Unit 3.4 Thermal Physics Flashcards
What is internal energy?
(3 things)
- Sum of the random distribution
- of kinetic & potential energies
- in a substance (solid, liquid and gas)
What is KE in a substance?
(2-way)
- Energy a substance has
- due to the movement of the ptcls in it
What is PE in a substance?
(3-way)
- Energy a substance contains
- due to the breaking of bonds
- & overcoming molecular attractive forces
Tell me about the changes of state
(2-way + 2-way)
- As temp of a substance rises
- changes state
- Internal energy also rises
- BUT, KE & PE don’t rise simultaneously
Describe the heating curve from points A - F
(5 points to describe)
(It’s probably better if u draw it)
- A - B = rise
- B - C = constant
- C - D = rise
- D - E = constant
- E - F = rise
From the heating curve, why does the temp. remain constant at some points?
(1 + 2-way)
- KE remains constant
- PE increasing as
- intermolecular forces are overcome
From the heating curve, which letter does KE only increase?
(3 things)
- None
- KE increases as temp. increase
- PE increases as ptcls move further apart
Which letters does only PE increase?
(3 things)
- B - C & D - E
- as KE doesn’t increase due to temp. = constant
- PE increases as intermolecular forces = overcome
From the heating curve, which points have both KE & PE increasing?
(3 things)
- A - B
- C - D
- E - F
State the relationship between temperature and KE?
Directly proportional
(Ek ∝ T)
Describe the process of melting using simple kinetic model
(3 things)
- Bonds breaking
- Particles no longer fixed in place
- Can move around each other
Describe the process of boiling using simple kinetic model
(2 things)
- All bonds broken
- Particles are completely free
Describe the process of evaporating using simple kinetic model
(2 things)
- Particles at the surface of the substance
- break all bonds and become free
From heating curve, describe energies at 0K?
(3 things)
- Minimum internal energy (u) at 0K
- Ek = 0
- Ep = minimum
Internal energy expressed as an equation?
Internal energy = Σ kinetic energy + potential energy
Symbol form of internal energy equation?
U = Σ Ek + Ep
Internal energy of an ideal gas equation?
(in data booklet)
U = 3/2 nRT
Why is the internal energy equation for an ideal gas different?
(2 things)
- Ideal gas has no intermolecular forces
- Therefore U = Σ Ek
What about the internal energy at 0K for an ideal gas?
(1 + 3-way)
- No internal energy at 0k
- U = Σ Ek and EK = 0
- as Ek ∝ T
- Therefore U = 0
What is thermodynamics?
(2-way)
- The study of heat energy &
- energy transfer
What is thermodynamics concerned with?
(3-way)
(probably optional)
- Interactions within a system
- and between the system
- and its surroundings
If an object is hot, where would heat go?
To the cold surroundings
If the surroundings is hot and the object is cold, where would heat go?
To the cold object
When heat transfers, what eventually happens to both the object and surroundings?
Reach same temperature
When they reach the same temperature, what happens to heat transfer?
Net energy/heat transfer stops
The scientific term for net energy/heat transfer stopping?
Thermal equilibrium
Describe heat (systems)
(2-way + 2 things)
- Heat = Q
- is the energy flow from higher to lower temp.
- Heat flows in/out of a system
- System has energy not heat
Describe work (in systems)
(2 things + 2-way)
- It’s like heat; energy in transit
- System doesn’t have work
- Has energy but work can be done by system
- as it transfers energy
Can energy be created/destroyed?
…. Why bro?
(4 by 4 steps)
No:
- If gas has work done
- Has transferred energy
- Energy must’ve entered gas
- Heat flow into gas = increase in U + work done by gas
Work done by a gas in expanding/contracting expressed in words?
Change in work done = pressure x change in volume
Work done by a gas in expanding/contracting in symbol form?
(data booklet)
△W = p△V
Derivation of ΔW = pΔV?
(4-way)
- Work = force x distance
- W = F x Δx
- W = P x A x Δx & A x Δx = ΔV
- HENCE, ΔW = pΔV
What happens to heat if work is done on the system and △W is -ve?
