Unit 12 Typical Industrial Plant Configurations Flashcards
Steam is the principal energy transfer medium that industry depends on for its process applications. It provides energy for process
Heating, pressure control, mechanical drives, electrical generation and component separation
Advantages of steam
Low toxicity, transportability, high efficiency, high heat capacity and low acquisition and production costs
Most of the heat contained in Steam is in the form of
Latent heat
Heat transfer fluid systems (HTF) - hot oil
Industrial Systems were a special heat transfer fluid, not water, is circulated by a pump through a fired heat exchanger.
HTF systems may be preferred when the temperature is above
175°C
Steam is generated in a boiler by
Transferring thermal energy released in a heat generating process, into liquid water. The additional energy carried by the steam is transferred out of the steam by thermal or mechanical action
Generation
3 heat conversion mediums
HTF, Compressed Gas, Steam
The efficiency of distribution is affected by
Thermal insulation, piping and component separation Technologies
Steam accumulators
Allow the additional energy in excess steam to be discharged into a pressure vessel partially filled with water
During system startup, steam traps allow
Air in equipment and lines to escape
Examples of end use processes
Process heating, mechanical Drive, electrical generation, enabling chemical reactions, fractionation of hydrocarbon components
Two types of processes
Physical and chemical
Absorption process
Absorbing agents called molecular sieves, are used as a filtering medium. The medium separates on the basis of physical size of molecules being different
Crystallization process
A crystalline substance is separated from a non-crystalline one by cooling the solution, and separating the components via a separating process such as filtering or centrifugation.
Dilution
Steam is often used to dilute a process gas which can reduce solid buildup on heat exchangers
Distillation/fractionation
During distillation, usually in a fractionation tower, compounds are separated into fractions by differential boiling points.
Process of drying or evaporation
The vaporization and removal of water or other liquids from a solution
Process quenching
Used to cool and thus stop High temperature reaction processes
Solvent extraction
Separation process which separates substances by using differences in solubility between compound in complex mixtures
Stripping Towers
Steam pulls unwanted contaminants from a process fluid and directs them to waste or back into the process
Thermo-mechanical
Direct conversion of thermal energy into mechanical action, which occurs in the final stages in industrial plants
Thermo-mechanical pulping (TMP)
Direct conversion of mechanical action into thermal energy
Chemical conversion process
Converts one compound into another by chemical reaction. Involves chemical manipulation of molecular size or chemical structure
Molecular size reduction
Involves converting a surplus of unsaleable product with a large molecular size into a smaller one that is in demand
Chemical structure adjustment
Rearranges the chemical structure of a compound or mixture to create a different product, or to improve performance in the product.
A hot oil system is one that uses
Oil as a thermal fluid, in place of steam or water, to transfer heat from a central source to other areas of the plant. Consists of a heat source and piping to distribute the heated oil and return the cooled oil. Heat exchangers transfer the oils heat to other fluids and the pump to create and maintain required circulation
A hot oil system is very much like a hot water heating system, but the difference being that
The fluid chosen has a much higher boiling point than water and the Steam runs at a higher temperature. So, heat transfer fluids exhibit a much lower vapour pressure than Steam.
Heat transfer fluids, especially hot oils are widely used in
High temperature processes, where low pressures are preferred
HTF vapour is generative at higher temperatures but
Exhibits lower pressures
The Vapor phase heat transfer system has even and constant
Heating temperature and the temperature difference between Inlet and Outlet of heat can be controlled within a 1-2°C range.
Vapor systems can be used if higher temperatures and heat transfer rates are required but
They are generally more expensive and complex than liquid systems.
Heat transfer fluids will degrade over time in
Elevated temperatures and oxidized if in contact with atmospheric air.
Many heat transfer fluids have relatively High
Coefficient of thermal expansion
Heat transfer fluids are non corrosive, and any corrosion problems within the system are usually caused by
Contaminants such as cleaning fluids left in the system at startup or leakage of process fluid in the system
The operating range between efficient operation and the point at which degradation of the oil occurs
20-30°C difference
Although heat transfer fluids have high flash points, the system almost always operates
Above the flash point
Liquid thermal systems generally consists of
A pump, fired heater, and expansion tank to allow for expansion and contraction of hot oil as it heats up and cools down
Three classes of heaters used in HTF systems
Radiant, convection and a combination of the two
Radiant heaters
Combustion gases do not flow across tube surfaces. Heat is transferred from the burning fuel to the tubes by radiation from the furnace space. Low efficiency (40-50%)
Convection heaters
Combustion gases flow across the tubes, heat is then transferred by conduction through the tube to the hot oil flowing in the tubes. Higher efficiency (75-85%)
Combination radiant and convection heaters
Favoured due to their efficiency in larger unit
Updraft fired heater
Radiant and convection tube sections
When operating the expansion tank, the tank level should be between _______
The temperature in the tank should be less than _______ to prevent fluid oxidation
2/3 and 3/4
60°C
Two pumps are usually installed in a hot oil system;
One operating and the other on standby
In order to maintain the standby pump at operating temperature _______
The suction valve of the standby pump should be left open all the time to allow a small amount of oil to flow backwards through the pump.
