Unit 3 Flashcards
Kinetic Molecular Theory
Describes Ideal Gas No Attractive Forces
Boyles Law
Inverse relationship of pressure and volume P1V1=P2V2
Charles Law
Proportional relationship of temperature and volume V/T=V/T
Combined Gas Law
No direct relationships PV/T=PV/T
Avogadros Law
Amount/Volume Relationship If two gases have same temp & pressure, must have same # of molecules
Daltons Law
If you have mixture of gases, the sum of all the pressures of the gases equals total pressure of mixture
Use % to find Partial Pressure
Mole percentage of gases overall makeup is proportinoal to percentage it contributes to overall pressure
Effusion
r1/r2=m2/m1
Root Means Square
Assumes molecule possess avg. kinetic energy Urms= SqrRt(3RT/M)
Ideal Gas Law
PV=nRT
Ideal Gas Law (for Density/Molar Mass)
M=dRT/P
Van Der Waals Equation
Tweaks ideal gas law for attractive forces a & b are constants for each molecule P=(nRT/V-nb)-(n2 a/ v2)
1 mol of an gas @ STP
Equals 22.4L
Mass-Volume Stoichometry
Mass Given -> Moles Given -> Mols of Unknown -> Volume of Unknown
Solute
Substance being disolved
Solvent
Does the disolving
Soluble
Able to be dissolved
Insoluble
Cant be dissolved
Like Dissolves
Like
Suspensions
needs to be constantly stirred or solute particles will settle out Can be filtered out easily
Colloids
Mixture that appears to be solution, but will eventually settle out Test with Tyndall Effect (shinning light)
Liquid-Gas Solution Factors
Temperature and Pressure
Most are soluble
Nitrate Salts
Alkali Metal Salts
Ammonium Salts
Halogen Salts (except lead. mercury, silver)
Sulfate Salts (except lead, mercury, barium, calcium)
Molarity
Moles Solute/Liters Solution
Molality
Moles Solute/Kilogram Solvent
Mass Percentage
mass component/mass solution x100%
ppm
mass component/mass solution x10^6
ppb
mass component/mass solution x10^9
Volatility
volatile substances evaporate quickly
Four Colligative Properties
Vapor Pressure Reduction
Boiling Point Elevation
Freezing Point Depression
Osmotic Pressure
Boiling Point Elevation
[Delta]Tb=Kb x m
Constant is .52 c/m
Freezing Point Depression
[Delta]Tf=Kf x m
Constant is 1.86 c/m
Osmotic Pressure
[Pie Symbol?]=MRT
Isotonic
When two solutions of indentical concentrations are separated
Hypotonic
One solution os lower than others
Hypertonic
One solution is higher than other