(2 things)
- Will flow out of system
- IF not in isolation
If a constant force is applied, what happens to the pressure?
(△W = p△V)
(2 things)
- Pressure = no change (isobaric)
- △W proportional to volume
How to find work done from △W = p△V graph?
Area under graph
If the △W = p△V graph is curved, how to find work done?
Count squares to estimate area under curve
If volume increases & pressure remains constant, deduce about the change in temperature of the gas
(1 + 2-way)
- PV/T is constant
- At constant pressure
- V & T increases
What would the △W = p△V graph look like if temperature was -ve?
(2 things)
- Temp decreases = volume decreases
- The opposite curve
Explain work done by gas = expansion
(4 things)
- Gas expanded…
- Molecules lose KE
- Positive work on piston
- +ve△W
Explain work done by system = compression
(4 things)
- Gas compressed…
- Molecules gain KE
- Negative work on piston
- -ve△W
What is the first law of thermodynamics
(a word eqn)
Heat energy absorbed = increase in internal energy by system + work done by the system
Symbol form of the first law of thermodynamics
(in data booklet)
Q = △U + W
Define Q
(first law of thermodynamics)
Heat energy absorbed
Define △U
(first law of thermodynamics)
Change in internal energy
Define W
(first law of thermodynamics)
Work done by system
What does it mean if Q is positive?
(first law of thermodynamics)
(2 things)
- Heat enters system
- Positive Q transfers energy to the system
What does it mean if Q is negative?
(first law of thermodynamics)
(2 things)
- Heat leaves system
- Negative Q transfers energy from the system
What does it mean if △U is positive?
(first law of thermodynamics)
(4-way)
- Temperature increases
- U ∝ T means an increase in T,
- giving increase in U
- U = positive
What does it mean if △U is negative?
(first law of thermodynamics)
(1-3-way)
- Temperature decreases
- U ∝ T means a decrease in T,
- giving a decrease in U
- U = negative
What does it mean if W is positive?
(first law of thermodynamics)
(5-way)
- Work is done by the gas
- Gas expanding
- Positive change in volume
- W = P x △V
- W is positive
What does it mean if W is negative?
(first law of thermodynamics)
(5-way)
- Work is done on the gas
- Gas compressing
- Negative change in volume
- W = P x -△V
- W is negative
How does a freezer use the first law of thermodynamics?
(Outside part)
(4 things)
- Coolant/refrigerant put into pipes
- Outside the freezer, pipes get thinner
- gets pumped around pipes, compresses coolant
- Coolant = warmer
How does a freezer use the first law of thermodynamics?
(Inside part)
(3 things)
- Coolant goes inside refrigerator
- Pipes get wider
- Coolant gets colder
Explain freezer in terms of the 1st law of thermodynamics pt. 1
(Inside)
(4 things)
- Pipe widens, volume increases
- PV/T = constant (pressure constant)
- Temp. inside pipe increases
- Q = △U + W
Explain freezer in terms of the 1st law of thermodynamics pt. 2
(Inside)
(3 things)
- W positive (expanded), △U positive (inc. in T)
- Q must be positive
- Heat flows from freezer into pipe
What about freezer outside in terms of the 1st law of thermodynamics?
(Independence right here… actually major check up yet no nothing soooo…)
Uhhh
1st law of thermodynamics data booklet edition?
△U = Q - W
(pray u know by then)
Sub △W = p△V into the 1st law of thermodynamics
(That’s work done in expanding a system)
(2-way)
- Q = △U + W
- Q = △U + P△V
What are the 4 different processes that affect how we write the 1st law of thermodynamics?
- Adiabatic processes (Q = 0)
- Constant Volumes processes (W = 0)
- Constant temperature (△U = 0)
- Cyclical process (W = Q)
What is the adiabatic processes?
(Q = 0)
When P, V & T not fixed
Explain adiabatic processes?
(2-way)
- If system well insulated
- No transfer of heat in/out of system
What does the first law become in adiabatic processes?
(2 way)
△U = W
(nR△T = area under graph)
Explain the graph of adiabatic processes?
