UNIT I Flashcards

1
Q

Study of hydrocarbons and their various derivatives

A

Organic chemistry

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2
Q

Study of all substances other than hydrocarbons and their derivatives

A

Inorganic chemistry

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3
Q

number of inorganic compounds

A

1.7 million

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4
Q

number of organic compounds

A

10 million

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5
Q

Compounds are categorized into two types:

A

organic compounds, inorganic compounds

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6
Q

from living organisms (with a vital force)

A

organic compounds

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7
Q

from minerals (without a vital force)

A

inorganic compounds

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8
Q

organic chemistry = compounds that contain ______

A

carbon

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9
Q

is a compound made from carbon atoms

A

organic compound

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10
Q

has one or more C atoms

A

organic compound

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11
Q

has many H atoms

A

organic compound

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12
Q

may also contain O, S, N, P, and halogens

A

organic compound

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13
Q

Properties of Organic Compounds

A

• contain carbon
• have covalent bonds
• have low melting points
• have low boiling points
• are flammable
• are soluble in nonpolar solvents
• are not soluble in water

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14
Q

______, ______, is an organic compound used
as a fuel.

A

Propane, C3H8

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15
Q

______, ______, is an inorganic compound composed of Na+ and Cl– ions.

A

NaCl, salt

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16
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O) organic.

has a high melting point

A

I

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17
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O)
organic.

is not soluble in water

A

O

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18
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O)
organic.

has a formula CH3─CH2─CH3

A

O

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19
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O)
organic.

has a formula MgCl2

A

I

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20
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O)
organic.

burns easily in air

A

O

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21
Q

Identify each of the following characteristics as most
typical of compounds that are I) inorganic or O)
organic.

has covalent bonds

A

O

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22
Q

Atoms to the left of carbon ______ electrons.

A

give up

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23
Q

Atoms to the right of carbon ______ electrons.

A

accept

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24
Q

Carbon ______ electrons.

A

shares

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25
Q

In carbon compounds, carbon has ______ valence electrons, and hydrogen has ______

A

4, 1

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26
Q

to achieve an octet, C forms ______ bonds

A

four

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27
Q

Carbon (C) atom makes total ______ bonds

A

4

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28
Q

The sharing of four valence electrons requires the
formation of four ______ which are represented by four lines

A

covalent bonds

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29
Q

______ predicts that a carbon atom with four single, covalent bonds is tetrahedral as shown in a
(a) tetrahedron
(b) ball-and-stick model
(c) space-filling model
(d) expanded structural
formula

A

VSEPR theory

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30
Q

In organic molecules with more carbon atoms, ______ electrons are shared

A

valence

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31
Q

In organic molecules with more carbon atoms, ______ bonds form between carbon and carbon atoms

A

covalent

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32
Q

In organic molecules with more carbon atoms, ______ bonds form between carbon and hydrogen atoms

A

covalent

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33
Q

______ are positively charged.

A

Protons

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34
Q

______ have no charge.

A

Neutrons

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35
Q

______ are negatively charged.

A

Electrons

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36
Q

Atomic number = # of ______

A

protons

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37
Q

Atomic number of carbon = ______

A

6

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38
Q

Neutral carbon has six ______ and six ______.

A

protons, electrons

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39
Q

number of protons + number of neutrons = ______

A

mass number

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40
Q

mass number - number of protons = ______

A

number of neutrons

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41
Q

______ = number of protons – number of electrons

A

charge of an ion

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42
Q

have the same atomic number, but different mass numbers

A

isotopes

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43
Q

All carbon atoms have the same atomic number, but not all have the same mass number because they do not all have the same number of ______.

A

neutrons

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44
Q

The first shell is ______ to the nucleus.

A

closest

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45
Q

The closer the atomic orbital is to the nucleus, the ______ its energy.

A

lower

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46
Q

Mnemonics of electron distribution

A

ELECTRON CONFIGURATION

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47
Q

Describes the arrangement of electrons by sublevel
according to increasing energy

A

ELECTRON CONFIGURATION

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48
Q

An electron goes into the atomic orbital with the lowest energy.

A

Aufbau principle

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49
Q

No more than two electrons can be in an atomic
orbital; the two electrons must be of opposite spin.

A

Pauli exclusion principle

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50
Q

An electron goes into an empty degenerate orbital rather than pairing up.

