Unit 7: Reversible reactions and equilibrium + calculating equilibrium constant Flashcards

1
Q

When did scientists discover reversible reactions

A

1803

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2
Q

What does it mean for a reaction to be a reversible reaction

A

The forward reaction and the backward reaction are occurring at the same rate

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3
Q

What does equilibrium mean

A

to be in a state of balance

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4
Q

What type of reactions are reversible

A

insoluble, weak acids, weak bases

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5
Q

when does chemical equilibrium occur

A

when the opposing reactions equal the same rate

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6
Q

after equilibrium is reached has the reaction stopped?

A

No, the reaction has not stopped things are still happening but at the molecular level

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7
Q

what reactions are soluble

A

strong acids, bases and soulble salts

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8
Q

what is the Haber Process

A

nitrogen gas and hydrogen gas react to produce ammonia

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9
Q

how do you measure the progress of a reversible reaction

A

reaction quotient or Qc

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10
Q

when can Qc be calculated?

A

at any point of the reaction because it is not constant

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11
Q

what is the equation for the quotient reaction?

A

[products] / [reactants]

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12
Q

what is the reaction quotient now called when equilibrium has been reached?

A

called the equilibrium constant or Kc

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13
Q

Is Kc constant?

A

Yes Kc is constant

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14
Q

what does Kc tell us

A

product to reaction concentrations once equilibrium has been reached

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15
Q

What is Qc dependent on?

A

The progress of the reaction, that is why it can change over time

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16
Q

What happens when Qc has stabilized

A

equilibrium has been reached

17
Q

Kc =

A

Qc

18
Q

when can equilibrium occur in a reaction?

A

it can occur at any point of the reaction, and it is unique to that specific reaction

19
Q

what does equilibrium NOT mean

A

that the concentrations are the same

20
Q

what does it mean if K>1

A

the equilibrium favors products

21
Q

what does it mean if K<1

A

the equilibrium favors reactants

22
Q

what is the equation for the for the inverse of a Kc reaction

A

1/ Kc

23
Q

On a particle diagram, when can you tell that equilibrium has been reached

A

the mlcls are still but changing, but the ratio is consistent

24
Q

on a haber process graph, how do you know when reactants are favored

A

when the reactants are less than the products, and vice versa for the products

25
Q

what should you do when q is smaller than k

A

when q is smaller than k, then we need to increase the amount of products, and decrease the amount of reactants to increase Q

26
Q

what should you do when q>k

A

when q is bigger than k, we need to decrease the amount of products and increase the amount of reactants

27
Q

why can’t solids and liquids be included in an equlibibrium expression

A

they do not have concentrations

28
Q

which states are included in the equilibrium expression

A

aqueous and gases

29
Q

what changes the Kc value

A

temperature

30
Q

what should you do if you have a reverse reaction when trying to calculate equilibrium constant

A

take the inverse of the OG Kc

31
Q

what happens when you multiply a reaction by a factor?

A

raise the OG Kc to the power of that factor

32
Q

what should you look @ when trying to calculate the Kc value

A

always look at the first reaction

33
Q

what happens when you combine reactions

A

multiply the Kc constants

34
Q

what do you use to calculate equilibrium expressions

A

a rice table

35
Q

what do you do when an initial concentration or pressure is not given

A

assume it starts at zero

36
Q

what ratio will the changes occur in?

A

mole to mole

37
Q

what should you do if you don’t know the change or final concentration

A

use x

38
Q

How can you use Qc in calculating equil. express.

A

Qc can be used to see the way the reaction is going to shift, and compare with Kc