Hot oil pump should be located
At a level below the expansion tank to provide necessary static head to avoid possible cavitation in the pump suction
Two pumps used for liquid thermal systems
Usually a centrifugal pump, but sometimes gear pumps are used
Petroleum refinery
Complex plant that contains several individual process plants. Each plant has a specific function
The overall goal of a refinery
The separation of hydrocarbon components in the crude oil and modification to maximize production of high demand products.
Gasoline boils within the range of
30 - 300°C
Examples of number 1 oils
Gasoline and kerosene
Distillate fuel oil
Distillable hydrocarbon liquid mixtures of lower volatility than kerosene. Number 2 oil
Residual fuel oil
The material remaining as an evaporated liquid from distillation or cracking processes. Used mainly as boiler fuel and ocean-going ships. Number 6 oil or bunker C
Aviation jet fuel
Blended grades of petroleum distillate suitable for use in jet engines. Have high stability, low freezing point and overall High volatility
Petro chemical feedstock
Refinery products having low molecular mass and high purity.
Examples of petrochemical feedstocks
Ethane, ethylene, propylene, acetylene, butane, butadiene, benzene
Crude petroleum
Mixture of hydrocarbon molecules of many different sizes and shapes.
The boiling point of hydrocarbons increase with
The number of carbon atoms
The first processing stage in a refinery separates fractions by
Boiling point ranges. Separates crude oil into fractions by increasing the boiling point. It is heated to vaporize it, and then the vapour is cooled gradually. As the vapour cools, heavier molecules condense first and are removed. Usually done in fractionating or distillation Towers.
The second stage in the refining process
Convert separated fractions into various product streams. Involves additional separation and processes that alter the molecular structure, like Hydrotreating, cracking, forming and alkylation
Once the products are formed,
They are further processed to remove undesirable contaminants like sulphur and carbon dioxide. Raw products are then Blended and additives are introduced to produce desired products.
Before entering the separation and chemical reaction processes, crude oil must first be
Heated. Initially with a heat exchanger, then a furnace.
After heating, the crude oil enters the
Distillation column. The crude separates into liquid and Vapor. Vapor Rises up the column, up the trays, as it bubbles through the barrier “bubble cap”. The liquid filled up the tray and flows into a secondary distillation column “stripper column”.
Stripper column
Injects the steam into the fraction to extract Vapor which travels with the stripping steam back into the main column.
Lighter hydrocarbons, which are recovered of the lowest temperatures;
Butane and liquid petroleum gases, gasoline blending components, naphtha
Mid temperature range products
Jet fuel, kerosene and distillates
Heaviest products
Residual fuel oil, recovered at temperatures sometimes over 530°C
Additional stages of processing
Hydrotreating, reforming, catalytic cracking and alkylation
Three groups of petrochemical feedstocks
Olefins, aromatics, synthesis gas (syngas)
Olefins
Doubly bonded carbons. Includes; ethylene, propylene and butadiene. Produced in the cracking process assisted by Steam
Aromatics
Includes benzene, Toluene, xylenes. Produced in the reforming process
Synthesis gas (syngas)
Mixture of CO and H2. Produced in lean combustion or steam reforming.
Steam generation Powers much of the refinery, so it is generally
The first system to start up and the last to shut down.
Most plants operate at least three distinct steam systems;
High pressure, medium pressure and low pressure. Systems are interconnected through let down, or pressure reducing stations, which exhaust the high pressure system to the medium system and the medium pressure system to the low pressure system.
High pressure steam system range
Low pressure steam system range
4130 - 10 340 Kpa
103 - 415 Kpa
Stripping Steam
Steam is injected into sidestream stripping columns to facilitate the movement of light products up the column. Injected steam carries the lighter hydrocarbons out of the stripper column and back into the main fractionating tower.
The most common method of heat tracing flow lines, valves, metres and Recorders is to use
Steam
Steam stations
Used in Refinery units, so technicians can hook up a steam hose to thaw frozen equipment and lines
Purging equipment with steam
Effective method of preparing a Refinery hydrocarbon unit for turn around. Cleans equipment and Towers in preparation for vessel entry.
Canada’s oil sands produce a heavy oil typically referred to as
Bitumen. The upgrading process for this oil converts bitumen into a high-quality, Light, low sulphur crude oil.
Bitumen diluted with naptha cut as a mixture is called
Dilbit
The first step in the upgrading process of dilbit is to remove
The naturally occurring light gas oil component and to recover the diluent naphtha. This is done in the diluent recovery units