A

Hund’s rule

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51
Q

______ electronic configuration of an atom describes the orbitals occupied by the atom’s electrons when they are all in the available orbitals with the lowest energy.

A

Ground-state

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52
Q

______ electronic configuration results when energy is applied to an atom in the ground state, one or more electrons can jump into a higher-energy orbital. The atom then would be in an excited state.

A

Excited-state

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53
Q

______ are electrons in inner shells (those below the outermost shell). They do not participate in chemical bonding.

A

Core electrons

54
Q

______ are electrons in the outermost shell.

A

Valence electrons

55
Q

Accounts for the outermost or valence electrons of an atom.

A

Condensed Electron Configurations

56
Q

The electron configuration can be abbreviated by indicating the innermost electrons with the symbol of the corresponding noble gas.

A

Condensed Electron Configurations

57
Q

Number of valence electrons = ______ number

A

Group

58
Q

______ developed a method to denote potential
bonding electrons by using one dot for every valence electron around the element symbol.

A

G. N. Lewis

59
Q

When forming compounds, atoms tend to gain, lose, or share electrons until they are surrounded by eight valence electrons (the ______).

A

octet rule

60
Q

Atoms on the Left Side of the Periodic Table ______ an Electron

A

Lose

61
Q

Atoms on the Right Side of the Periodic Table ______ an Electron

A

Gain

62
Q

A ______ Atom Can Lose or Gain an Electron

A

Hydrogen

63
Q

An ______ is Formed by the Attraction Between Ions of Opposite Charge

A

Ionic Bond

64
Q

______ are Formed by Sharing Electrons

A

Covalent Bonds

65
Q

Nonpolar covalent bond = bonded atoms are ______

A

the same

66
Q

Polar covalent bond = bonded atoms are ______

A

different

67
Q

Bond polarity depends on the ______ in ______.

A

difference, electronegativity

68
Q

Difference in electronegativity is a gauge of ______.

A

bond polarity

69
Q

If the electronegativity difference between two bonded atoms is 0.4-1.9 (unequal sharing of electrons)

A

Polar Covalent Bond

70
Q

If the electronegativity difference is >2.0 (transfer of electrons)

A

Ionic Bond

71
Q

If the electronegativity difference is 0-0.39 (equal sharing of electrons)

A

Nonpolar Covalent Bond

72
Q

the greater the difference in electronegativity, the ______ the dipole moment, and the ______ polar the bond

A

greater, more

73
Q

Formal charge formula

A

FC = VE - (B +d)

74
Q

In order to have a complete octet, the number of bonds and the number of lone pairs must total ______.

A

four

75
Q

An ______ is a three-dimensional region around the nucleus where an electron is most likely to be found.

A

atomic orbital

76
Q

______ orbital is a sphere with the nucleus at its center.

A

s

77
Q

______ have both particle-like and wave-like properties.

A

Electrons

78
Q

A ______ is a consequence of the wave-like properties of an electron.

A

node

79
Q

There is zero probability of finding an electron at the ______.

A

node

80
Q

p orbitals have ______ lobes. They are generally depicted as ______ shaped. Computer-generated representations reveal that they are more like ______.

A

two, teardrop, doorknobs

81
Q

______ node (node): A point or plane of zero electron density in an orbital. Always bordered by two or more orbital lobes.

A

Orbital

82
Q

Three p orbitals have ______ energy.

A

the same

83
Q

Each p orbital is ______ to the other two p orbitals.

A

perpendicular

84
Q

______ combines the tendency of atoms to fill their octets by sharing electrons (the Lewis model) with their wavelike properties, assigning electrons to a volume of space called an orbital.

A

Molecular orbital (MO) theory

85
Q

According to MO theory, covalent bonds result when
atomic orbitals combine to form ______.

A

molecular orbitals

86
Q

The covalent bond that is formed when the two orbitals overlap is called a ______ bond.

A

sigma (σ)

87
Q

Orbitals are ______. The number of molecular orbitals formed must equal the number of atomic orbitals combined.

A

conserved

88
Q

We think of covalent bonds forming through the
sharing of electrons by adjacent atoms. In such an approach this can only occur when orbitals on the two atoms ______.

A

overlap

89
Q

______ bonds are characterized by
• Side-to-side overlap.
• Electron density above and below the internuclear axis.

A

Pi

90
Q

The four C-H bonds in methane are identical because carbon uses ______ atomic orbitals.

