unit 4 Flashcards

1
Q

Alkali metal

A

An element in Group 1 of the periodic table. These elements are extremely reactive and will react spontaneously with water creating hydrogen gas and hydroxide ions in solution.

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2
Q

Alkaline Earth Metal

A

An element in Group 2 of the periodic table. These elements are reactive (but less so than Group 1), creating hydrogen gas and hydroxide ions in solution.

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3
Q

Anion

A

A negatively charged ion

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4
Q

Atomic radius

A

Half the distance between adjacent nuclei. Size of an atom in Picometers (pm)

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5
Q

Brittle

A

The ability to be crushed into pieces when hammered, a property of nonmetals.

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6
Q

Cation

A

A positively charged ion.

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7
Q

Diatomic Molecule

A

A nonmetal atom that forms one or more nonpolar covalent bonds with another atom of the same element to form a molecule consisting of the two atoms when there is no other element to bond with. Elements that do this are Br, I, N, Cl, H, O and F. BRINClHOF like brinklehoff

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8
Q

Ductile

A

The ability to be stretched into a wire, a property of metals.

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9
Q

Dull

A

The lack of ability to reflect light efficiently, a property of nonmetals.

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10
Q

Group

A

Columns down the periodic table that contain elements with the same number of valence electrons and thus similar chemical properties. Aka “families”

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11
Q

Electronegativity

A

The relative ability for an atom to gain an electron. Fluorine has the highest electronegativity 4.0. INCREASES across a period and DECREASES down a group

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12
Q

Effective nuclear charge

A

The overall attraction to the nucleus that a valence electron experiences. This increases as the # of protons increases and the occupied number of energy levels remains the same

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13
Q

Halogen

A

An element in Group 17 of the periodic table. These elements are extremely reactive, not as much as groups 1 and 2. e.g. fluorine, chloride, bromine, etc

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14
Q

Ionization energy

A

The energy required to remove an electron from the valence shell. Unit: kJ/mol Kilojoules per mol. It INCREASES across a period and DECREASES down a group.

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15
Q

Ionic radius

A

The size of an ion compared to the original atom. Metal atoms lose electrons and form + charged ions that are SMALLER than the original atom, nonmetal atoms form – charged ions that are LARGER than the original atom.

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16
Q

Luster

A

The ability to reflect light, a property of metals.

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17
Q

Malleable

A

The ability to be hammered or rolled into thin sheets, a property of metals.

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18
Q

Metal

A

Elements that have low electronegativity and ionization energy and large radius that tend to lose electrons to form chemical bonds. Most of the periodic table is metals

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19
Q

Metallic Character

A

describes the set of chemical properties that are usually associated with the elements classified as metals in the periodic table ie. LOSING ELECTRONS conductor, malleable, ductile. increases <- and v

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20
Q

Metalloid

A

Elements that exhibit properties of both metals and nonmetals. B, Si, Ge, As, Sb, Te (sometimes Po and As)

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21
Q

Orbital

A

The location in the electron cloud with the highest probability of finding an electron.

22
Q

Monatomic atom

A

A molecule composed of just one atom

23
Q

Noble gases

A

A Group 18 element on the periodic table. These elements are nonreactive, with a full valence shell (8).

24
Q

Nonmetal

A

Elements that have high electronegativity and ionization energy and small radius that tend to gain or share electrons to form chemical bonds.

25
Properties of metals
good conductors of heat and electricity, dense, malleable, ductile, lose electrons easily, high melting points, lustrous, solid at room temp (EXCEPT MERCURY)
26
Properties of non metals
bad conductors of heat and electricity, low density, brittle, gains electrons easily, low melting points, dull.
27
Properties of metalloids
variable conductors of heat and electricity, variable density, brittle, gains or loses electrons, variable melting points, and lustrous.
28
Nonreactive
Not capable of readily gaining or losing e’s or undergoing a chemical change/reaction. INERT. e.g. noble gases
29
Oxidation
The loss of valence electrons from an atom or ion, resulting in the increase in oxidation number of an element.
30
Periodic law
Properties of elements repeat in a predictable way when arranged by atomic number
31
Periods
Rows across the periodic table with elements having the same number of occupied principal energy levels.
32
Rare Earths/Inner Transition metals
F Block elements. Fill the F orbitals. Many are radioactive.
33
Reactivity
aka “activity” is a measure of how readily a substance undergoes a chemical reaction.
34
Reduction
The gain of valence electrons from an atom or ion, resulting in the decrease in oxidation number of an element.
35
shielding effect
a decrease in attraction between electrons and the nucleus in an atom due to distance and repulsion between extra electrons and energy levels between the nucleus and valence electrons. More internal or “core electrons” lesson the effect of the nucleus on valence electrons
36
shielding electrons
non-valence electrons, AKA core electrons
37
transition metals
Metals from D Block. Display classic metallic properties. Hard, shiny, ductile, malleable and they make COLORED IONS in solution and colored crystals as a solid. They also have multiple oxidation numbers (polyvalent)
38
Z effective
The net attraction from the positive nucleus that a negative valence electron can “feel”. The core electrons are said to shield the valence electrons from the full attractive forces of the protons in the nucleus. Zeff = Z -S Z is nuclear charge, S is the number of core electrons. The higher the Zeff, the greater the relative attraction for valence electrons
39
Antoine Lavoisier
"Father of modern chemistry" who first organized the 'elements' (some were compounds, not elements). His 'list of simple substances' was ordered based off of reactivity w/ oxygen and other elements
40
Johann Dobereiner
scientist who made Model of Triads in 1829. He grouped 3 sets of 3 elements with similar chemical properties (e.g. Li, Na, and K reacting with water, chlorine and hydrogen similarly).
41
Law of triads
Law connected to Johann Dobereiner which states the atomic mass of the middle element in a triad about equals the mean of the 1st and 3rd atomic masses. (1st observed pattern in the elements)
42
John Newlands
Scientist who created the law of octaves in 1865.
43
Law of Octaves
law created by John Newlands. When elements placed in order of atomic weights, every 8th element has similar properties to the 1st. (predecessor of periodic law)
44
Dmitri Mendeleev
OUR MAN who created 1st periodic table in 1869. He arranged them in a grid and listed elements in atomic mass. He predicted the existence and properties of elements not yet discovered e.g. Gallium
45
Henry Moseley
Made the modern periodic table! He ordered the elements in increasing atomic number.
46
Moseley's experiments
Lowkey don't understand this ahaha Moseley shot beta particles at atoms and on impact, each element emitted an X ray with a unique frequency. He made graph by plotting the sq root of the x ray frequency vs the atomic number, and found that it was an increasing linear graph. This means that the atomic number was equal to the amount of charge in the nucleus, and the atomic number = the number of protons
47
Periodicity
tendency to recur at intervals
48
How to know valence electrons based on spdf notation
total number of s and p in the highest PEL
49
Alloy
mixture or blend of 2 or more metallic elements. Made from melting then mixing metals, properties differ to original metals.
50
representative elements
elements group 1,2,13-18 that make up the 'main group' of elements with regular properties i think