Unit 2 Exam Flashcards

1
Q

Redox Reactions involve….

A

The transfer of electrons

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2
Q

Oxidation

A

Loss of electrons

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3
Q

Reduction

A

Gain of Electrons

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4
Q

Oxidizing Agent

A

Thing being reduced

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5
Q

Reducing Agent

A

Thing being oxidized

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6
Q

What are the two types of Cells. Give a brief description

A

Voltaic (Galvanic)- Spontaneous, system does work on surroundings Anode (-) -> Cathode (+)
Electrolytic- nonspontaneous, energy comes from surroundings Anode (+) -> Cathode (-)

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7
Q

Where does Oxidation occur?
Reduction?

A

Anode
Cathode

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8
Q

What does the salt bridge do?

A

Prevents the buildup of electrons at the cathode and a lack of electrons at the anode

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9
Q

Which has a higher reduction potential, the anode or the cathode?

A

Cathode

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10
Q

Voltage

A

Potential energy, potential for electrons to flow

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11
Q

Standard Hydrogen Electrode

A

Accepted Zero voltage
Not practical because of the release of H2 gas

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12
Q

Indicator Electrode

A

Where the analyte is active, most likely the Cathode

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13
Q

Reference electrode

A

Maintains a constant potential for relative voltage measurements by the indicator electrode
Anode

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14
Q

Examples of reference electrodes

A

Copper in lab
Ag/AgCl electrode
Hydrogen electrode
Combination electrode
Saturate Calomel Ectectrode (S.C.E)

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15
Q

Examples of indicator electrodes

A

Metal (wire, lead)
Ion selective (detecting only one ion)

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16
Q

How does a pH indicator work

A

PH of internal solution is fixed, as the pH of the external solution changes, the electron potential across the glass changes

17
Q

How does an ion selective electrode work?

A

Unknown ion on outside, known on the inside, influx tells you the concentration

18
Q

How is the voltage and the flow of electrons related?

A

The bigger the voltage the better the flow of electrons

19
Q

Overpotential

A

Voltage required to overcome the activation energy for a reaction at an electrode surface

20
Q

Ohmic Potential

A

Voltage needed to overcome the inherent cell resistance

21
Q

Concentration Polarization

A

Occurs when the concentrations of reactants and products are different from those in bulk solution

22
Q

How does adding ions (salt) effect the resistance

A

By adding salt, you are increasing the ions and decreasing the resistance because the ions are passing on the charge