Unit 12/13/14 Flashcards
Fast diffusion
High to low concentration
Low density of liquid or solid
Liquid 1g/1000 cc
Solid 1g/cc
1 atm
760mm Hg or 760 torr
1 Pa
.0000009869 atm (6 zeros)
.00750 torr or mm Hg
Sea level=1 atm
760 torr=760 mm Hg=101.325 kPa=14.696 psi
Stp T
0 C or 273 K
Standard pressure 1 atm
760 torr or mm Hg=101.325 kPa
Standard molar volume
1 mole of any gas 22.4 L
Dalton’s partial pressure law
Total pressure is equal to sum of each gases partial pressure
Pt=Pa+Pb+Pc….+Pn
*Charles law V1/T2=
V2/T1
Boyles law P1V1=
P2V2
Combined gas laws
P1V1/T1=
P2V2/T2
PV=nRT
P=pressure in atm V=volume in liters n=number of moles R=gas constant .0821L(atm)/mol(K) T=temp in K
Molecular weight and density
D=MP/RT
M=molar mass D=density mass/volume R=.0821 T=temp in K P=pressure in atm M=DRT/P Remember HOFBRINCL
Graham’s law (effusion)
Rate a/rate b=sqrt(molar mass b/molar mass a)
Convert pressure to atmospheres
645 mm to atm
645 x 1 atm/760 mm = .85 atm
Density in?
g/L
Find mass using density formula
m=MPV/RT
What type of equation?
An 800 mL sample of gas, measured at 44 C and 900 mm pressure. How many moles?
PV=nRT or n=PV/RT
What type of equation?
Total pressure is 1.8 atm. Container contains 255 mm pressure due to N2, 518 mm pressure due to CO2 and in unknown pressure of CL2. What is the pressure due to the chlorine gas?
Pt=Pa+….Pc
Pt=760(1.8)-518-255=595 mm
What type of equation?
What is the molecular weight of a gas that effuses 0.629 times as fast as O2.
Rate of a/rate of b=sqrt(Mb)/sqrt(Ma)
.629=sqrt(32g/mol)/x
What type of equation?
What is the molecular weight of 3.47 g of a gas at 87 C with a volume of 3 L at a pressure of 1.4 atm?
D=PM/RT or M=DRT/P
What type of equation?
What is the mass in grams of 1 L of methane (CH4) at STP?
m=MPV/RT
What type of equation?
Convert to standard conditions: 1520 mL of gas at -33 C and 720 mm pressure.
V1P1T2=V2P2T1 or V1P1/T1=V2P2/T2
What type of equation?
A sample of gas occupies 50 L at 27 C. What will be the volume of the gas in L at ST?
V1T2=V2T1
What type of equation?
A gas has a volume of 240 mL at 70 cm pressure. What pressure, in cm is needed to reduce the volume to 60 mL.
V1P1=V2P2
Mole-mole
How many moles of ammonia are produced when 6 moles of hydrogen gas react with an excess of nitrogen gas?
3H2+N2—>2NH3
6molH2 x 2mol NH3/3molH2= 4 mol NH3
Mercury (ii) oxide
HgO
Write the combustion reaction for pentane
C5H12—>5CO2+6H2O
Limiting reactant
That amount of reactant that controls the amount produced. Completely consumed in the reaction.
Excess reactant
Left over. Not completely consumed.
Rules for finding limiting reactant
Solve both equations
-the one that produces the least is the limiting-correct amount
Percent yield formula
Percent yield=actual/theoretical x 100
Butane
C4H10
Pentane
C5H12
Stoichiometry and density in liquid and gas
Liquid g/mL
Gas g/L
Stoichiometry molarity
Used when determining volume of aqueous solution. M=moles/Liter
H is always terminal atom
Can only hold 2 electrons
Central atom usually has lower
Electronegativity