UNIT 1 Section 10 - Acids, Bases and pH Flashcards

1
Q

define a bronsted lowry acid

A

proton donor

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2
Q

define a bronsted lowry base

A

proton acceptor

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3
Q

write an equation for the ionisation of water to from H+ ions

A

H2O <—-> H+ + OH-

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4
Q

write an equation for the ionisation of water to produce a hydroxonium ion

A

2H2O <—-> H3O+ + OH-

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5
Q

what is the equation for Kw

A

Kw= [H+][OH-]

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6
Q

what is the value of Kw at 289K

A

1x10-14

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7
Q

what physical factors affect the value of kw and how

A

temperature

if the temperature is increased the equilibrium shifts to the right so Kw increases and the pH decreases

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8
Q

why is pure water still neutral is the pH isnt 7

A

the concentration of H+ is still equal to the concentration of OH-

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9
Q

what is the expression for pH

A

pH=-log10[H+]

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10
Q

if two solutions have a difference of 1 what is the difference in [H+]

A

a factor of 10

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11
Q

what is the expression of [H+] from pH

A

[H+] = 10-pH

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12
Q

what is the difference when finding [H+] from the concentration of diprotic and triprotic acids

A

need to multiply the concentration of the acid by the number of protons

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13
Q

define the term strong acid

A

one which fully dissociates in water

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14
Q

define the term strong base

A

one which fully dissociates in water

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15
Q

what is a weak acid and base

A

weak acids and bases do not fully dissociate in water and only partially dissociate into their ions

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16
Q

give examples of strong acids

A

HCL, H2SO4,H3PO4

17
Q

give some examples of strong bases

A

NaOH, CaCO3, Na2CO3

18
Q

give some examples of weak acids

19
Q

give an example of a weak base

20
Q

what is the expression for Ka

A

Ka = [H+][A-]/[HA]

21
Q

what is a titration

A

teh addition of an acid or base of a known concentration to an unknown base or acid to determine the concentration of the unknown acid or base

22
Q

define the term equivalence point

A

the point where the exact volume of base has been added to neutralise the acid or vice versa

23
Q

what generally happens to the pH of a solution around the equivalence point

A

there is a large and rapid change in pH except in weak acid and weak base titration

24
Q

what is the end point

A

when the indicator just changes colour

25
what are the properites of a good indicator for a reaction
sharp colour change end point must be the same as the equivalence point distinct colour change
26
what indicator would you use for a strong acid-base titration
Phenolphthalein
27
what indicator would you use for a strong-acid weak base titration
methyl orange
28
what indicator would you use for a strong base-weak acid titration
phenolphthalein
29
what indicator would you use from a weak acid and weak base titration
neither work
30
what colour is methyl orange in and acid and colour in an alkali and what pH does it change
red in acid yellow in alkali 4-5
31
what colour is phenolphthalein in and acid and colour in an alkali and what pH does it change
colourless in acid red in alkali 9-10
32
what is the half neutralisation point
when the volume = half the volume that has been added at the equivalence point
33
draw a strong acid base graph
refer to booklet
34
draw a strong acid weak base graph
refer to booklet
35
draw a weak acid strong base graph
refer to booklet
36
draw a weak acid and weak base graph
refer to booklet