Unit 1 Flashcards

1
Q

Volume Units

A

3 -1

cm s

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2
Q

Mass Units

A

-1

gs

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3
Q

Concentration Units

A

-1 -1

moll s

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4
Q

What is Enthalpy?

A

A measure of the energy stored in a chemical

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5
Q

Exothermic Reaction

A

The products have less energy than the reactants.

Give out energy.

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6
Q

Endothermic Reaction

A

The products have more energy than the reactants.

Take in energy.

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7
Q

What does Heterogenous mean?

A

Different state

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8
Q

What does homogenous mean?

A

Same state

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9
Q

How could you distinguish between metals and non-metals?

A

Conductivity test

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10
Q

What is the Activation Energy (Ea)?

A

The minimum kinetic energy reactants need in order to become products

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11
Q

What is the Activated Complex?

A

The unstable arrangement of atoms at the peak of the Energy diagram

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12
Q

What does a catalyst do?

A

Speeds up the reaction

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13
Q

What happens to the nuclear charge as you go across a period and down a group?

A

As you got across the PT the nuclear charge increases.

As you go down a group the number of energy levels increases but the number of outer electrons stays the same

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14
Q

What is the trend in atomic size/volume as you go across the PT and down a group?

A

The atomic size decreases across a period as the nuclear charge increases pulling outer electrons closer to the nucleus.

Down a group atomic size increases as there are more energy levels.

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15
Q

What happens to the Ionisation energy as you go across a period and down a group?

A

Across a period the ionisation energy increases as the nuclear charge increases holding the outer electrons closer.

Down a group the ionisation energy decreases as the outer electrons are further away from the effect of the nucleus. There is also a screening effect from the inner electrons which shields the outer electrons from the full nuclear charge.

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16
Q

What is the 1st Ionisation energy?

A

The energy needed to remove the first mole of electrons.

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17
Q

What is the 1st, 2nd and 3rd Ionisation energy of Magnesium?

A

+ - -1
1st- Mg(g) ➡️ Mg (g) + e 744kJmol
+ 2+ - -1
2nd- Mg (g) ➡️ Mg (g) + e 1460kJmol
2+ 3+ - -1
3rd- Mg (g) ➡️ Mg (g) + e 7750kJmol

18
Q

Why is there such a large jump in the third Ionisation energy of Magnesium?

A

Because the third electron if pulled off a full outer energy level which is closer to the nucleus

19
Q

What is Electronegativity?

A

A measure of atoms attraction for electrons in a bond

20
Q

What happens to the Electronegativity as you go across a period and down a group?

A

Across a group the Electronegativity increases as the growing nuclear charge pulls bonding electrons closer.

Down a group the Electronegativity decreases as the bonding electrons are further away from the nucleus and there is a screening effect from the inner electrons.

21
Q

Average Rate

A

Change in volume/time taken
Change in mass/time taken
Change in concentration/time taken etc.

22
Q

What is intramolecular bonding?

A

These are the bonds between atoms inside molecules

E.g. H - Cl
⬆️
intra

23
Q

What is Covalent bonding?

A

Covalent bonds occur in non-metal atoms, these share their outer electrons

24
Q

What is pure covalent bonding?

A

When each atom has the same electronegativity values, so the electrons are shared equally

25
Q

What is polar covalent bonding?

A

Polar covalent bonds are formed in compounds between non-metal atoms which have different electronegativity values

26
Q

What is Ionic bonding?

A

Ionic bonds are formed between metal and non-metal atoms with a large difference in electronegativity.

Atoms gain or lose electrons to be like the nearest noble gas.

27
Q

What is Metallic bonding?

A

Metallic bonds occur between atoms of metal elements.

Metals have very little attraction for their outer electrons, which are free to move (delocalised).

28
Q

What is Intermolecular bonding (Van der Waals)?

A

This is the name given to the bonding which exist between molecules

29
Q

What are London Dispersion Forces?

A

These are cause by uneven distributions of electrons.

The atom or molecule gets a slightly charged end which induces an opposite charge in neighbouring atoms/molecules.

30
Q

What is polar-polar attraction?

A

A polar molecule has permanently charged ends.

Polar to polar attraction is the attraction between opposite charges on neighbouring molecules.

31
Q

What is Hydrogen Bonding?

A

This is where hydrogen is bonded to very electronegative elements:

N O F

32
Q

What are the properties of the Noble Gases?

A

Monatomic
Only have London Dispersions Forces
Low mpt/bpt
Don’t conduct electricity

33
Q

What are the properties of Covalent Molecular elements?

A

Low mpt/bpt
Only have London Dispersion Forces
Don’t conduct electricity

34
Q

What are the properties of Covalent Network elements?

A

Giant network structures containing millions of atoms
High mpt/bpt
Don’t conduct electricity
Strong covalent bonds between atoms

35
Q

What are the properties of Metallic Lattices?

A

High mpt/bpt

Conduct electricity

36
Q

Why are some polar molecules overall non-polar?

A

Because there are no polar to polar attraction neighbouring molecules as the molecules are symmetrical

37
Q

What are the 3 allotropes of Carbon?

A

Graphite
Diamond
Fullerenes

38
Q

Graphite

A

Covalent network
Conducts electricity
Used in pencils

39
Q

Diamond

A

Covalent network
High mpt/bpt
Doesn’t conduct electricity
Used in drill heads and jewellery

40
Q

Fullerenes

A

Covalent molecular
Doesn’t conduct electricity
Used in nano-technology