domains
- 5 bonds and no non bonding pairs = trigonal bipyramidal
- 4 bonds and one non bonding pair = see saw
- 3 bonds and two non bonding pairs = T-shape
- 2 bonds and three non bonding pairs = linear
What are the possiblities of a central molecule that has 6 electron bonding domains
- 6 bonds and no non bonding pair = octrahedral
- 5 bonds and 1 non bonding pair = square pyramidal
- 4 bonds and 2 non bonding pairs = square planar
- 3 bonds and 3 non bonding pairs = T - shaped
- 2 bonds and 4 non bonding pairs = linear
What is the bond angle in a linear shape
180 degree