unit 13 - organic chemistry Flashcards

1
Q

hydrocarbons

A
  • called hydrocarbons because they are ONLY made of hydrogen and carbon atoms
  • each series is called a homologous series
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2
Q

why is each series of hydrocarbons called a homologous series?

A
  • because all the molecules in a series share the same general formula
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3
Q

properties of organic compounds: melting and boiling point

A
  • contain carbon and covalently bonded
  • low melting point and boiling point
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4
Q

properties of organic compounds: reacting time

A
  • slow reacting bc they are large and don’t dissociate
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5
Q

properties of organic compounds: molecule type

A
  • mostly nonpolar molecules (symmetrical)
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6
Q

properties of organic compounds: solubility

A
  • usually not soluble in water (polar)
  • “like dissolves like”
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7
Q

properties of organic compounds: electrolytes?

A
  • most are non-electrolytes (poor conductors)
  • ** except for organic acid **
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8
Q

homologous series #1: alkanes

A
  • straight chain with ONLY single bonds (saturated) between the carbons
  • formula name: ends in -ane
  • general formula: C(n)H(2n+2) where
    n=whole number
  • ex: n=10
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9
Q

meth-

A

1 carbon

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10
Q

eth-

A

2 carbons

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11
Q

prop-

A

3 carbons

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12
Q

but-

A

4 carbons

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13
Q

pent-

A

five carbons

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14
Q

hex-

A

6 carbons

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15
Q

hept-

A

7 carbons

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16
Q

oct-

A

8 carbons

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17
Q

non-

A

9 carbons

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18
Q

dec-

A

10 carbons

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19
Q

how many electrons does a carbon atom need to complete its valence shell

A

4 electrons
- need to see 4 lines (bonds) around each carbon

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20
Q

how many more electrons does a hydrogen atom need to complete its valence shell?

