Unit 1 Topic 2 - Thermodynamics Flashcards

1
Q

What type of molecule has a better source of potential energy for a cell?

A

Non-polar covalent bonds

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2
Q

First law of thermodynamics

A

The total amount of energy in a system and its surroundings remains constant

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3
Q

Second law of thermodynamics

A

The entropy of a system and its surroundings is always increasing

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4
Q

At the equilibrium point of an exercising reversible reaction,

A

An equal number of reactant molecules are being converted to products as there are product molecules being converted to reactants

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5
Q

What is true of exergonic reactions?

A

Free energy decreases as the reaction proceeds and the reactants have more free energy than the products

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6
Q

Is energy released or absorbed in the breakdown of complex molecules? (catabolic reaction)

A

Released

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7
Q

Why is ATP useful in living cells?

A

The free energy released when ATP is hydrolyzed can be used to drive endergonic cell functions

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8
Q

How do cells replenish ATP supplies?

A

By coupling endergonic ATP synthesis with exergonic catabolic reactions

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9
Q

In an exergonic reaction, activation energy is

A

The amount of energy that must be absorbed by reactants before the reaction can proceed

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10
Q

Energy

A

Capacity to do work

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11
Q

Kinetic energy

A

Energy of motion

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12
Q

Potential energy

A

Energy stores in an object because of its location or chemical structure

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13
Q

What is potential energy related to?

A

The position of electrons

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14
Q

The farther away an electron is from the nucleus of an atom, the greater or lesser its potential energy?

A

Great

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15
Q

Isolated system

A

Does not exchange energy or matter with its surroundings

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16
Q

Closed system

A

System that exchanges energy but not matter with its surroundings

17
Q

Open system

A

System that exchanges both energy and matter with its surroundings

18
Q

Entropy

A

Tendency of energy to become dispersed or spread out

19
Q

Processes with a negative delta G are

A

Spontaneous and exergonic

20
Q

Processes with a positive delta G are

A

Endergonic and require free energy

21
Q

Exergonic reactions…

A

Release free energy and the reactants have more free energy than the products

22
Q

Diffusion is an example of an exergonic or endergonic reaction?

A

Exergonic. It is driven by the increase in entropy as molecules spread out and it is spontaneous!

23
Q

What happens at chemical equilibrium?

A

Reactants are converted to products and products are converted back to reactants at equal rates

24
Q

Living systems are highly organized but still follow the second law of thermodynamics… why?

A

They are open systems and use energy and matter from the surroundings. The entropy of the surroundings increases

25
Why is a constant supply of energy (food) required to sustain life?
All biological molecules breakdown (entropy increases
26
Metabolism
Biochemical modification and use of energy in the synthesis and breakdown of organic molecules
27
Catabolic pathway
Releases the potential energy of a molecule in breaking it down to a simpler molecule (exergonic)
28
Anabolic pathway
Uses energy to convert a simple molecule to a more complex molecule (endergonic)
29
How does the cell make the endergonic reaction associated with ATP proceed spontaneously?
By coupling the exergonic reaction of ATP breakdown (which is not technically a hydrolysis reaction)
30
In exergonic reactions, the products must have ___________ than the reactants
Less free energy
31
Photosynthesis is an endergonic or exergonic process
Endergonic
32
Enthalpy
The potential energy in a system
33
Energy coupling
The process by which ATP is brought in close contact with a reactant molecule involved in an endergonic reaction, and when the ATP is hydrolyzed, the terminal phosphate group is transferred to the reactant molecule.
34
Coupled reaction
Reaction that occurs when an exergonic reaction is joined to an endergonic reaction, producing an overall reaction that is exergonic
35
ATP Cycle
Continued breakdown and resynthesis of ATP
36
How do cells harness the energy of ATP to drive endergonic reactions?
Hydrolyze ATP and use the released phosphate group to phosphorylate a reactant in the endergonic reaction, thereby increasing the energy of the reactant and changing the reaction from a positive delta G to a negative delta G
37
What happens to the phosphate group that is removed when ATP is converted to ADP?
It is acquired by a reactant in an endergonic reaction