Vaporizers Flashcards
What is vaporization
- converting a liquid to a gas
What does volatility mean?
-the ability of a substance to break it’s intermolecular forces
Why do we call our inhaled agents volatile agents?
- liquids are converted to vapor to be inhaled by patient and provide general anesthesia
What is the goal of the vaporizer
1) convert liquid to vapor at a consistent concentration with
2) tight control
so that we can deliver anesthesia safely (no underdosing or overdosing)
Vaporization is dependent on what three things?
- vapor pressure of each volatile agent
- temperature of the ambient environment (linear)
- amount of carrier gas (FGF) increase in flows increase dilution (linear)
What gas laws apply to vaporization
- Ideal Gas Law
- Dalton’s Law of Partial Pressure
Describe the process of vaporization. How do the components of the Ideal Gas Law relate to vaporization?
- in a sealed container gas molecules crash into the walls and exert a pressure
- that pressure is:
- directly proportional to the number of moles of gas molecules present
- directly proportional temperature of the system
- inversely proportional is volume
Dalton’s Law of Partial Pressure
-total pressure in a given space is calculated by adding the partial pressures of each gas
How is vapor pressure calculated from total pressure?
How is concentration calculated from vapor pressure?
- (molar fraction)(total pressure) = (vapor pressure)
- vapor pressure/barometric pressure = concentration or molar fraction
What is concentration measured in?
V/V %
Enflurane Vapor Pressure
172 mmHg
Isoflurane Vapor Pressure
240 mmHg
Halothane Vapor Pressure
244 mmHg
Sevoflurane
157 mmHg
Desflurane Vapor Pressure
669 mmHg
When anesthesia providers select a dose of volatile agent that the vaporizer will deliver they select what?
- v/v %
- partial pressure of gas / total atmospheric pressure x 100
What is the partial pressure of oxygen, nitrogen, and other at atmospheric temp?
- Oxygen = .21 x 760 = 160
- Nitrogen = .779 x 760 = 592
- Other = .011 x 760 = 8.4
What effect does temperature have on the vaporization process?
-(direct) as temperature decreases, vapor pressure decreases
What is the latent heat heat of vaporization?
- the energy (calories or joules) at which a liquid or volatile anesthetic changes from a liquid to a gas without changing its temperature
Why is there no change in temperature?
There is no temperature change because although you are adding energy to the liquid, energy is escaping in the form of kinetic energy once the molecules at the surface leave in the form of gas molecules
When the latent heat of vaporization is reached, what effect happens to the liquid
-the remaining liquid will be depleted of its energy, having a cooling effect, decreasing vapor pressure
Why is the liquid cooling a problem?
Decrease in vapor pressure means decrease in anesthetic concentration means under-dose
How do you prevent the cooling of liquid
-add a constant heat source
Liquid and vapor are _____ at vapor pressure
Equilibrium
Adding heat source shift equilibrium toward _____
at this time vapor pressure is ________
(Right) toward vapor
Increases