Unit 4 Lasers Flashcards

1
Q

What is a LASER, difference btw ordinary and laser

A

light amplification stimulated emission radiation

ORDINARY
not very intense
Moderatly Monochromatic
non directional
High divergence
Moderately coherant

LASER
very intense
Highly Mono Chromatic
Directional
Low Divergence
Highly Coherent
(phi diff neither equal not constant)

HOW is light produced
interaction of atoms with EM radiation

1) Absorption
2) Spontaneous Emission
3) Stimulated emission(Einstien)
atom-> discrete energy levels

Spontaneous: makes atom go to higher energy/absorption once it happens 2 things can happen: if u dont interfere it drops and E is released in terms of photons
hv + E1=E2
2) when photon projected at atom it forces atom to jump down(photon not absorbed by atom) and hence it also releases hv, thus
hv+E2=E1+2hv(Stimulated emission)

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2
Q

properties of laser

A

1) Monochromaticity (spectral line broadening)

Light from a laser typically comes from an atomic transition with a single precise wavelength. So the laser light expected to have single spectral colour

laser light is highly
monochromatic but not truly monochromatic!

2) Coherance
In the stimulated emission the emitted photons are “in phase”

phase difference btw 2 points remain constant in time

temporal coherance
If the electric fields of a laser are sampled at different times and
if the samples exhibit a well defined phase correlation, then the
laser is said to be temporally coherent

Spatial coherence:
* When EM fields at different spatial regions have a phase correlation (either zero or a constant phase difference), the beam is said to be
spatially coherent

phase difference at any location remains constant for constant intervals of time

  1. Divergence (directionality): very low divergence
  2. Intensity
    * The high intensity of a Laser arises out of the properties of
    Monochromaticity, Coherence and Low divergence
    A lot of energy is concentrated in a small cross sectional area
    High power IR lasers are used to cut metals
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3
Q

Helium Neon laser

A

1) Material He and Ne 10:1
2) pumping -> electrical (using e-) DC source
3) Resonant Cavity: glass plates(Brerusters window)=> to polarize light

3s →2p⇒632.8 nm,
3s → 3p ⇒ 3391.2nm,
2s → 2p⇒1152.3nm

Absorption levels in the He atoms and lasing levels in the Ne atomic transitions
pumping starts from He

Energetic electrons in the discharge excite electrons in the He atoms to 23
S and 21S states which are meta-stable

Excited He atoms transfer their energy to Ne atoms by collisions and excites the Ne atoms to 2s and 3s levels (Energy levels of these Ne states are close
to the He excited states -This process is referred to resonant energy transfer)
This create population inversion

Ne atoms de-excites to the ground states through the intermediate states 3p and 2p

Transition from 3s to the 2p states gives the
characteristic red laser (wavelength of 632.8 nm

3s to 3p and 2s to 2p lines give rise to wavelengths
in the Infra red of 3.39 μm and 1.152 μm

WORKING
apply 1000V
e get energised in their journey from cathode to anode
Energetic e bombard He then exciting it e+He=e+He
Energetic He bombard Ne thus exciting it He+Ne=He+Ne

  • low power laser
    ISA if Ne produced laser why He?
    helps in population inversion, uses lesser energy

Why do u need methane
will absorb IR via rotational /vibrational

CH4 absorbs 99% IR

Uses four-level pumping scheme

Lasing operates in continuous wave mode

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4
Q

Einstien coefficients (probability measures)

A

ISA! what are these coefficients for
=> for atomic probability
=> each energy level, atom depends on 2 energy level
A –> A21
B –> B12, B21 are EINSTIENS COEFFICIENTS

Rate of absorption
Ra ∝ N1
Rab ∝ E(v)
Rab=B12N1E(v)

B12 is coefficient of absorption

Rate of Spontaneous emission
R spe ∝ N2
R spe = A21*N2

A21 = coeff for spontaneous

Rate of Stimulated emission

Rste ∝ N2
Rste ∝ E(v)
Rste = B21N2E(v)