A

1

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21
Q

methane molecular formula

A

CH4

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22
Q

ethane molecular formula

A

C2H6

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23
Q

propane molecular formula

A

C3H8

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24
Q

butane molecular formula

A

C4H10

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25
pentane molecular formula
C5H12
26
hexane molecular formula
C6H14
27
heptane molecular formula
C7H16
28
octane molecular formula
C8H18
29
nonane molecular formula
C9H20
30
decane molecular formula
C10H22
31
side chains
- Hydrocarbons that have 1 less Hydrogen than the formula call for - methyl, ethyl, propyl
32
methyl group
- CH3
33
ethyl group
- C2H5
34
propyl group
- C3H7
35
naming side chains: number of side chains
- first 4 prefixes that exist - mono (not used) - di: 2 of a group - tri: 3 of a group - tetra: 4 of a group
36
steps to naming alkanes with side chains
1. find the # of carbon in the longest chain 2. name this chain with the prefix & -ane 3. name any side chains 4. number side chains to give the lowest # carbon 5. list the side chains alphabetically before longest chain name
37
homologous series #2: alkenes
- hydrocarbons that contain DOUBLE BONDS (btw two carbons) - unsaturated - general formula: C(n)H(2n) - formula name ends in: -ene
38
methene
CH2
39
ethene
C2H4
40
propene
C3H6
41
butene
C4H8
42
pentene
C5H10
43
naming alkenes: position of "="
- need a # to tell you the position of C=C
44
homologous series #3: alkynes
- hydrocarbons with a TRIPLE bond - unsaturated - general formula: C(n)H(2n-2) - "yne"
45
ethyne
- C2H2
46
propyne
C3H4
47
butyne
C4H6
48
pentyne
C5H8
49
functional groups
- have other elements, not just C & H like hydrocarbons - If the name of a functional group has a number, the functional group can move; if not the group is always on the end
50
halides general formula
- have the general formula "R-X" - Where R is a long chain of carbons and the “X” stands for a Halogen (Group 17: F,I,Br,Cl) Fluoro, Iodo, Bromo, & Chloro - Halides are names like Alkanes but a Halogen replaces a Hydrogen atom ex: - 2-Di (ex. 2,3 DiChloro) - 3-Tri (ex. 2,2,3 TriBromo)
51
halogens bonding rules
- halogens are in group 17 - have 7 valence electrons and only need one more - halogens ONLY need one bond between them and another atom
52
halides
- think of them as a methyl or an ethyl group - use specific words (fluoro, iodo, etc) - the halides replace a hydrogen - just like the side chains, make sure that the halides get the lowest number possible
53
halide names: F
fluoro
54
halide names: Cl
chloro
55
halide names: I
iodo
56
halide names: Br
bromo
57
aldehydes (-CHO)
- known for distinctive fragrances, solvents - named like alkane, drop "e" and add "al" ex: pentane -> pentanal ** name NEVER gets a # bc the group is always on the end of a molecule - they are named by the number of carbons in the chain
58
aldehydes bonding rules: O
- O is in group 16, it has 6 valence electrons and needs two more - Oxygen must have two bonds around it like in C=O
59
aldehydes: methanal
- formaldehyde - disinfectant
60
ketones (-COC-)
- energy source derived from fatty acids when body is low on glucose; solvents - named like alkane, drop "e" and add "one" - names of ketones MUST get a number bc group is moveable - ***remember C=O must be around 2 carbons, so it can not be on carbon #1
61
ketone naming example
ex: 2 Butanone or just butanone ex: 3 Pentanone (# is crucial here)
62
2 Propanone
acetone
63
isomers: aldehydes and ketones
- aldehydes and ketones that have the same molecular formula are isomers of each other ex: Pentanal & 2 Pentanone
64
alcohols (-OH)
- nonelectrolytes - used as beverages, solvents, fuels - they can have more than 1-OH but not on the same carbon atom - name like alkanes, drop the "e" and add "ol" - alcohols MUST have #'s bc OH group is moveable
65
drinkable alcohol is...
ethanol
66
3 types of alcohols
- categorized by # of OH's - monohydroxy alcohols: 1OH - dihydroxy alcohols: 2 OH ex: 1, 2 ethanediol - trihydroxy alcohols: 3 OH
67
glycerol
1, 2, 3 propanetriol - trihydroxy alcohol
68
monohydroxy alcohols
- alcohols that have 1-OH group: - primary, secondary, or tertiary
69
Monohydroxy Alcohols: Primary Alcohol
- alcohol in which the carbon with the "OH" group is attached to only 1 carbon
70
Monohydroxy Alcohols: Secondary Alcohol
- alcohol carbon is bonded to 2 other carbons
71
Monohydroxy Alcohols: Tertiary Alcohol
- alcohol carbon is bonded to three other carbons - alcohol has a side chain
72
ethers (-OC)
- used as solvents - general formula: R-O-R - named by side groups on each side of the oxygen atom ex: CH3OCH3 -> dimethyl ether
73
alcohols and ethers
- alcohols and ethers with the same molecular formula and different structure are isomers ex: 2 Butanol and Diethyl Ether
74
organic acids (-COOH)
- used for food preservation bc they inhibit bacterial growth - name like an alkane, drop "E" and add "oic acid" - name NEVER gets a number because the COOH is always on the end of the molecule
75
esters (-COOC)
- fruit smelling (aromatic), used in perfumes and cosmetics - name side chain off the "o" - name like alkane, drop the "e" and add the oate - named in two pieces; side chain and the other side, nvr gets a number
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isomers: organic acids and esters
- that have the same molecular formula but diff structures are isomers - ex: pentanoic acid and ethyl propanoate
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-COOH
organic acid
78
-CHO
aldehydes
79
-COOC
esters
80
-COC
ketone
81
-OH
alcohol
82
-OC
ether
83
amines (-NH2)
- derived from ammonia, used in dyes and decongestants - name like alkane, drop "e", and add "amine" - one of 2 groups that contain N - MUST get a # bc the NH2 group is movable
84
amides (-CONH2)
- used in making paper, crayons, pencils & inks - name like alkane, drop "e" and add "amide"
85
combustion
Is an organic reaction because it involves the burning of hydrocarbons in the presence of Oxygen to produce Carbon Dioxide and Water - Hydrocarbon + O2 → CO2 + H2O
86
addition
• The organic version of synthesis • The break down of a alkene’s (unsaturated) double bond to a single bond and halogen atoms add on where the double bond was
87
fermentation
• The process by which bacteria or yeast convert glucose into ethanol (2 carbon alcohol) and carbon dioxide • 1C6H12O6 → 2 C2H5OH + 2 CO2
88
substitution
• Occurs when a hydrogen on an ALKANE is placed by a halogen
89
esterification
• The process of making Esters and water from an organic acids and an alcohol by dehydration synthesis • Org acid + alcohol → Ester + H2O
90
saponification
The process of making soap from animal FAT and a strong base. The products are 3 soap molecules and glycerol
91
polymerization
• The process of putting together many smaller repeating units (monomers) to make a larger molecule (polymer)
92
natural polymers
- made by living things • monomers -> polymers • amino acids -> proteins • glucose/sugar -> carbs, cellulose (plant cell walls)
93
synthetic polymers
• made in a laboratory - ex: rayon, nylon, polyethylene, plastics, polyester
94
condensation polymerization
- dehydration synthesis - removal of H2O to put monomers together
95
addition polymerization
- alkene, unsaturated
96
isomers
- molecules that have the same molecular formula but different structure - isomers will differ in physical properties such as melting point, boiling point, density, solubility, etc