Unit A - Bonding Flashcards

1
Q

What are valence electrons?

A

Electrons in the highest energy level around the nucleus. They are found in the outermost energy level of an atom.

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2
Q

What is Electronegativity?

A

The tendency for an atom to attract valence electrons.

Electronegativity gradually increases as we move from the left to right in a period.

Electronegativity decreases as we move down the group.

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3
Q

What are the trends in the periodic table?

A

If it goes right electronegativity increases due to electrons in the valence getting more and more desperate to fill the orbitals.

If it goes down electronegativity decreases because the actual size of the molecules increases.

Right: Electronegativity increases - electrons in valence having more desperation to fill orbitals.

Down: Electronegativity decreases - actual size of molecules increases.

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4
Q

Which electrons determine the molecule’s shape?

A

Valence electrons

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5
Q

What is AXE and what does each letter represent?

A

A - # of molecules around the central molecule.
X - # of bonding pairs.
E - # of lone pairs.

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6
Q

What are the names of the possible 5 molecular shapes?

A
  • Linear
  • Trigonal Planar
  • Tetrahedral
  • Trigonal Pyramid
  • Bent
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7
Q

What are the general AXE formulas?

A

AX2, AX3, AX4, AX3E, AX2E2

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8
Q

How do we know which end of the molecule is slightly positive?

A

We can know which end of the molecule is slightly positive by the plus sign.

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9
Q

Slightly negative?

A

It is when the atom that attracts the electrons more will get a slightly negative charge since electrons will spend more time around that atom.

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10
Q

What is a bond dipole?

A

Charge separation which occurs as a result of the different electronegativities of the bonded atoms.

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11
Q

What is so special about the number 1.7 when it comes to chemical bonding?

A

The thing that is special about the number 1.7 is that when the difference in electronegativity is greater than 1.7 then it will be ionic. When the difference in electronegativity is between 0.5 and 1.7 it is a polar covalent bond.

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12
Q

What are intramolecular forces?

A

Forces that keep the atoms within a compound “stuck” together.

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13
Q

Are they stronger than all of the intermolecular forces?

A

They are stronger than all of the intermolecular forces.

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14
Q

What are intermolecular forces?

A

Forces that are accountable for keeping the molecules together in solid, liquid, or gaseous form.

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15
Q

What are the 3 types?

A

London dispersion forces, Dipole-dipole forces, Hydrogen bonding

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16
Q

Can you rank them in order of strongest to weakest?

A

Hydrogen bonding, dipole-dipole forces, London dispersion forces

17
Q

What determines the strength of the London forces?

A

The thing that determines the strength of the London forces is the greater the number of electrons in the atoms of a molecule the greater the London dispersion forces.

18
Q

What is hydrogen bonding and what atoms does it occur between?

A

It is when it is directly bonded to a highly electronegative atom.

The atoms that it occurs between are nitrogen, oxygen or fluorine.

19
Q

Can you use intermolecular forces to explain trends in melting points and boiling points?

A

I think we can use intermolecular forces to explain trends in melting points and boiling points. During high boiling point stronger forces are acting which means they are intermolecular forces because they are stronger than intramolecular molecules.

20
Q

Why are metals malleable?

A

Metals are malleable because bonds are between cations and a sea of electrons rather than between cations and cations; cations may be moved in the sea of electrons without breaking bonds.

21
Q

What is the metallic bonding model?

A

Metallic bonding model is an array of cations in a sea of valence electrons.

22
Q

Can you explain conductivity of solid ionic, aqueous ionic, and molecular compounds?

A

During the solid ionic, both the positively and negatively charged ions stay in place. There will be no current on a conductivity testing meter during the solid ionic.

During the aqueous ionic, it will conduct electric current since the ions are free to move toward the oppositely charged molecule.

During the molecular compounds, charges cannot leave the molecule and no electric current will flow.

23
Q

What is a Covalent Bond?

A

It is created when both electronegativities are high.

24
Q

What is a Ionic Bond?

A

It is created when the difference in electronegativities are quite large.