B21 is coefficient of stimulated emission

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5
Q

condition for lasers

A

Under thermal equilibrium, N 1&raquo_space; N2 Which leads to R Ab > R StEm

RA»»R StE
N1»»N2

TO PRODUCE LASER:
Rsfe&raquo_space;> Ra => N2»»N1
ISA =>
(population inversion) =>
getting more atoms on the higher energy level than in lower energy level

Stimulated Emission is crucial for laser emission
* Only Stimulated Emission can ensure same wavelength and phase (Coherence)

Stimulated Emission has to dominate over spontaneous
Emission and absorption during emission
*For this to happen, we must have Population Inversion
(N2>N1)
*To achieve population inversion we need an external energy
source called energy pump
*Thermal equilibrium is disrupted

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6
Q

two level system ISA!!

A

intially N1>N2
need N2>N1

has E1 (lower), E2(higher level)

by pumping we can move e- from E1 -> E2, excited level has short time, thus it will be de-excited to lower level

thus population inversion cannot be achieved

problem with 2 system: doesnt have a meta level state

meta level state: an excited energy level with higher life time

ISA !!!!
can 2 level system get population inversion

=> NO, at best can get N1=N2

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7
Q

Three level system

A

has three energy levels E1(Lower Lasting), (sharp level)
E2(Upper Lasting, meta stable),
E3 (broad level)

From pumping mechanism we can raise the atoms from E1 -> E3 excited level, lifetime is very short, this they quickly transfer to E2, thus atoms can be retained for a long time, thus population inversion is present

Thus stimulated emission of radiation takes place btw meta stable state and ground level leading to LASER light

POPULATION inversion takes a lot of energy/pumping power required

as population inversion is created btw excited level and boundary level

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8
Q

Requirments of Laser

A

Material -> atoms/molecules/ions/colloids/semi-conductor

Law required=> energy levels that support population inversion

Pumping Source: to excite atoms to a higher energy levels
uses electrical/optical currently

Resonant Cavity:
has 2 mirrors on both sides

makes sure laser bream travels in only one direction

also used for light amplification

Photons travelling in directions not perpendicular to the mirrors are not amplified

ISA! why are the mirrors there:
to increase the optical length

Consists of two mirrors of various
geometries and coatings creating standing waves

Resonant cavity must obey the condition that the gain should be greater than or less than to threshold gain!

Round trip gain
Let R1 and R2 be the reflective coefficients of the mirrors
* L, the distance between the mirrors

In a round trip even if we achieve a gain compared to the loss over billions of such trips the total gain would be significant

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8
Q

4 level energy level system

A

E1
E2(lower level, excited level)
E3(meta level state, Upper level )
E4

Raising atoms from E1 to E4, atoms then make fast transitions to E3, btw E3 and E2 laser is produced, from E2 atoms go back to E1 and the cycle repeats

Since both E2, and E3 are excited levels, pumping power required for population inversion is lower

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9
Q

CO2 Laser 4 level

A

Material - CO2, N2,He
pumping- electrical
Resonant Cavity: A specialized optical resonator

Symmetric stretching (n00)
2. Asymmetric stretching (00n)
3. Bending mode(0n0)
are quantized energies

  1. Symmetric stretching:
    Bond lengths always equal
    2 Asymmetric stretching:
    Bond lengths unequal
  2. Bending mode

WORKING

  • switch on high voltage
    electrons get energised
  • energetic electrons bombard N2,exciting it
    -excited N2 bombards CO2 thus exciting Asymmetric mode

CO2(001)=>CO2(100)+radn
λ=10.6 μm
CO2(001)=>CO2(020)+radn
λ=9.4 μm
CO2(100)=>CO2(020)+radn
CO2(010) + He => CO2(000)
He* collides wiht walls thus losing energy

ISA: if Co2 produces laser why is N needed

N is meta stable thus has population inversion

ISA why is Co2 more efficient than atomic lasers,
efficiency of Co2 more efficient than He

Extensively used for welding, cutting ,drilling

Uses four-level pumping scheme - continuous wave mode

Uses four-level pumping scheme - continuous wave mode
* The active centers are CO2 molecules
* Helium (He) helps in the depopulation of lower levels, also as He has
thermal conductivity to keep temperature of CO2
low (to avoid
population in the lower level by thermal excitation).

