synthesis summary reactions thing Flashcards

1
Q

all reactions usuing concentrates sulfuric / nitic / phosphoruc acid catalysts

A
  • dehydration of alcohols forming alkenes (sulfuric)
  • alcohols and carboxylic acids forming ester(sulf/phos)
  • sulfonation (sulf)
  • nitration ( sulf+nitr mixture)
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2
Q

using acids catalysts

A

acid catalysed hydration

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3
Q

using lithium aluminium hydride dissolved in ether

A
  • reduction of aldehydes/ketones forming alcohols

- carboxylic acid + lithium alu.. forming alcohol

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4
Q

using aq KOH/NaOH

A

nucleophilic sub of monohaloalkane forming alcohol

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5
Q

using KOH in hot ethanol

A

base induced elimination of monohaloalkanes

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6
Q

using oxidising agents (copper oxide, acidified dichromate, acidified potassium permangante )

A
  • alcohols reacting with oxidising agents to form aldehydes/ketones
  • oxidising alcohols to form carboxylic acid
  • oxidising aldehydes to form carboxylic acid
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7
Q

using aq acid / an alkali

A
  • hydrolysing nitrile to form carboxylic acid ( acid)
  • hydrolysing amides ( acid/ alkali)
  • hydrolysing esters ( acid/alkali)
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8
Q

using methoxide in alcohol ( eg potasssium methoxide in methanol ) ( alcoholic alkoxides)

A
  • nucleophilic substitition of monohaloalkane to form ether
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9
Q

using ethanolic potassium cyanide

A

nucleophilic sub of monohaloalkanes forming nitriles

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10
Q

catalyst of nickel / platinum

A

electrophilic addition of alkene - hydrogenation

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11
Q

catalyst alcl3

A

alkylation of benzene

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12
Q

catalyst alcl, iron(iii) chloride

A

chlorination

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13
Q

catalyst AlBr iron(iii)Br

A

bromination

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