Unit 1 Flashcards

1
Q

Volume Units

A

3 -1

cm s

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2
Q

Mass Units

A

-1

gs

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3
Q

Concentration Units

A

-1 -1

moll s

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4
Q

What is Enthalpy?

A

A measure of the energy stored in a chemical

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5
Q

Exothermic Reaction

A

The products have less energy than the reactants.

Give out energy.

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6
Q

Endothermic Reaction

A

The products have more energy than the reactants.

Take in energy.

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7
Q

What does Heterogenous mean?

A

Different state

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8
Q

What does homogenous mean?

A

Same state

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9
Q

How could you distinguish between metals and non-metals?

A

Conductivity test

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10
Q

What is the Activation Energy (Ea)?

A

The minimum kinetic energy reactants need in order to become products

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11
Q

What is the Activated Complex?

A

The unstable arrangement of atoms at the peak of the Energy diagram

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12
Q

What does a catalyst do?

A

Speeds up the reaction

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13
Q

What happens to the nuclear charge as you go across a period and down a group?

A

As you got across the PT the nuclear charge increases.

As you go down a group the number of energy levels increases but the number of outer electrons stays the same

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14
Q

What is the trend in atomic size/volume as you go across the PT and down a group?

A

The atomic size decreases across a period as the nuclear charge increases pulling outer electrons closer to the nucleus.

Down a group atomic size increases as there are more energy levels.

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15
Q

What happens to the Ionisation energy as you go across a period and down a group?

A

Across a period the ionisation energy increases as the nuclear charge increases holding the outer electrons closer.

Down a group the ionisation energy decreases as the outer electrons are further away from the effect of the nucleus. There is also a screening effect from the inner electrons which shields the outer electrons from the full nuclear charge.

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16
Q

What is the 1st Ionisation energy?

A

The energy needed to remove the first mole of electrons.

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17
Q

What is the 1st, 2nd and 3rd Ionisation energy of Magnesium?

A

+ - -1
1st- Mg(g) ➡️ Mg (g) + e 744kJmol
+ 2+ - -1
2nd- Mg (g) ➡️ Mg (g) + e 1460kJmol
2+ 3+ - -1
3rd- Mg (g) ➡️ Mg (g) + e 7750kJmol

18
Q

Why is there such a large jump in the third Ionisation energy of Magnesium?

A

Because the third electron if pulled off a full outer energy level which is closer to the nucleus

19
Q

What is Electronegativity?

A

A measure of atoms attraction for electrons in a bond

20
Q

What happens to the Electronegativity as you go across a period and down a group?

A

Across a group the Electronegativity increases as the growing nuclear charge pulls bonding electrons closer.

Down a group the Electronegativity decreases as the bonding electrons are further away from the nucleus and there is a screening effect from the inner electrons.

21
Q

Average Rate

A

Change in volume/time taken
Change in mass/time taken
Change in concentration/time taken etc.

22
Q

What is intramolecular bonding?

A

These are the bonds between atoms inside molecules

E.g. H - Cl
⬆️
intra

23
Q

What is Covalent bonding?

A

Covalent bonds occur in non-metal atoms, these share their outer electrons

24
Q

What is pure covalent bonding?

A

When each atom has the same electronegativity values, so the electrons are shared equally

25
What is polar covalent bonding?
Polar covalent bonds are formed in compounds between non-metal atoms which have different electronegativity values
26
What is Ionic bonding?
Ionic bonds are formed between metal and non-metal atoms with a large difference in electronegativity. Atoms gain or lose electrons to be like the nearest noble gas.
27
What is Metallic bonding?
Metallic bonds occur between atoms of metal elements. Metals have very little attraction for their outer electrons, which are free to move (delocalised).
28
What is Intermolecular bonding (Van der Waals)?
This is the name given to the bonding which exist between molecules
29
What are London Dispersion Forces?
These are cause by uneven distributions of electrons. The atom or molecule gets a slightly charged end which induces an opposite charge in neighbouring atoms/molecules.
30
What is polar-polar attraction?
A polar molecule has permanently charged ends. Polar to polar attraction is the attraction between opposite charges on neighbouring molecules.
31
What is Hydrogen Bonding?
This is where hydrogen is bonded to very electronegative elements: N O F
32
What are the properties of the Noble Gases?
Monatomic Only have London Dispersions Forces Low mpt/bpt Don't conduct electricity
33
What are the properties of Covalent Molecular elements?
Low mpt/bpt Only have London Dispersion Forces Don't conduct electricity
34
What are the properties of Covalent Network elements?
Giant network structures containing millions of atoms High mpt/bpt Don't conduct electricity Strong covalent bonds between atoms
35
What are the properties of Metallic Lattices?
High mpt/bpt | Conduct electricity
36
Why are some polar molecules overall non-polar?
Because there are no polar to polar attraction neighbouring molecules as the molecules are symmetrical
37
What are the 3 allotropes of Carbon?
Graphite Diamond Fullerenes
38
Graphite
Covalent network Conducts electricity Used in pencils
39
Diamond
Covalent network High mpt/bpt Doesn't conduct electricity Used in drill heads and jewellery
40
Fullerenes
Covalent molecular Doesn't conduct electricity Used in nano-technology