Unit 3.4 Thermal Physics Flashcards
What is internal energy?
(3 things)
- Sum of the random distribution
- of kinetic & potential energies
- in a substance (solid, liquid and gas)
What is KE in a substance?
(2-way)
- Energy a substance has
- due to the movement of the ptcls in it
What is PE in a substance?
(3-way)
- Energy a substance contains
- due to the breaking of bonds
- & overcoming molecular attractive forces
Tell me about the changes of state
(2-way + 2-way)
- As temp of a substance rises
- changes state
- Internal energy also rises
- BUT, KE & PE don’t rise simultaneously
Describe the heating curve from points A - F
(5 points to describe)
(It’s probably better if u draw it)
- A - B = rise
- B - C = constant
- C - D = rise
- D - E = constant
- E - F = rise
From the heating curve, why does the temp. remain constant at some points?
(1 + 2-way)
- KE remains constant
- PE increasing as
- intermolecular forces are overcome
From the heating curve, which letter does KE only increase?
(3 things)
- None
- KE increases as temp. increase
- PE increases as ptcls move further apart
Which letters does only PE increase?
(3 things)
- B - C & D - E
- as KE doesn’t increase due to temp. = constant
- PE increases as intermolecular forces = overcome
From the heating curve, which points have both KE & PE increasing?
(3 things)
- A - B
- C - D
- E - F
State the relationship between temperature and KE?
Directly proportional
(Ek ∝ T)
Describe the process of melting using simple kinetic model
(3 things)
- Bonds breaking
- Particles no longer fixed in place
- Can move around each other
Describe the process of boiling using simple kinetic model
(2 things)
- All bonds broken
- Particles are completely free
Describe the process of evaporating using simple kinetic model
(2 things)
- Particles at the surface of the substance
- break all bonds and become free
From heating curve, describe energies at 0K?
(3 things)
- Minimum internal energy (u) at 0K
- Ek = 0
- Ep = minimum
Internal energy expressed as an equation?
Internal energy = Σ kinetic energy + potential energy
Symbol form of internal energy equation?
U = Σ Ek + Ep
Internal energy of an ideal gas equation?
(in data booklet)
U = 3/2 nRT
Why is the internal energy equation for an ideal gas different?
(2 things)
- Ideal gas has no intermolecular forces
- Therefore U = Σ Ek
What about the internal energy at 0K for an ideal gas?
(1 + 3-way)
- No internal energy at 0k
- U = Σ Ek and EK = 0
- as Ek ∝ T
- Therefore U = 0
What is thermodynamics?
(2-way)
- The study of heat energy &
- energy transfer
What is thermodynamics concerned with?
(3-way)
(probably optional)
- Interactions within a system
- and between the system
- and its surroundings
If an object is hot, where would heat go?
To the cold surroundings
If the surroundings is hot and the object is cold, where would heat go?
To the cold object
When heat transfers, what eventually happens to both the object and surroundings?
Reach same temperature
When they reach the same temperature, what happens to heat transfer?
Net energy/heat transfer stops
The scientific term for net energy/heat transfer stopping?
Thermal equilibrium
Describe heat (systems)
(2-way + 2 things)
- Heat = Q
- is the energy flow from higher to lower temp.
- Heat flows in/out of a system
- System has energy not heat
Describe work (systems)
(3 things + 2-way)
- It’s like heat
- It’s energy in transit
- System doesn’t have work
- Has energy but work can be done by system
- as it transfers energy
Can energy be created/destroyed?
(5 by 5 steps)
- No
- If gas has work done
- Has transferred energy
- Energy must’ve entered gas
- Heat flow into gas = increase in U + work done by gas
Work done by a gas in expanding/contracting expressed in words?
Change in work done = pressure x change in volume
Work done by a gas in expanding/contracting in symbol form?
(data booklet)
△W = p△V
Derivation of ΔW = pΔV?
(4-way)
- Work = force x distance
- W = F x Δx
- W = P x A x Δx & A x Δx = ΔV
- HENCE, ΔW = pΔV
What happens to heat if work is done on the system and △W is -ve?
(2 things)
- Will flow out of system
- IF not in isolation
If a constant force is applied, what happens to the pressure?
(△W = p△V)
(2 things)
- Pressure = no change (isobaric)
- △W proportional to volume
How to find work done from △W = p△V graph?
Area under graph
If the △W = p△V graph is curved, how to find work done?
Count squares to estimate area under curve
If volume increases & pressure remains constant, deduce about the change in temperature of the gas
(1 + 2-way)
- PV/T is constant
- At constant pressure
- V & T increases