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10
Q

Ruby Laser

A

Material Al2O3(passive)+Cr 3+
pumping: optical
Resonant Cavity:
Silver coatings of the polished ends of the rod form the mirror arrangement

The ends cut and polished at Brewster’s angle also
eliminates the need of mirrors.

wrapped around with a tub of Xe, around a rod doped with Cr

active component produces laser, passive is support system

Ruby => pulsed laser system

➢This corresponds to photons with 550 nm
(green) and 410nm (blue) wavelengths as the
absorption wavelengths

One of the intermediate energy states of Cr3+
ions is a Meta Stable
The transition from the upper absorption
energy levels to the intermediate state is
through non radiative transitions.

This leads to an increase in the population of
the intermediate state while the population of
the ground state is depleted rapidly.

Non radiative transitions
Thus, For a short duration of time the population of the intermediate state > the population of the ground state - POPULATION INVERSION

TRANSISTIONS FROM THE INTERMEDIATE STATE TO THE GROUND STATE CAN
LEAD TO PHOTONS OF THE STIMULATED TYPE leading to a LASER with a
wavelength of 694.3 nm.
Typical ruby laser pulse widths are of the order of a millisecond.

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11
Q

semi conductor laser

A

gives off light => when it is forward biased

semiconductors with a direct band gap

DIRECT BAND:ISA!!
GaAs(similar to Si) -> LED
➢ Conduction band e- can recombine directly with a hole in the valence band
=> recombination => spontaneous, stimulated;

hole doesn’t move only e- moves

INDIRECT band gap
releases heat

=>λ=885 nm (IR)
=> a barrier btw n, p
materiail

Active medium: Heavily doped direct band gap semiconductors
* Energy Pump: Electrical
* Laser Cavity: Two opposite sides of diode laser are cleaved for
emission of laser

electron meeting hole -> recombination=>
light(1.4 ev), Heat

  • low cost, simple, compact and portable
  • small in size
  • operate at low powers
  • Have high efficiency of the order of 40%
  • Mass produced
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12
Q

LASER HOMOJUNCTION AND HETROJUNCTION

A

Homo junction
n, p type are heavily doped

-> Heat produced =>high
a barrier btw n, p

HETRO JUNCTION

material => AlGaAs, GaAs

(Al=> Refractive index lower compared to GaAs) (As=> Eg increases (2ev))

=> Charge confinement:
GaAs active layer =>
lower band gap than AlGaAs layers
GaAs => recombination occurs here
=>High efficiency by
Charge confinement
=> energy pit=> more recombination

ISA=> what produces laser/name of mechanism => double Hetro Junction

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13
Q

Essential features of laser

A

1) mono chromatic,
degree of mono chromacity = Δv/v
Δv= spread of f, v=central f
-> line widh => Δv

CAUSES OF BROADNING:
1) Natural broadening of energy gap
>Doppler shift ->gas lasers >Collisional broadening:
interruption in radn, when atom collides a atom releasing radn

2) Coherence:
ISA numerical = Zc = c/Δv
Zc-coherence length

3) gain curve=>frequency comb-> series of discrete equally spaced f lines
ISA =>MADE OF locking’s(same phase wavelenghts) all have phases lined up

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14
Q

Holograph vs normal pic

A

PICTURE
2D pic, lacks depth info
▪ Captures the intensity of light reflected from an
object on a film
▪ no info of the phase of the EMF field

