Unit 1, periodic trends Flashcards
one section of it
Trend #1- Atomic radius
Decreases from left to right across periods (strength of nucleus increases with more protons- with a stronger pull on the outer electrons)
Increases from top to bottom down groups (number of energy levels increases, further and further from the nucleus, increasing the size of the atom)
Atomic radius
an estimate of the size of an atom from its nucleus to its outermost electrons
Ionic radius
when an atom loses outer electrons it loses an entire energy level; therefore it becomes smaller, positive cation
a negative ion (anion) has more electrons than protons, the electrons repel each other and the effect of the nuclear charge is shared among more electrons (anions are bigger than their original atoms)
Ion
formed when an atom loses or gains electrons
Cation
positive ion, lost electrons, metals
Anion
negative electron, gained ions, non-metals
Trend #2 Ionization Energy
Ionization energy increases from left to right across a period (since atomic radius decreases, the valence electrons are held closer together, needing more energy to remove)
Ionization energy increases from bottom to top of a group (radius decreases, so more energy is required to remove the valence electrons because there is a greater attractive force)
Ionization energy
the energy reeded to remove a valence electron from an atom or ion in its gaseous state
Electron Affinity
the energy released when a gaseous atom gains an electron
Trend #3 Electron affinity
large values of ionization energy means that removing an electron is difficult and requires a lot of energy
Increases from left to right
Increases from bottom to top
Electronegativity
the attraction an atom has to the electrons it is covalently sharing
Trend #4 Electronegativity
Down a group (decreases)- there are more protons and a greater number of energy levels. The inner electrons are creating a shielding effect resulting in less attraction to the nucleus
Across a period (increases) the radii decreases therefore electrons are held closer to the nucleus since there is a stronger pull, so shared electrons in a bond are attracted more greatly
delta E number line
0-0.4 : non-polar, pure covalent bond, bonding e are shared equally
0.4<x<= 1.7: polar bond, e are not shared equally, partial negatives (biggest number) and partial positives
1.7< : ionic bond or extremely polar covalent bond