Unit 6 Water Treatment Flashcards
Impurities in a boiler can;
Result in lose of efficiency, and can create a dangerous situation that may result in catastrophic failure
Sludge
Produced elsewhere but carried along by flowing water, will deposit on the boiler heat transfer surfaces
Scale
Formation from salts, which have solubility in source water, but are totally insoluble under the conditions inside a boiler
Corrosion
Happens in the hottest areas of the boiler, includes water wall, screen tubes, and superheater tubes
Carryover
From impurities downstream of the boiler. Negatively affects the purity of the steam that contacts parts of the energy plant
Two methods of treating boiler water
External and internal water treatment
External water treatment
Takes place before the water enters the boiler
Internal water treatment
Adding specific chemicals to boiler water that target problematic impurities
Direct amine measurements can be made using a;
Gas chromatograph
Shock feeding only one type of biocide will result in;
Organisms becoming immune to it
Biological attack on cooling tower wood occurs when;
The cellulose deteriorates
Suspended solids
Substances that have not been dissolved, but are held or suspended in the water.
Examples of suspended solids;
Clay, sand, silica, organic materials
Particles smaller than ________ are considered to be dissolved solids
2um
Larger materials in water such as tree and branches are considered;
Not to be suspended solids, since they are easily dealt with using screens
If suspended solids are not removed;
They can form deposits within the boiler, which can reduce heat exchange, which in turn can lead to metal failure. Can also lead to erosion of metal surfaces or plug up equipment.
A higher concentration of suspended solids can lead to;
Foaming, which results in carryover or priming from the steam drum
Most common methods of reducing suspended solids externally;
Through gravity settling like clarifiers and pressure filtration
How to remove suspended solids internally;
Through boiler blowdown
Dissolved solids are usually:
Ionic compounds dissolved in water
Ionic compounds with calcium and magnesium cations are called
Calcium and magnesium salts
Brackish water
Water containing high dissolve salt concentrations
When conducting water hardness tests, calcium and magnesium appear as
Dissolved solids
Ppm is equivalent to
Mg/L for liquids
Bicarbonate of calcium and magnesium
Cause temporary hardness because they will precipitate out of the water at temperatures below the boiling point. these can be removed before they enter the boiler
Sulfates of calcium and magnesium cause;
Cause permanent hardness since they do not precipitate until the water boils at which point they form hard, dense scale on boiler surfaces
Technologies that remove silica
Lime softening, reverse osmosis and ion Exchange
Two ways sludge and scale reduce heat transfer
Scale insulates boiler surfaces, impeding heat transfer
Scale reduces the flow of boiler water
Sludge and scale build-up can lead to
Boiler overheating
3 ways foaming can occur in a boiler
Dissolved solids or by the presence of oils or suspended solids
Dissolved solids are most commonly removed externally using
Some sort of ion exchange such as lime softeners cation exchangers using zeolites, and anion exchangers and demineralizers
Dissolved gases
Gases that are in solution
Examples of dissolved gases
Nitrogen, ammonia, oxygen, and carbon dioxide
As the temperature increases, the solubility of gases in water tends to
Decrease, which results in the release of dissolved gases
2 dissolved gases of primary concern to power engineers
Oxygen and carbon dioxide, because of their ability to produce boiler corrosion
Dissolved oxygen in boiler water
Produces a form of ferrous metal corrosion due to improperly treated feed water.