(4 things)
(Whiteboard, means u draw it)
- Diagonal down line
- Going up = compression (-ve work)
- Going down = expansion (+ve work)
- PV/T = constant
What is constant volume processes?
(W = 0)
Isochoric
(V = fixed)
Explain constant volume processes?
(4 things)
- If volume held constant
- System can’t do work
- Happens to a solid/liquid
- due to volume being fixed
What does the first law become in constant volume processes?
(3 way….?)
△U = Q
(3/2 n R△T = △U)
(W = P△V, SO W = 0)
Explain the graph of constant volume processes?
(3 things)
(Whiteboard, means u draw it)
- Straight line down/up
- No area under graph, no work
- △pV = nR△T
What is “constant temperature”?
(△U = 0)
Isothermal
(T = fixed)
Explain “constant temperature”?
(2-way)
- For an isothermal process
- pV = constant
What does the first law become in “constant temperature”?
(3 way…?)
△U = 0
U ∝ T
Q = W
Explain the graph of “constant temperature”?
(3 things)
(Whiteboard, means u draw it)
- Curving down line
- PV = constant
- Work = area under graph
What is cyclical process?
(W = Q)
Work done = heat flow
Explain cyclical process?
(3 things)
- After certain interchanges of heat and work,
- are restored to their initial state
- So, no properties of the system are changed
What does the first law become in cyclical process?
△U = 0
Explain the graph of cyclical process?
(4 things)
(Whiteboard, means u draw it)
- Triangle with points A, B & C
- Area of triangle = total work done
- W +’ve if expansion higher
- W -‘ve if compression higher
How much energy required to raise temperature of 1kg of a substance?
1K
“Specific heat capacity” equation
(different re-iteration in data booklet)
E = m x c x △T
Word form of “specific heat capacity” equation?
Energy = mass x specific heat capacity x rise in temperature
Specific heat capacity at it’s “base”?
(2-way-step)
- C = J/KgK
- JKg-1K-1
Specific heat capacity at it’s SI units?
(Another 2-way-step)
- C = Kgm2s-2/KgK
- m2s-2k-1
How do u find the thermal equilibrium temperature during energy transfer between 2 blocks?
(5 steps)
(Heavily question in-need, refer to “page 19”)
(Whiteboard)
- Use E = m x c x △T
- Find their value for each block
- For T of each, ? - T if higher temp, vice versa for other
- Left = Right
- Re-arrange, VOILA
What are the items needed for the practical to finding the specific heat capacity?
(7 things)
- Power supply
- Ammeter
- Voltmeter
- Thermometer
- Heater
- Metal block
- “insulation”
How do u place the ammeter and voltmeter in the practical to finding the specific heat capacity?
(2-way)
- Ammeter = series
- Voltmeter = parallel
How do u draw the diagram of the practical to work out the specific heat capacity?
(Whiteboard lol)
Trust on the following day
Method for practical to work out specific heat capacity?
(3 steps)
- Record start temperature
- Turn heater on (record I, V) for 10 mins
- Record highest temperature reached
How do u calculate the energy?
(Practical to find specific heat capacity)
E = IVt
Energy = current x voltage x time
Some energy will be lost to the material of the container. How it’ll affect experimental value + how to minimise that?
(Practical to find specific heat capacity)
(2-way y’all)
- Experimental value = higher than actual value
- Insulation to minimise effect
Units for specific heat capacity. How come u can leave the temperature at degrees Celsius?
(Practical to find specific heat capacity)
(3 thingies)
- Formula for SHC uses difference in temperature
- NOT absolute temperature
- and 1°c = 1K
How to improve results and experiment?
(Practical to find specific heat capacity)
(3… way)
- Add more insulation, by adding lid, prevent heat loss to surroundings
- Add oil, induce contact with heat & block
- Do repeats to check for anomalies
The main way to improve investigation to measure specific heat capacity?
(2 things)
(probably white board??????)
- Range of results taken
- Graph analysis used
This booklet contains the min + max gradients, therefore, pls don’t forget (hopefully) that for the Uncertainties (EXCLUSIVE)
Hope
Ya did it
Always check
Spam the questions
K