Unit 3 Flashcards
What is Valence Shell Electron - Pair Repulsion Theory (VSEPR)?
Describes the orientation of electron groups around the central atom.
- States that electrons are arranged as far apart as possible around the central atom
- States that the specific shape of a molecule is determined by the number of atoms attached to the central atom.
Explain a linear molecular shape
Linear
- 2 electron groups
- 2 bonded pairs
- 0 lone pairs
Explain a trigonal planar molecular shape
Trigonal planar
- 3 electron groups
- 3 bonded pairs
- 0 lone pairs
Explain a bent molecular shape
Bent
(two ways to write)
120 Degrees
- 3 electron groups
- 2 bonded pairs
- 1 lone pair
or
109 Degrees
- 4 electron groups
- 2 bonded pairs
- 2 lone pairs
Explain a tetrahedral molecular shape
Tetrahedral
- 4 electron groups
- 4 bonded pairs
- 0 lone pairs
Explain a trigonal pyramidal molecular shape
Trigonal pyramidal
- 4 electron groups
- 3 bonded pairs
- 1 lone pairs
How do you predict the molecular shape of a compound?
- Draw the Lewis structure
- Count the number of bonded pairs and lone pairs for the central atom
- Using the info you know about each shape, determine the correct shape
How do you determine the polarity of a molecule?
The molecule is polar if there are different terminal atoms or if there are lone pairs around the central atom. Otherwise, the molecule is nonpolar!
What’s the difference between intramolecular and intermolecular forces?
An “intramolecular force” is the force that holds atoms together within a molecule (covalent bond), while an “intermolecular force” is the force that exists between separate molecules.
- Intramolecular forces are all stronger than intermolecular forces.
Explain Ionic Bonds.
- Strong bonds between ions.
Explain Dipole-Dipole forces.
- Medium strong forces between polar molecules.
- Molecules orient themselves so that their negative side aligns with the positive side of another molecule.
Explain Hydrogen Bonds.
- Strong forces between all molecules.
- Molecule has N, O, or F attached to a hydrogen atom; H atom forms hydrogen bond with the N, O, or F on another molecule.
Explain Dispersion Forces.
- Weak forces between all molecules.
- Electrons in a neutral atom or molecule “flow” to one side of the atom/molecule and create a temporary negative charge.
Explain the melting points of intermolecular forces.
Melting points of compounds are related to the strength of intermolecular forces between molecules or compounds.
- They are lower due to weak forces such as dispersion forces
- They are higher due to stronger forces such are hydrogen bonding.
What is a Chemical change/reaction?
A chemical change occurs when a substance is converted into one or more new substances with different formulas and different properties.
- It may be observed by the formation of bubbles, a change in color, the production of a solid, or heat.