Unit A - Bonding Flashcards
What are valence electrons?
Electrons in the highest energy level around the nucleus. They are found in the outermost energy level of an atom.
What is Electronegativity?
The tendency for an atom to attract valence electrons.
Electronegativity gradually increases as we move from the left to right in a period.
Electronegativity decreases as we move down the group.
What are the trends in the periodic table?
If it goes right electronegativity increases due to electrons in the valence getting more and more desperate to fill the orbitals.
If it goes down electronegativity decreases because the actual size of the molecules increases.
Right: Electronegativity increases - electrons in valence having more desperation to fill orbitals.
Down: Electronegativity decreases - actual size of molecules increases.
Which electrons determine the molecule’s shape?
Valence electrons
What is AXE and what does each letter represent?
A - # of molecules around the central molecule.
X - # of bonding pairs.
E - # of lone pairs.
What are the names of the possible 5 molecular shapes?
- Linear
- Trigonal Planar
- Tetrahedral
- Trigonal Pyramid
- Bent
What are the general AXE formulas?
AX2, AX3, AX4, AX3E, AX2E2
How do we know which end of the molecule is slightly positive?
We can know which end of the molecule is slightly positive by the plus sign.
Slightly negative?
It is when the atom that attracts the electrons more will get a slightly negative charge since electrons will spend more time around that atom.
What is a bond dipole?
Charge separation which occurs as a result of the different electronegativities of the bonded atoms.
What is so special about the number 1.7 when it comes to chemical bonding?
The thing that is special about the number 1.7 is that when the difference in electronegativity is greater than 1.7 then it will be ionic. When the difference in electronegativity is between 0.5 and 1.7 it is a polar covalent bond.
What are intramolecular forces?
Forces that keep the atoms within a compound “stuck” together.
Are they stronger than all of the intermolecular forces?
They are stronger than all of the intermolecular forces.
What are intermolecular forces?
Forces that are accountable for keeping the molecules together in solid, liquid, or gaseous form.
What are the 3 types?
London dispersion forces, Dipole-dipole forces, Hydrogen bonding