Valence And Ionic & Covalent Bonds Flashcards

1
Q

Define bond.

A

Forces that hold atoms together.

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2
Q

Define covalent bond.

A

A bond where two atoms share electrons.

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3
Q

Define ionic bond.

A

A bond between a metal and non-metal.

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4
Q

Define electronegativity.

A

An atoms ability to attract electrons in a chemical bond.

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5
Q

Define empirical formula.

A

The simplest ratio of atoms.

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6
Q

Why don’t noble gases have electronegativity?

A

Because they have a full outer shell.

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7
Q

Define ΔEN.

A

Difference in electronegativity.

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8
Q

To predict what type of bond will form you need to work out ΔEN. How is this done?

A

EN(Element 1) - EN(Element 2) = ΔEN

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9
Q

What is the ΔEN value for ionic bonds?

A

More than 2.1

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10
Q

What is the ΔEN value for polar covalent bonds?

A

0.4 to 2.1

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11
Q

What is the ΔEN value for non-polar covalent bonds?

A

Less than 0.4

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12
Q

Define δ-

A

It means delta negative and gain of electron density.

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13
Q

Define δ+

A

It means delta positve and loss of electron density.

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14
Q

Define deshielding.

A

When the electrons aren’t shared equally as a polar covalent bond is formed.

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15
Q

What does this diagram represent?

A

A polar covalent bond has formed. The arrow represents a dipole directing to the more electronegative element.

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16
Q

What are the three rules for drawing Lewis structures?

A
  1. Count the valence electrons (number of outer electrons).
  2. Use two electrons to form a covalent bond.
  3. Use remaining electrons to yield full valency for all atoms.
17
Q

Define duet rule.

A

Full valency of the first shell, which is two electrons.

18
Q

Define octet rule.

A

Full valency of the outer shell, which is eight electrons.

19
Q

How many bonds can Hydrogen make?

A

One.

20
Q

The octet rule applies to which four elements?

A

Carbon, Nitrogen, Oxygen and Fluorine as they cannot exceed eight electrons.

21
Q

What four elements can have less electrons than the octet rule?

A

Beryllium, Magnesium, Boron and Aluminium.

22
Q

What two elements can have the same or more electrons than the octet rule?

A

Phosphate and Sulphur.

23
Q

Define structural isomers.

A

Same molecular formula, but different gross connectivity.

24
Q

Define geometric isomers.

A

Same gross connectivity, but different orientation in space due to no rotation about double bond.

25
Q

Define saturated.

A

CnH2n+2

26
Q

Define unsaturated.

A

CnH2n

27
Q

Define valency.

A

The potential of an atom of an element to combine with other atoms measured by the number of electrons which an atom will give, take or share to form a chemical bond.

28
Q

Define postive valence.

A

Valence electrons are donated.

29
Q

Define negative valence.

A

Valence electrons are accepted.

30
Q

Define ionisation energy.

A

The energy required to remove a valence electron from a given atom.

31
Q

If an atom has high ionisation energy, are the valence electrons easier or harder to remove?

A

Harder.

32
Q

If an atom has small ionisation energy, are the valence electrons easier or harder to remove?

A

Easier.

33
Q

How many times stronger is a covalent bond than an ionic bond?

A

5 to 20 times stronger.

34
Q

What do ionic bonds exist as at the molecular level?

A

Crystal lattice.

35
Q

What percentage of cells are water?

A

70%.

36
Q

Define bond length.

A

The distance at the lowest energy point is the separation between the atoms at which their attraction is maximal.

37
Q

Who is regarded as the founder of modern Biology and Chemistry?

A

Linus Pauling.

38
Q

Who developed the concept of the “chemical bond” and “molecular biology” in the 1940’s?

A

Linus Pauling.