HOLOGRAPH:
3D images =>
capturing phase and intensity

ISA=> DIFF btw real and virtual image, (are laterally inverted)

interference of the reference beam
with light reflected from the object => hologram

recorded interference pattern => 3D image

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15
Q

Dielectric

A

Dielectric: material is kept in an electric field inside weaken?
Eo=σ/eo => E=Eo/Er
Er=10, E=Eo/10

atom with electric field =>
-> atom stretched, when electric field if produced => portion of e- cloud,
region of ‘+’ charges

new E’ field opposing E

E=Eo/En => E<Eo

NUMERICALS:
σ’=σ(1-1/εr)
OR
q’=q(1-1/εo)

the atom arrow => big Phat dipole moment

μ/V= ∑μ/V

P(dielectric polarization)=>
separated center of ‘+’ change to center, of ‘-‘ change

P=μ/V = σ’
XeoE

ISA
Cause of polarization types of polarisation on electric field:

Deformation of atomic Electric field => universal in all atomic

-> Ionic probability
Pi -> due to movement of ions of in ionic crystals to the presence of E

deformation -> electron ionic-> moving
Before ∑μ=0
After ∑μ != 0
∑μ/V =Pi !=0

ISA -> total polarisation
P=Pe+Pi

DOES TEMP AFFECT ions => NO, independent of T, as separation of ions is by equal amount

16
Q

H20

A

dipoles vertical are equal at 104 degree, horizontal dipole will cancel out

Orientational polaristion
Net μ != 0=>all dipoles wont be completely orient due to
ISA => thermal affect makes H20 oscillate
=> H20 neighboring atoms affect atoms next to it

Thermal energy affects it
Polarization ∝ 1/T

=> Pd

17
Q

Orientational or dipolar Polarization

A

Pd ∝ 1/T
Structural Interface
Different Phase(Diff resistivity)
Space charge polarization on interfacial polarization

unequal charges, concentrations at the boundary, of multi-phase materials

Space charge or Interfaval polarization Ps ∝ 1/T

total P=Pe+Pi+Pd+Ps

E=Eo-E’
E=Eo/eo
P=(er-1)E

P= σ-eoE
Pd =eoE+p
B=μo(H+M)

ISA => what is P due to => Bound charges
=> P due to => free charges
=> E due to => both
=> E is a macroscopic (and its average)

ISA=> Eo+Edipole (dipole-dipole interaction)
=Eint
Eint=Ei => local field or internal field or macroscopic field

μ ∝ E
polarizability (atomic property )

ISA!
CLAUSSIS -MOSOTTI
ϵr-1/ ϵr+2 =N(Z)/3ϵo

SIGNIFICANCE OF RELATION: relates an atomic property to a bulk property (Eg)
bulk => E=Eo/Er

18
Q

special materials

A

special dielectric
Ferromagnetic
Piezoelectric => PZT(lead zirconate titanate)
pyroelectric

centrosymmetric

material’s structure where it is symmetric about its center. every point in the material, there is an equivalent point equidistant from the center but in the opposite direction.

ISA
dielectric=>piezoelectric=>pyroelectric=>ferroelectric

Ferro Materials:
-> similar to ferro magentic
=> spontaneous polorisation
=> shows hysteresis behavior
=> above transition = paraelectric

VERY IMP = Bariu titanate BaTiO3(water purification)
ISA=> is this unit cell electrically neutral? YES

dipole=> Ba2+ up, O2- down, Ti4- down when E is upwards

In paraelectric, E applied is polarized else, 0 dipole

2) is it a dipole (effective positive charge= effective negative charge)
NOT a DIPOLE

ISA = explain phase transition of BaTiO3
Curie temp = 120
>120 = paraelectric (cubic, non-polar)
120-5 = distortion (tetrahedral phase)
2nd phase transformation 2M
5-90=orthorhombic(distortion), along body diagonals

19
Q

ISA what is the most significant Feature:

ISA=> Ferro electric, why does the curve go up

ISA=>short notes on properties, application of piexxo, ferro(etc)

Non linear optics

A

Spontaneous Polarization can be reversed

domains break, became more mobile
=> polarizations increase

NLO
P=XϵoE
X=> isotropic anstropic

Large E => Non linear effects
P=P1+P2+P3+
Pl=XϵoE+X2ϵoE^2+X3ϵoE^2

SHG=> second Harmonic generation