Unit 2 - #10 Amines / Amides Flashcards
Naming - Amine
-amine
Naming - Amide
-amide
MP/BP - Amine
Intermediate, lower than alcohol
MP/BP - Amide
Very high, higher than alcohol
Polarity/Solubility - Amine
Polar, soluble
Polarity/Solubility - Amide
Polar, soluble
State - Amine
Gases (smaller), solids (larger)
State - Amide
Solids
Notable use - Amine
Dye
Notable use - Amide
Kevlar vests
Name - C-C-C-N
Propanamine
Name - N-C-C-C(-C)-C-C-C (cyclical)
3-methylaniline
Name - C-C-C-C-C-N-C
N-methylpentan-2-amine
Name - C-C-C-C(=O)-N-C
N-methylbutanamide
Name - C-C(=O)-N(-C)-C-C
N-ethyl-N-methylethanamide
Formation - Amide
Carboxylic acid + Amine
What are primary, secondary, and tertiary amines?
- N attached to 1 C, 2 H bond sites
- N attached to 2 C, 1 H bond sites
- N attached to 3 C, 0 H bond sites
Rank M.P/B.P of primary, secondary, tertiary amines
3 < 2 < 1
What is the naming for a benzene ring with an amine group?
-aniline
How do you turn a primary amine into a secondary amine?
Haloalkane + Primary Amine -> Secondary Amine
How do you create a primary amine?
Add a haloalkane to ammonia.
X-R + NH3 -> R-NH2 + X
Explain amidification
Type of condensation
Carboxyl group (COOH) + Amine group (N) = Amide group C(=O)-N + H2O removed