A

hybrid

91
Q

An ______ orbital has a large lobe and a small lobe.

A

sp3

92
Q

______ are mixed orbitals that result from combining atomic orbitals.

A

Hybrid orbitals

93
Q

Carbon is tetrahedral. The tetrahedral bond angle is ______.

A

109.5°

94
Q

All the bonds in methane and ethane are ______. All single bonds in organic compounds are ______.

A

sigma (s) bonds

95
Q

The Two sp Orbitals Point in ______ Directions. The Two p Orbitals are ______.

A

Opposite, Perpendicular

96
Q

orbitals used in bond formation determine the ______

A

bond angle

97
Q

The shorter the bond, the ______ it is.

A

stronger

98
Q

A π Bond is ______ Than a σ Bond

A

Weaker

99
Q

Hydrogen-containing compound that produces H+ ions in solution

A

Arrhenius acid

100
Q

Hydroxide-containing compound that produces OH– ions in solution

A

Arrhenius base

101
Q

Substance that can donate a proton (H+ ion) to some other substance
̶ Proton donor

A

Brønsted–Lowry acid

102
Q

Substance that can accept a proton (H+ ion) from some other substance
̶ Proton acceptor

A

Brønsted–Lowry base

103
Q

When an acid loses a proton, it forms its ______.

A

conjugate base

104
Q

When a base gains a proton, it forms its ______.

A

conjugate acid

105
Q

A substance that can either lose or accept a proton
and thus can function as either a Brønsted–Lowry
acid or a Brønsted–Lowry base

A

Amphiprotic Substance

106
Q

An acid that supplies one proton (H+ ion) per molecule during an acid–base reaction

A

Monoprotic Acid

107
Q

An acid that supplies two protons (H+ ions) per
molecule during an acid–base reaction

A

Diprotic Acid

108
Q

Carbonic acid (H2CO3) is a ______ acid

A

diprotic

109
Q

An acid that supplies three protons (H+ ions) per
molecule during an acid–base reaction

A

Triprotic Acid

110
Q

______ acid, ______, is the most common triprotic acid.

A

Phosphoric, H3PO4

111
Q

An acid that supplies two or more protons (H+ ions) during an acid–base reaction

A

Polyprotic Acid

112
Q

Includes both diprotic and triprotic acids

A

Polyprotic Acid

113
Q

Transfers ~100% of its protons to water in an
aqueous solution
Equilibrium position lies far to the right

A

Strong Acid

114
Q

Transfers only a small percent of its protons to water in an aqueous solution
Equilibrium position lies far to the left

A

Weak Acid

115
Q

Hydroxides of Groups IA and IIA

A

Strong bases

116
Q

An equilibrium constant for the reaction of a weak
acid with water

A

Acid Ionization Constant

117
Q

Acid strength increases along with an increase in
______
Acid strength increases with an increase in the
______
Percent ionization increases with an increase in the
______

A

percent ionization, magnitude of Ka, magnitude of Ka

118
Q

The stronger the acid, the ______ the Ka.

A

larger

119
Q

The stronger the acid, the ______ the pKa.

A

smaller

120
Q

The equilibrium constant for the reaction of a weak
base with water

A

Base Ionization Constant

121
Q

The ______ indicates the concentration of protons is a solution.

A

pH

122
Q

pH values decrease as the acidity of the solution
______.

A

increases

123
Q

Solutions with pH values less than 7 are ______,
whereas those with pH values greater than 7 are
______.

A

acidic, basic

124
Q

A Measure of Acidity

A

pH

125
Q

pH = ______

A

-log [H+]

126
Q

Ionic compounds containing a metal or polyatomic
ion as the positive ion and a nonmetal or polyatomic
ion (except hydroxide) as the negative ion

A

Salts

127
Q

All common soluble salts are completely ______
into ions in solution

A

dissociated

128
Q

The chemical reaction between an acid and a
hydroxide base in which a salt and water are the
products

A

Neutralization Reaction

129
Q

In a neutralization reaction, what products are
formed?

A

Water and salt

130
Q

The Henderson–Hasselbalch Equation

A

pKa = pH + log [HA]/[A–]

131
Q

The ______ tells us whether (at a given pH) a compound will be in its acidic form (with its proton) or in is basic form (without its proton).

A

Henderson–Hasselbalch equation