unit 3 - chem math Flashcards
mole
- a mole represents a number
- 1 mole = 6.02 x 10^23
mass of an atom is in
AMU
mass of a mole of atoms is in
grams
when converting moles to anything
MOLEtiply
when converting TO moles
divide
gram formula mass
- mass of 1 mole
- the mass of a substance expressed in grams instead of AMU
molar mass
gfm
% composition
the amount of an element in a compound expressed as a %
hydrate
is a salt that has a definite amount of water molecules embedded into its structure
anhydrous salt
what we are left with after heating a hydrate and the water evaporates
molecular formula
- true formula for a compound
- exact number of atoms of each element in the compound
empirical formula
simplest whole # ratio of compound
to find the ratio of molecular to empirical…
molecular mass/empirical mass
1 mole of any gas occupies
22.4 liters at STP
stoichiometry
the area of chem math where we take a balanced chemical equation to use mole ratios (coefficients) to make predictions about the products of the reaction
1 step stoichiometry problems are
- mole to mole
- liter to liter
limiting reagent problems
a reactant is in short supply
hint about determine LR problems
LR problems will give you the masses of each reactant
elements
made of one kind of atom
compound
substance made of two or more elements that are chemically combined
ionic compounds
form between positive and negative ions
when do u use roman numerals
always use a roman numeral to designate the charge on metals with multiple oxidation states
molecules
made of 2 NON METALS held together by covalent bonds
covalent bonds prefix vowel rule
drop the o or a in the prefix name if the element begins with a vowel
ammonia
NH3
hydrogen peroxide
H2O2
subscripts
number written below and to the right of a chemical symbol, shows the number of atoms of each element
chemical formula
a shorthand notation for a compound or diatomic element
chemical equation
a representation of a chemical reaction where the reactants and products are expressed in formulas
what is conserved in chemical reactions
mass charge and energy
the law of conservation of mass
- mass is neither created nor destroyed in any chemical reaction
- the number of atoms of each element in the reactants must equal the number of atoms of each element in the products
combustion
a chemical combines with OXYGEN to produce carbon dioxide and water
synthesis
production of a single compound from two or more substances (elements)
methane
CH4
decomposition
when a single compound breaks down into 2 or more simpler substances
single replacement
an element (a) reacts with a compound (bc) to take the place of one of the components of the compound
double replacement
two compounds both exchange partners
atom
smallest particle of an element
atoms are made of 3 subatomic particles
protons, neutrons, electrons
nucleon
any particle found in the nucleus (protons and neutrons)
all atoms are electrically neutral because…
electrons = #protons
protons
- particles found in the nucleus of an atom
- have a mass of 1 amu
- each have a +1 charge
- number of protons of an atom NEVER change
atomic number
the number of protons
nuclear charge
the number of protons
neutrons
- particles that are located in the nucleus
- have a mass of 1 amu
- neutral charge
mass number
the total number of protons and neutrons in an atom (always a whole number)
mass # = P + N
electrons
- particles that rotate or revolve around the nucleus
- very small (1/1836 of a proton)
- mass = zero AMU
- charge for each is -1
- electrons are lost and gained in chemical reactions
23
Na
11
23 <- mass number (P + N)
Na <- element symbol
11 <- atomic number (=P)
S-32 , C-12
32 & 12 are mass numbers
ions
atoms with a charge
- #Protons does not equal #Electrons
- amount of positive charge does not equal negative charge
isotopes
atoms of the same element that have the same number of protons, BUT a different number of neutrons
- named after their mass number
atomic mass
average of the masses of all naturally occurring isotopes of an element
- written as a decimal
- closest to the mass number of the most common isotope
john dalton
cannonball model
- believed that atoms were solid with indivisible parts
- atoms were indestructible
- believed that atoms are the basic unit of matter
jj thomson
plum pudding model
- discovered electrons using a cathode ray tube
- believed atoms were solid, positive spheres with electrons embedded in it
ernest rutherford
nuclear model
- an atom has a positive nucleus at the center, with electrons outside the nucleus
- atom is made up mostly of empty space
gold foil experiment
observations:
- most alpha particles went through the gold foil
- occasionally an alpha particle was deflected back
conclusions:
- atom is made up mostly of empty space
- an atom has a positive, dense, nucleus
niels bohr
planetary/bohr model
- electrons are arranged in energy levels in orbit around the nucleus
- electrons orbit around the nucleus like planets move around the sun
- electrons revolve around in several concentric rings/shells/PELs
- each ring represents an amount of energy electrons have associated with a definite average distance from the nucleus
PEL 1 electron capacity
2
PEL 2 electron capacity
8 electrons
PEL 3 electron capacity
18 electrons
PEL 4 electron capacity
32 electrons
modern theory
wave mechanical theory or electron cloud model
- one cannot predict the exact position of an electron in time
- electrons are found in orbitals
orbitals
regions of electron probability
electronic configuration
of electrons in each ring around the atom
valence electrons
electrons that are in the outermost ring of an atom, involved in bonding
ground state
- all the electrons are in the lowest energy orbitals or rings
- this state is the electron configuration given on the periodic table
excited state
- an electron has absorbed energy and temporarily moved to a higher energy ring
- unstable condition
light produced
- when an electron absorbs energy it jumps away from the nucleus and enters the excited state
- when the electron falls back down to the ground state it releases energy in the form of light
spectroscope
an instrument that can separate polychromatic light into the many wavelengths of light that make it up
color spectrum of an element is
a unique characteristic and can be used to identify it; it’s a unique fingerprint
sublevels
s p d f
principle quantum number
determines the number of sublevels within the PEL
electron spin
an orbital can hold only two electrons and they must have opposite spin
electron configurations w skips
- note that after the 3p sublevel is filled, the 4s is filled than the 3d
- 4s is further from the nucleus BUT electrons in 3d have more energy due to repulsion between electrons