While dissolved in boiler water, oxygen causes
A form of corrosion called pitting, which is localized and hard to spot
Oxygen removal is accomplished by a combination of
External and internal methods
Carbon dioxide, when dissolved in water forms
Carbonic acid
When condensate forms, the carbon dioxide dissolves, forming
Carbonic acid
Carbonic acid causes
Grooving on metal surfaces of condensate return lines
As more dissolved carbon dioxide is present,
The pH drops
Carbonic acid formation in condensate lines can be inhibited by adding
Neutralizing agents internally to the boiler or directly to the steam lines
The lower the pH value,
The more acidic the water is
A high pH value indicates
A basic or alkaline solution
Hard and softened water contains
Carbonate and bicarbonate salts of calcium, magnesium and sodium
A safe range of pH is
Between 8.5 and 12.7. Outside this range, corrosion can be significant
Magnetite
Prevents further oxidation of the boiler heat transfer surface. Therefore considered highly beneficial
Caustic embrittlement
May result from high pH levels. Very difficult to detect, due to its fine cracking. Caustic embrittlement commonly results in boiler metal failure
High pH boiler water may cause
Foaming in the boiler drum
Most boilers operate with a pH of about
9.5 to 10.5, balances corrosion and foaming
Sodium hydroxide, also known as caustic soda is commonly added to
Raise pH
To lower pH
The boiler is blown off or it’s continuous blowdown rate is increased
Three main steps Municipal potable water systems use to purify their water
Remove solids, remove pathogens, disinfect
When the temperature is low, water holds
Slightly more oxygen
Turbidity
Is a measure of water cloudiness
Municipal Water Treatment process
Clarification, filtration, disinfection
When boilers use Municipal Water as feedstock, it requires further processing. This will;
Reduce hardness, remove oxygen and other dissolved gases, adjust the pH
External treatment for dissolved oxygen will only lower the level to the range of
10 ppb
The first stage of water treatment is usually
The removal of suspended solids
Settling ponds
Slow or delay the velocity of water, this allows suspended solids to settle, by gravity, to the bottom
Clarifier vs settling pond
Clarifiers can finish in an hour or two, while settling ponds may take days. With clarifiers, the accumulations of solids are drained from the bottom
How a clarifier works
Water is introduced in the centre of the clarifier, and flows to the bottom middle section. As the water flows, the particles settle out, and are removed by a rake that moves the sludge to a central blow off point
Backwashing
Involves reversing the flow of water through the filter, thus freeing trapped solids. Backwash flow rate must be correct, otherwise it will be not be effective
Once the initial removal of suspended solids is done, the water usually
Passes through a filter to remove the last of the suspended particles
Four common types of filters
Pressure filters, filter Aid tubular filters, cartridge filters, activated carbon filters
Overtime, filters become plugged with suspended particles
And must be backwashed
Filter Aid tubular filter
Closed cylindrical housing that contains several screen type cylindrical tubes. Can be quite large and similar in concept to an air cleaning baghouse
Cartridge filters
Similar to an oil filter in an automotive engine. Outer shell can be either steel or plastic. Inner cylinder made of woven fibres
Activated carbon filter
Often used to remove taste or odours from water. Also used to remove chlorine, especially from Municipal Source water. Not very effective against dissolved solids
Chlorine must be removed to protect;
Reverse osmosis membranes and ion exchange material
Water is considered hard when it contains over;
Over 120 PPM (120mg/L) of calcium or magnesium ions
Scale could possibly lead to;
Deposit corrosion, and even cause metal failure
Calcium and magnesium ions are unaffected by;
Clarifiers or filters
Four methods to soften water
Lime soda systems, sodium zeolites, demineralizers, reverse osmosis
Lime soda softeners
Lime reacts with impurities that cause carbonate hardness. Soda ash reacts with impurities that cause non carbonate hardness. After these reactions, they become suspended solids, and are no longer dissolved solids. Now they can be removed using clarification, flocculation, or filtration.
Two categories of lime soda softeners
Hot ( 95-100°C )
Cold ( 25-30°C )
Lime soda hot process versus cold process
Hot process is more common because it is quicker, and the solids are easier to filter out. The hot process can remove silica, whereas the cold process cannot
Sodium zeolite system
Rely on the principles of ion exchange to soften water. They cost less than lime soda softeners, are easier to control, and the chemicals are safer for operators. Magnesium and calcium ions are replaced with ones that do not cause scale and are highly soluble. Can bring the hardness down to zero, while the sodium increases dramatically
When a sodium zeolite softener is removed from service the following procedure is followed;
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- Backwashing
- Brining (regeneration)
- Slow rinse (displacement)
- Fast rinse