Intro to Organic Flashcards

1
Q

why is the IUPAC system useful

A

it allows scientists to discuss organic chemistry safely as they all know what they are talking about

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2
Q

define empirical formula

A

simplest whole number ration of atoms in a molecule

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3
Q

define molecular formula

A

gives the actual number of atoms of different elements in a molecule

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4
Q

define displayed formula

A

shows every atom and every bond in a molecule

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5
Q

define structural formula

A

shows arrangement of atoms in a molecule without showing every bond

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6
Q

define skeletal formula

A

drawn as lines with each vertex being a carbon atom and the carbon atoms and H atoms are assumed

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7
Q

give the suffixes for
a) no double bonds
b) at least one double bonds
c) an alcahol
d) an aldehyde
e) a ketone
f) a carboxylic acid

A

a) ane
b) ene
c) ol
d) al
c) one
f) oic acid

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8
Q

define structural isomerism

A

when molecules have the same molecular formula but different structural formula

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9
Q

what is positional isomerism

A

functional group is attached to the main chain at a different place

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10
Q

what is functional group isomerism

A

same atoms but a different functional group due to a different arrangement of atoms

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11
Q

what is chain isomerism

A

hydrocarbon chain organised differently

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12
Q

define stereoisomerism

A

when molecules have the same structural and molecular formula but have a different arrangement of atoms in space

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13
Q

what is E-Z isomerism and how are the E and Z isomers decided

A

E-Z isomerism is caused by a limited rotation of C=C double bonds

it the two substituents with the highest atomic number are on the same side then it is a Z isomer and if they are on different sides E

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14
Q

define a general formula

A

an algebraic formula that can describe any member of a family of compounds

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15
Q

define a homologous series

A

a family of compounds that have the same functional group and a general formula

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16
Q

what are the features of a homologous series

A
  1. same general formula
  2. increases by CH2
  3. similar chemical properties
  4. gradually changing physical
  5. same functional group