Unit 2 Flashcards

1
Q

What do reducing agents do?

A

They undergo oxidation

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2
Q

What do reducing agents do?

A

They undergo oxidation i.e. Lose electrons

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3
Q

What do oxidising agents do?

A

They gain electrons

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4
Q

What functional group do carboxylic acids have?

A

COOH O Carboxyl

C-OH

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5
Q

What functional group do alcohols have?

A

-OH Hydroxyl

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6
Q

How many bonds do each of the following elements need to have?

A
Carbon-4
Oxygen-2
Hydrogen-1
Halogens-1
Nitrogen-3
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7
Q

What type of reaction takes place when an ester is formed?

A

Condensation reaction

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8
Q

What ester is formed when ethanol reacts with propanoic acid?

A

Ethyl propanoate

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9
Q

What catalyst is used to prepare an ester?

A

Concentrated sulphuric acid

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10
Q

How can the hydrolysis of an ester be brought about?

A

By warming the ester with an alkali like sodium hydroxide solution through a reflux condenser

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11
Q

How do you calculate the percentage yield?

A

Percentage = Actual yield X 100

Yield Theoretical

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12
Q

When 5.2g of ethanol is mixed with excess ethanoic acid and a few drops of sulphuric acid, 8.12g of ethyl ethanoate is formed. What is the percentage yield of ethyl ethanoate?

A

✔️ ❓
Ethanol + ethanoic acid ➡️ ethyl ethanoate + water

n= 5.2/46 m= n x fm
= 0.113043478 = 0.113043478 x 88
= 9.9g

% = 8.12/9.9 x 100 = 82%

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13
Q

What is the difference between fats and oils?

A

Fats are solids at room temperature while oils are liquids. Oils therefore have a lower melting point

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14
Q

What does saturation mean?

A

All single bonds

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15
Q

What does unsaturation mean?

A

Some double C=C bonds

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16
Q

Fat molecules

A

They have all single bonds so can pack close together

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17
Q

Oil molecules

A

Have C=C double bonds so molecules cannot pack close together therefore melting points are lower

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18
Q

What reaction takes place when fats or oils are formed

A

Condensation reaction since fats and oils are naturally occurring esters

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19
Q

What is the only alcohol that is in fats and oils?

A

Glycerol

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20
Q

Why are fats and oils called triglycerides?

A

Because 3 moles of acid are required for each mole if glycerol

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21
Q

What is the addition of hydrogen called?

A

Hydrogenation

22
Q

What 4 elements do proteins contain?

A

CHON

Carbon, Hydrogen, Oxygen and Nitrogen

23
Q

What 2 functional groups do amino acids have per molecule?

A

Amino group Carboxyl group
H O
N ⏸
H -C-OH
O
H H ⏸
N - C - C - OH
H R

24
Q

What are enzymes?

A

Soluble globular proteins which act as biological catalysts

25
What functional group do aldehydes/alkanals have?
O ⏸ Carbonyl group (on end carbon) -C-OH
26
What functional group do ketones/alkanones have?
O ⏸ Carbonyl group (on middle carbon) -C-H
27
What is the formula for Benzene?
C H | 6 6
28
What are three uses for aromatic compounds?
Medicines, dyes and paints
29
How do you identify a primary alcohol?
The -OH is bonded to a carbon with two -H atoms
30
How do you identify a secondary alcohol?
The -OH is bonded to a carbon which is bonded to one -H atom
31
How do you identify a tertiary alcohol?
The -OH is bonded to a carbon which is not bonded to any hydrogen atoms
32
What do oxidation reactions involve?
Either the addition of oxygen or the removal of hydrogen
33
What are the two steps when primary alcohols are oxidised?
Alcohol➡️Aldehyde➡️Carboxylic Acid
34
What happens when a secondary alcohol is oxidised?
Alcohol➡️Ketone➡️No further oxidising
35
What happens when tertiary alcohols undergo oxidation?
They do not undergo oxidation
36
When using acidified potassium dichromate, what is the colour change?
Orange➡️Green
37
When using acidified potassium permanganate, what is the colour change?
Purple➡️Clear
38
What 2 ways can prevent good from spoiling?
Add an antioxidant or prepare food in an inert gas e.g nitrogen
39
How is soap formed?
By the alkaline hydrolysis is fats and oils
40
What is the equation of soap forming?
Fat/oil + Sodium Hydroxide ➡️ Soap + Glycerol
41
What does hydrophobic mean?
Water hating
42
What does hydrophilic mean?
Water loving
43
What is an emulsifier?
A substance which allows substances to be soluble in water
44
What are free radical scavengers?
Molecules which react with free radicals to form stable molecules and prevent chain reactions
45
What are essential oils?
The concentrated extracts of volatile, non-water-soluble aroma compounds from plants
46
What are essential oils used in?
Perfumes, cosmetic products, cleaning products and as flavourings in food
47
What is steam distillation?
One of the methods used to extract oils from plants
48
What are terpenes?
Natural organic compounds
49
What are terpenes used in?
Perfumes, essential oils and medicines
50
What are free radicals?
An atom with an unpaired electron and is highly reactive