Unit 2) 3) Strong And Weak Acids And Bases Flashcards
Definition of strong and weak in chemistry (acids and bases)
- the words strong and weak have very different meaning : string acid is either concentrated or dilute depending on the number of moles of acid per litre of solution. Same applies to weak acid
What is monoprotic / monobasic acid
- Any acid weak or strong that is capable of donating ONE hydrogen ion per molecule is termed monoprotic or monobasic
- an acid like sulphuric acid which can donate two hydrogen ions is called diprotic or dibasic
- hydrochloric , nitric and ethanoic acids are monoprotic
What is the degree of ionisation and what does it determine
- the degree of ionisation is the ability of the non ionised acid molecule to produce hydrogen ions
- this is what determines whether an acid is classified as strong or weak
- the more an acid molecule tends to produce hydrogen ions the stronger it will be
Definition of a strong acid
A strong acid is completely disassociated (ionised ) in aqueous solution
What are strong lab acids
- hydrochloric acid (HCL)
- nitric acid (HNO3)
- sulfuric acid (H2SO4)
What do these strong acids do when in water
They will fully dissociate (or ionise) in water. This means all the acid molecules become ions.
What does a strong acidic solution consist of for example HCL and how can this be indicated through its equation
- an aqueous solution of hydrogen chloride (hydrochloric acid) will exist entirely as hydronium and chloride ions. No molecules or hydrogen chloride are present
- the arrow (in equation (HCL(g) + H20(l) —- > H+ (aq) + Cl- (aq) ) tells us that the reaction goes fully in the left to right direction
Weak acid definition
A weak acid is only partially dissociated in aqueous solution. Weak acids are an equilibrium mixture of non ionised acid molecules, hydrogen ions and the conjugate base of the acid.
Examples of weak acids
Most carboxyxilic acids eg ethanoic acid, methanoic acid , propanoic acid
Carbonic acid
Sulfurous acid
Weak acids are in data booklet
What does a weak acid consist of and what indicates this in equation
- equilibrium mixture of non ionised acid molecules , hydrogen ions and the conjugate base of the acid
- ethanoic acid equation (CH3COOH(aq) + H2O___ (equilibrium arrow) ____ CH3COO-(aq) + H3O+ (aq) ) the equilibrium reversible arrow tells us that the dissociation process
- the position of the equilibrium lies well over to the left hand side so there will be very few hydronium ions and ethanoate ions present at equilibrium compared with a much larger number of ethanoic acid molecules
- we can also say that the value of the equilibrium constant K is much less than 1 for this reaction
Acids such as carbonic , sulfurous and sulfuric have two hydrogen atoms per molecule that can become hydrogen ions are known as diprotic acids.
Their ionisation takes place in _____ steps. This is show in the data booklet
Two
Strong and weak bases
The same definitions apply to strong and weak bases
Definition and Examples of strong base
- strong base is completely ionised in aqueous solution I.e all the available hydroxide ions are released into solution.
Examples include
Oxides and hydroxides Of group (sodium hydroxide , potassium hydroxide )
Oxides and hydroxides of Group 2 metals : barium hydroxide , barium oxide
Definition and examples of a weak base
- a weak base is partially ionised in aqueous solution, only some of the molecules in a weak base are disassociated (ionised) when dissolved in water
- ammonia
- amino alkanes (amines)
Position of equilibrium of weak base
- position of equilibrium lies well over to the left hand side (K<1)